{"product_id":"photochemically-generated-intermediates-in-synthesis-isbn-9780470915349","title":"Photochemically-Generated Intermediates in Synthesis","description":"\u003cp\u003e\u003cb\u003eExamines the latest applications of photochemistry to generate important intermediates\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003ePresenting the latest breakthroughs in the field of organic photochemistry, this book offers tested and proven photochemical approaches to synthesis, creating promising new possibilities and applications for photochemical reactions. It focuses on photoreactions involving an intermediate where mechanistic aspects control the course of the reaction and its synthetic value. Readers will discover new insights into the mechanisms and nature of photo-produced reactive intermediates for organic synthesis as well as the methods to generate them. Moreover, by focusing on highly efficient techniques for producing such species, the authors enable researchers to design and perform photoreactions within the framework of green, sustainable chemistry.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePhotochemically-Generