{"product_id":"reagents-for-silicon-mediated-organic-synthesis-isbn-9780470710234","title":"Reagents for Silicon-Mediated Organic Synthesis","description":"Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database \u003ci\u003ee-EROS.\u003c\/i\u003e Another hot volume in the series \u003ci\u003eHandbooks of Reagents for Organic Synthesis\u003c\/i\u003e, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry.  \u003cp\u003eFor the selection the Editor focussed on three key synthetic approaches with the greatest impact:\u003c\/p\u003e \u003cp\u003e1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization.\u003c\/p\u003e \u003cp\u003e2. The specific use of the silane functionality as a hetero \u003ci\u003et-\u003c\/i\u003ebutyl group, often colloquially referred to as the use of silicon as a 'fat proton'.\u003c\/p\u003e \u003cp\u003e3. The use of the \u003ci\u003eBrook rearrangement\u003c\/i\u003e as an 'anion relay stratagem'.\u003c\/p\u003e \u003cp\u003eA new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.\u003c\/p\u003e  \u003cb\u003ePreface xiii\u003c\/b\u003e  \u003cp\u003e\u003cb\u003eIntroduction xv\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eReagent Finder Table xxiii\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eShort Note on InChIs and InChIKeys xxxi\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3-Acetoxy-2-trimethylsilylmethyl-1-propene 1\u003c\/p\u003e \u003cp\u003eAllyl(2-chloroethyl)dimethylsilane 9\u003c\/p\u003e \u003cp\u003eAllyl Trichlorosilane 10\u003c\/p\u003e \u003cp\u003eAllyltrimethylsilane 14\u003c\/p\u003e \u003cp\u003eAllyltrimethylsilylzinc Chloride 24\u003c\/p\u003e \u003cp\u003eAmmonium Hexafluorosilicate 25\u003c\/p\u003e \u003cp\u003eAzidotrimethylsilane 26\u003c\/p\u003e \u003cp\u003eBenzene, [[Difluoro(trimethylsilyl)methyl]seleno] 33\u003c\/p\u003e \u003cp\u003eBenzene, [[Difluoro(trimethylsilyl)methyl]thio]- 36\u003c\/p\u003e \u003cp\u003eBenzene, [[(1\u003ci\u003eE\u003c\/i\u003e)-2-(Trimethylsilyl)ethenyl]seleno] 39\u003c\/p\u003e \u003cp\u003eBenzene, [[(1\u003ci\u003eE\u003c\/i\u003e)-2-trimethylsilyl)ethenyl]sulfonyl]- 42\u003c\/p\u003e \u003cp\u003e2,1-Benzoxasilole, 1,3-Dihydro-1,1-dimethyl- 43\u003c\/p\u003e \u003cp\u003e \u003ci\u003eN\u003c\/i\u003e-Benzyl-\u003ci\u003eN\u003c\/i\u003e-(methoxymethyl)-\u003ci\u003eN\u003c\/i\u003etrimethylsilylmethylamine 44\u003c\/p\u003e \u003cp\u003e1,2-Bis(\u003ci\u003et\u003c\/i\u003e-butyldimethylsilyl)hydrazine 46\u003c\/p\u003e \u003cp\u003e1,2-Bis(chlorodimethylsilyl)ethane 48\u003c\/p\u003e \u003cp\u003e1,4-Bis(dimethylamino)-1,1,4,4-tetramethyldisilethylene 50\u003c\/p\u003e \u003cp\u003eBis(1-methoxy-2-methyl-1-propenyloxy)dimethylsilane 51\u003c\/p\u003e \u003cp\u003eBis(methylthio)(trimethylsilyl)methane 52\u003c\/p\u003e \u003cp\u003e[Bis(2-pyridyldimethylsilyl)methyl]lithium 54\u003c\/p\u003e \u003cp\u003e1,3-Bis(triisopropylsilyl)propyne 56\u003c\/p\u003e \u003cp\u003e\u003ci\u003eN,O\u003c\/i\u003e-Bis(trimethylsilyl)acetamide 58\u003c\/p\u003e \u003cp\u003e(1\u003ci\u003eE\u003c\/i\u003e,3\u003ci\u003eE\u003c\/i\u003e)-1,4-Bis(trimethylsilyl)-1,3-butadiene 73\u003c\/p\u003e \u003cp\u003eBis(\u003ci\u003eß\u003c\/i\u003e-trimethylsilylethanesulfonyl)imide 74\u003c\/p\u003e \u003cp\u003e\u003ci\u003eN,O\u003c\/i\u003e-Bis(trimethylsilyl)hydroxylamine 75\u003c\/p\u003e \u003cp\u003eBis[(trimethylsilyl)methyl]zinc 76\u003c\/p\u003e \u003cp\u003eBis(trimethylsilyl) Peroxide 79\u003c\/p\u003e \u003cp\u003eBis(trimethylsilyl) Selenide 82\u003c\/p\u003e \u003cp\u003eBis(trimethylsilyl) Sulfide 83\u003c\/p\u003e \u003cp\u003eBromomagnesium Hexamethyldisilazide 85\u003c\/p\u003e \u003cp\u003e(Bromomethyl)chlorodimethylsilane 85\u003c\/p\u003e \u003cp\u003eBromotrimethylsilane 92\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-1-Bromo-4-trimethylsilyl-1-buten-3-yne 100\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eZ\u003c\/i\u003e)-2-Bromo-1-(trimethylsilyloxy)ethylene 105\u003c\/p\u003e \u003cp\u003e2-Bromo-3-trimethylsilyl-1-propene 106\u003c\/p\u003e \u003cp\u003e(1-Bromovinyl)trimethylsilane 109\u003c\/p\u003e \u003cp\u003e\u003ci\u003et\u003c\/i\u003e-Butyldimethylchlorosilane 110\u003c\/p\u003e \u003cp\u003e\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl Cyanide 120\u003c\/p\u003e \u003cp\u003e(\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl)diphenylphosphine 121\u003c\/p\u003e \u003cp\u003e2-\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl-1,3-dithiane 122\u003c\/p\u003e \u003cp\u003e\u003ci\u003eO\u003c\/i\u003e-(\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl)hydroxylamine 124\u003c\/p\u003e \u003cp\u003e \u003ci\u003eN\u003c\/i\u003e-(\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl)-\u003ci\u003eN\u003c\/i\u003e-methyltrifluoroacetamide 125\u003c\/p\u003e \u003cp\u003e\u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl Trifluoromethanesulfonate 127\u003c\/p\u003e \u003cp\u003e\u003ci\u003et\u003c\/i\u003e-Butyldiphenylchlorosilane 135\u003c\/p\u003e \u003cp\u003e1-\u003ci\u003et\u003c\/i\u003e-Butylthio-1-\u003ci\u003et\u003c\/i\u003e-butyldimethyl-silyloxyethylene 138\u003c\/p\u003e \u003cp\u003e1-\u003ci\u003et\u003c\/i\u003e-Butylthio-1-\u003ci\u003et\u003c\/i\u003e-butyldimethylsilyloxypropene 141\u003c\/p\u003e \u003cp\u003e\u003ci\u003et\u003c\/i\u003e-Butyl Trimethylsilylacetate 147\u003c\/p\u003e \u003cp\u003e3-Butyn-2-ol, 4-(Trimethylsilyl)- 148\u003c\/p\u003e \u003cp\u003eChlorodiisopropylsilane 151\u003c\/p\u003e \u003cp\u003eChlorodimethylsilane 156\u003c\/p\u003e \u003cp\u003eChlorodimethylvinylsilane 157\u003c\/p\u003e \u003cp\u003eChlorodiphenylsilane 162\u003c\/p\u003e \u003cp\u003e(Chloromethyl)dimethylphenylsilane 162\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-(3-Chloro-1-methyl-1-propenyl)-trimethylsilane 166\u003c\/p\u003e \u003cp\u003e1-Chloro-1-methylsiletane 166\u003c\/p\u003e \u003cp\u003eChlorotrimethylsilane 170\u003c\/p\u003e \u003cp\u003eChlorotriphenylsilane 182\u003c\/p\u003e \u003cp\u003eCyanotrimethylsilane 184\u003c\/p\u003e \u003cp\u003eDiazo(trimethylsilyl)methyllithium 191\u003c\/p\u003e \u003cp\u003e(Dibromomethyl)trimethylsilane 197\u003c\/p\u003e \u003cp\u003eDi-\u003ci\u003et\u003c\/i\u003e-butylchlorosilane 198\u003c\/p\u003e \u003cp\u003eDi-\u003ci\u003et\u003c\/i\u003e-butyldichlorosilane 201\u003c\/p\u003e \u003cp\u003e\u003ci\u003etrans\u003c\/i\u003e-1,1-Di-\u003ci\u003et\u003c\/i\u003e-butyl-2,3-dimethylsilirane 207\u003c\/p\u003e \u003cp\u003eDi-\u003ci\u003et\u003c\/i\u003e-butylsilyl Bis(trifluoromethanesulfonate) 209\u003c\/p\u003e \u003cp\u003eDichlorodiisopropylsilane 222\u003c\/p\u003e \u003cp\u003eDichlorodimethylsilane 228\u003c\/p\u003e \u003cp\u003e1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 230\u003c\/p\u003e \u003cp\u003e1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane 233\u003c\/p\u003e \u003cp\u003eDicyanodimethylsilane 234\u003c\/p\u003e \u003cp\u003e1,2-Diethoxy-1,2-bis(trimethylsilyloxy)ethylene 235\u003c\/p\u003e \u003cp\u003e\u003ci\u003eN,N\u003c\/i\u003e-Diethylaminodimethylsilane 237\u003c\/p\u003e \u003cp\u003eDiethyl[dimethyl(phenyl)silyl]aluminum 237\u003c\/p\u003e \u003cp\u003eDiiododimethylsilane 238\u003c\/p\u003e \u003cp\u003eDiisopropyl Chlorosilane, Polymer-supported 240\u003c\/p\u003e \u003cp\u003eDiisopropylsilyl Bis(trifluoromethanesulfonate) 241\u003c\/p\u003e \u003cp\u003eDilithium Cyanobis(dimethylphenylsilyl)-cuprate 248\u003c\/p\u003e \u003cp\u003e(\u003ci\u003ea\u003c\/i\u003e,\u003ci\u003ea\u003c\/i\u003e-Dimethylallyl)trimethylsilane 252\u003c\/p\u003e \u003cp\u003e(2-Dimethylaminomethylphenyl)phenylsilane 253\u003c\/p\u003e \u003cp\u003eDimethyl(phenyl)silane 254\u003c\/p\u003e \u003cp\u003eDimethylphenylsilyllithium 255\u003c\/p\u003e \u003cp\u003e1,1-Dimethylsilacyclobutane 261\u003c\/p\u003e \u003cp\u003eDimethylthexylsilyl Chloride 263\u003c\/p\u003e \u003cp\u003eDimethylthexylsilyl Trifluoromethanesulfonate 265\u003c\/p\u003e \u003cp\u003e1,3,2-Dioxaborolane, 2-(Dimethylphenylsilyl)-4,4,5,5- tetramethyl-, 1,3,2-Dioxaborolane, 4,4,5,5-Tetramethyl- 2-(methyldiphenylsilyl)-, 1,3,2-Dioxaborolane, 4,4,5,5- Tetramethyl-2-(triphenylsilyl)- 270\u003c\/p\u003e \u003cp\u003eDiphenyldifluorosilane 276\u003c\/p\u003e \u003cp\u003eDisilane, 1,1,1,2,2,2-hexamethyl- 278\u003c\/p\u003e \u003cp\u003e1-Ethoxy-1-(trimethylsilyloxy)cyclopropane 285\u003c\/p\u003e \u003cp\u003eEthoxy(trimethylsilyl)acetylene 289\u003c\/p\u003e \u003cp\u003eEthyl Lithio(trimethylsilyl)acetate 293\u003c\/p\u003e \u003cp\u003eEthyl (Methyldiphenylsilyl)acetate 295\u003c\/p\u003e \u003cp\u003eEthyl 2-(Methyldiphenylsilyl)propanoate 296\u003c\/p\u003e \u003cp\u003eEthyl Trimethylsilylacetate 297\u003c\/p\u003e \u003cp\u003eFluorosilicic Acid 301\u003c\/p\u003e \u003cp\u003eFormamide, \u003ci\u003eN\u003c\/i\u003e-\u003ci\u003eN\u003c\/i\u003e,bis(trimethylsilyl)- 302\u003c\/p\u003e \u003cp\u003eHexachlorodisilane 309\u003c\/p\u003e \u003cp\u003eHexamethylcyclotrisiloxane 310\u003c\/p\u003e \u003cp\u003eHexamethyldisiloxane 313\u003c\/p\u003e \u003cp\u003eHexamethyldisilazane 317\u003c\/p\u003e \u003cp\u003e(Iodoethynyl)trimethylsilane 321\u003c\/p\u003e \u003cp\u003e(Iodomethyl)trimethylsilane 323\u003c\/p\u003e \u003cp\u003eIodotrimethylsilane 325\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-1-Iodo-3-trimethylsilyl-2-butene 336\u003c\/p\u003e \u003cp\u003e3-Iodo-2-trimethylsilylmethyl-1-propene 338\u003c\/p\u003e \u003cp\u003eIsocyanatotrimethylsilane 339\u003c\/p\u003e \u003cp\u003eKetene \u003ci\u003et\u003c\/i\u003e-Butyldimethylsilyl Methyl Acetal 341\u003c\/p\u003e \u003cp\u003e3-Lithio-1-triisopropylsilyl-1-propyne 347\u003c\/p\u003e \u003cp\u003eLithium \u003ci\u003eN\u003c\/i\u003e-Benzyltrimethylsilylamide 349\u003c\/p\u003e \u003cp\u003eLithium Bis[dimethyl(phenyl)silyl]cuprate 350\u003c\/p\u003e \u003cp\u003eLithium Cyano(dimethylphenylsilyl)cuprate 353\u003c\/p\u003e \u003cp\u003eLithium Hexamethyldisilazide 356\u003c\/p\u003e \u003cp\u003eMethanamine, 1,1-Bis(trimethylsilyl) 369\u003c\/p\u003e \u003cp\u003eMethanesulfonamide, 1,1,1-Trifluoro-\u003ci\u003eN\u003c\/i\u003e[(trifluoromethyl)sulfonyl]-\u003ci\u003eN\u003c\/i\u003e(trimethylsilyl)- 372\u003c\/p\u003e \u003cp\u003e(Methoxymethyl)bis(trimethylsilyl)amine 374\u003c\/p\u003e \u003cp\u003e1-Methoxy-2-methyl-1-(trimethylsilyloxy)propene 376\u003c\/p\u003e \u003cp\u003e\u003ci\u003eN\u003c\/i\u003e-Methyl-\u003ci\u003eN,O\u003c\/i\u003e-bis(trimethylsilyl)-hydroxylamine 380\u003c\/p\u003e \u003cp\u003eMethyldiphenylchlorosilane 381\u003c\/p\u003e \u003cp\u003e(Methylthio)trimethylsilane 388\u003c\/p\u003e \u003cp\u003eMethyltrichlorosilane 389\u003c\/p\u003e \u003cp\u003eMethyl Trichlorosilyl Ketene Acetal (1) 393\u003c\/p\u003e \u003cp\u003eMethyl 2-Trimethylsilylacrylate 396\u003c\/p\u003e \u003cp\u003e1-Methyl-1-(trimethylsilyl)allene 397\u003c\/p\u003e \u003cp\u003e2-Methyl-2-(trimethylsilyloxy)-3-pentanone 400\u003c\/p\u003e \u003cp\u003ePDMS Thimbles 403\u003c\/p\u003e \u003cp\u003ePhenylsilane–Cesium Fluoride 408\u003c\/p\u003e \u003cp\u003e(2-Phenylsulfonylethyl)trimethylsilane 409\u003c\/p\u003e \u003cp\u003ePhenylthiobis(trimethylsilyl)methane 411\u003c\/p\u003e \u003cp\u003e(Phenylthiomethyl)trimethylsilane 412\u003c\/p\u003e \u003cp\u003e(Phenylthio)trimethylsilane 414\u003c\/p\u003e \u003cp\u003e1-(Phenylthio)-1-(trimethylsilyl)cyclopropane 418\u003c\/p\u003e \u003cp\u003e1-Phenylthio-1-trimethylsilylethylene 419\u003c\/p\u003e \u003cp\u003e2-(Phenylthio)-2-(trimethylsilyl)propane 420\u003c\/p\u003e \u003cp\u003ePhenyl Trimethylsilyl Selenide 421\u003c\/p\u003e \u003cp\u003ePhosphine, Tris(trimethylsilyl)- 422\u003c\/p\u003e \u003cp\u003ePolymethylhydrosiloxane 427\u003c\/p\u003e \u003cp\u003ePotassium Hexamethyldisilazide 432\u003c\/p\u003e \u003cp\u003e (+)-9-(1\u003ci\u003eS\u003c\/i\u003e,2\u003ci\u003eS\u003c\/i\u003e-Pseudoephedrinyl)-(10\u003ci\u003eR\u003c\/i\u003e)-(trimethylsilyl)- 9-borabicyclo[3.3.2]decane 453\u003c\/p\u003e \u003cp\u003e2-Pyridyldimethylsilane 457\u003c\/p\u003e \u003cp\u003eSilane, 1,1-(Chloromethylene)bis[1,1,1]-trimethyl- 461\u003c\/p\u003e \u003cp\u003eSilane, Chlorotri-2-propen-1-yl- 463\u003c\/p\u003e \u003cp\u003eSilane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(\u003ci\u003eE\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003eSilane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(\u003ci\u003eZ\u003c\/i\u003e)\u003c\/p\u003e \u003cp\u003eSilane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1- trimethyl-(\u003ci\u003eE\u003c\/i\u003e + \u003ci\u003eZ\u003c\/i\u003e) 464\u003c\/p\u003e \u003cp\u003eSodium Hexamethyldisilazide 468\u003c\/p\u003e \u003cp\u003eTetrabutylammonium Difluorotriphenylsilicate 479\u003c\/p\u003e \u003cp\u003e2,4,6,8-Tetraethenyl-2,4,6,8-tetramethylcyclotetrasiloxane 484\u003c\/p\u003e \u003cp\u003e3-Tetrahydropyranyloxy-1-trimethylsilyl-1-propyne 487\u003c\/p\u003e \u003cp\u003e1,1,3,3-Tetramethyldisilazane 488\u003c\/p\u003e \u003cp\u003e1,1,2,2-Tetraphenyldisilane 490\u003c\/p\u003e \u003cp\u003eTrialkylsilyl Cyanide, Polymer-supported 494\u003c\/p\u003e \u003cp\u003eTribenzylchlorosilane 496\u003c\/p\u003e \u003cp\u003eTri(\u003ci\u003et\u003c\/i\u003e-butoxy)silanethiol 497\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-1-Tri-\u003ci\u003en\u003c\/i\u003e-butylstannyl-2-trimethylsilylethylene 499\u003c\/p\u003e \u003cp\u003eTrichloroiodosilane 500\u003c\/p\u003e \u003cp\u003eTriethoxysilane 501\u003c\/p\u003e \u003cp\u003eTriethylsilane 506\u003c\/p\u003e \u003cp\u003eTriethylsilyl Hydrotrioxide 514\u003c\/p\u003e \u003cp\u003e3-Triethylsilyloxy-1,4-pentadiene 515\u003c\/p\u003e \u003cp\u003e(\u003ci\u003ea\u003c\/i\u003e-Triethylsilyl)propionaldehyde Cyclohexylimine 516\u003c\/p\u003e \u003cp\u003eTriethylsilyl Trifluoromethanesulfonate 517\u003c\/p\u003e \u003cp\u003eTrimethylsilyl Trifluoromethanesulfonate 518\u003c\/p\u003e \u003cp\u003eTrifluoromethanesulfonic Acid, Chlorobis (1,1-Dimethylethyl)silyl Ester 537\u003c\/p\u003e \u003cp\u003eTrifluoromethyltrimethylsilane 539\u003c\/p\u003e \u003cp\u003eTriisopropylsilanethiol 546\u003c\/p\u003e \u003cp\u003e(Triisopropylsilyl)acetylene 550\u003c\/p\u003e \u003cp\u003eTriisopropylsilyl Chloride 554\u003c\/p\u003e \u003cp\u003eTriisopropylsilylethynyl Triflone 558\u003c\/p\u003e \u003cp\u003eTriisopropylsilyl Trifluoromethanesulfonate 559\u003c\/p\u003e \u003cp\u003eTrimethylsilylacetic Acid 562\u003c\/p\u003e \u003cp\u003eTrimethylsilylacetone 563\u003c\/p\u003e \u003cp\u003eTrimethylsilylacetonitrile 564\u003c\/p\u003e \u003cp\u003eTrimethylsilylacetylene 569\u003c\/p\u003e \u003cp\u003e(Trimethylsilyl)allene 580\u003c\/p\u003e \u003cp\u003eTrimethylsilylallyllithium 582\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-1-Trimethylsilyl-1,3-butadiene 585\u003c\/p\u003e \u003cp\u003e3-Trimethylsilyl-3-buten-2-one 586\u003c\/p\u003e \u003cp\u003e9-[1-(Trimethylsilyl)-2(\u003ci\u003eE\u003c\/i\u003e)-butenyl] -9-borabicyclo[3.3.1]nonane 588\u003c\/p\u003e \u003cp\u003eTrimethylsilylcopper 589\u003c\/p\u003e \u003cp\u003eTrimethylsilyldiazomethane 590\u003c\/p\u003e \u003cp\u003eTrimethylsilyldiethylamine 598\u003c\/p\u003e \u003cp\u003e2-Trimethylsilyl-1,3-dithiane 604\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethanesulfonamide 609\u003c\/p\u003e \u003cp\u003e\u003ci\u003eß\u003c\/i\u003e-Trimethylsilylethanesulfonyl Chloride 611\u003c\/p\u003e \u003cp\u003e[\u003ci\u003eN\u003c\/i\u003e-(2-(Trimethylsilyl)ethanesulfonyl)-imino]phenyliodane 617\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethanethiol 618\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethanol 622\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethoxycarbonylimidazole 627\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethoxymethyl Chloride 628\u003c\/p\u003e \u003cp\u003e[2-(Trimethylsilyl)ethoxymethyl]triphenylphosphonium Chloride 633\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethyl Chloroformate 634\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)ethyl 3-Nitro-1\u003ci\u003eH\u003c\/i\u003e-1,2,4-triazole-1-carboxylate 636\u003c\/p\u003e \u003cp\u003e(Trimethylsilyl)ethynylcopper(I) 637\u003c\/p\u003e \u003cp\u003eTrimethylsilyl Fluorosulfonyldifluoroacetate 638\u003c\/p\u003e \u003cp\u003e\u003ci\u003eN\u003c\/i\u003e-(Trimethylsilyl)imidazole 640\u003c\/p\u003e \u003cp\u003eTrimethylsilylketene 645\u003c\/p\u003e \u003cp\u003eTrimethylsilyllithium 650\u003c\/p\u003e \u003cp\u003eTrimethylsilyl Methanenitronate 653\u003c\/p\u003e \u003cp\u003e1-Trimethylsilyl-1-methoxyallene 656\u003c\/p\u003e \u003cp\u003eTrimethylsilylmethyl Azide 657\u003c\/p\u003e \u003cp\u003e1-[(Trimethylsilyl)methyl]-1\u003ci\u003eH\u003c\/i\u003e-benzotriazole 658\u003c\/p\u003e \u003cp\u003e2-Trimethylsilylmethyl-1,3-butadiene 660\u003c\/p\u003e \u003cp\u003e3-[(Trimethylsilyl)methyl]-3-butenoic Acid Methyl Ester 662\u003c\/p\u003e \u003cp\u003eTrimethylsilylmethyllithium 664\u003c\/p\u003e \u003cp\u003eTrimethylsilylmethylmagnesium Chloride 666\u003c\/p\u003e \u003cp\u003eTrimethylsilylmethylpotassium 674\u003c\/p\u003e \u003cp\u003e2-Trimethylsilylmethyl-2-propen-1-ol 675\u003c\/p\u003e \u003cp\u003e1-Trimethylsilyloxy-1,3-butadiene 677\u003c\/p\u003e \u003cp\u003e2-Trimethylsilyloxy-1,3-butadiene 681\u003c\/p\u003e \u003cp\u003e2-Trimethylsilyloxyfuran 684\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eZ\u003c\/i\u003e)-2-(Trimethylsilyloxy)vinyllithium 693\u003c\/p\u003e \u003cp\u003e5-Trimethylsilyl-1,3-pentadiene 695\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)phenyl Triflate 697\u003c\/p\u003e \u003cp\u003eTrimethylsilylpotassium 700\u003c\/p\u003e \u003cp\u003e2-Trimethylsilyl-1,3-propanediol 701\u003c\/p\u003e \u003cp\u003e3-Trimethylsilyl-2-propen-1-yl Acetate 703\u003c\/p\u003e \u003cp\u003e3-Trimethylsilyl-1-propyne 704\u003c\/p\u003e \u003cp\u003e3-Trimethylsilyl-2-propynylcopper(I) 711\u003c\/p\u003e \u003cp\u003e2-(Trimethylsilyl)thiazole 712\u003c\/p\u003e \u003cp\u003eTrimethylsilyltributylstannane 719\u003c\/p\u003e \u003cp\u003e3-Trimethylsilyl-3-trimethylsilyloxy-1-propene 723\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-1-Trimethylsilyl-2-trimethylstannylethylene 724\u003c\/p\u003e \u003cp\u003e(Trimethylsilyl)vinylketene 725\u003c\/p\u003e \u003cp\u003e1-(Trimethylsilyl)vinyllithium 726\u003c\/p\u003e \u003cp\u003e(\u003ci\u003eE\u003c\/i\u003e)-2-(Trimethylsilyl)vinyllithium 729\u003c\/p\u003e \u003cp\u003e1-(Trimethylsilyl)vinylmagnesium Bromide–Copper(I) Iodide 730\u003c\/p\u003e \u003cp\u003eTrimethyl{2-[(tributylstannyl)methyl]-2-propenyl}silane 731\u003c\/p\u003e \u003cp\u003eTriphenylsilane 733\u003c\/p\u003e \u003cp\u003eTris(dimethylamino)sulfonium Difluorotrimethylsilicate 739\u003c\/p\u003e \u003cp\u003eTris(trimethylsilyl)aluminum 745\u003c\/p\u003e \u003cp\u003eTris(trimethylsilyl)methane 746\u003c\/p\u003e \u003cp\u003eTris(trimethylsilyl)silane 747\u003c\/p\u003e \u003cp\u003eVinyltrimethylsilane 755\u003c\/p\u003e \u003cp\u003e\u003cb\u003eList of Contributors 763\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eReagent Formula Index 779\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eSubject Index 785\u003c\/b\u003e ???\u003c\/p\u003e  \u003cp\u003e\u003cstrong\u003ePhilip Fuchs\u003c\/strong\u003e began his career at Purdue in 1973. Since that time, he has graduated an extended family of 55 Ph.D.s. His awards and honors include an Eli Lilly young faculty fellowship (1975), an Alfred P. Sloan fellowship (1977), a Pioneer in Laboratory Robotics award (1986), a Martin teaching award (1991), and being voted by the students as one of Top 10 Teachers in School of Science at Purdue (1991, 1993, 1995, 1996).\u003cbr\u003eFuchs has consulted for Pfizer, and Eli Lilly, served on the editorial board of \u003cem\u003eThe Journal of Organic Chemistry\u003c\/em\u003e, and is currently an executive editor for the \u003cem\u003eElectronic Encyclopedia of Organic Reagents (e-EROS)\u003c\/em\u003e, an online dynamic encyclopedia published by John Wiley \u0026amp; Sons.  \u003cb\u003eReagents for Silicon-Mediated Organic Synthesis\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eSilicon reagents are usually low-cost, versatile and allow a wide range of reactions. For the selection the Editor focused on three key synthetic approaches with the greatest impact:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eUse of silicon as a \u003ci\u003e“temporary tether”\u003c\/i\u003e by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization\u003c\/li\u003e \u003cli\u003eThe specific use if the silane functionality as a hetro t-butyl group, often colloquially referred to as the use of silicon as a “fat proton”.\u003c\/li\u003e \u003cli\u003eThe use of the Brook rearrangement as an \u003ci\u003e“anion relay stratagem”.\u003c\/i\u003e A new feature in this Handbook is the reagent finder, and alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eAll the information compiled in this volume is also available in electronic format on Wiley Online Library. \u003ci\u003eThe electronicEncyclopedia of Reagents for Organic Synthesis\u003c\/i\u003e (e-EROS) includes all the reagents described in this volume plus many more reagents of other types and for other uses. e-EROS allows for text and structure search and has many new and updated entries added every year.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989921120485,"sku":"NP9780470710234","price":153.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780470710234.jpg?v=1761785915","url":"https:\/\/k12savings.com\/products\/reagents-for-silicon-mediated-organic-synthesis-isbn-9780470710234","provider":"K12savings","version":"1.0","type":"link"}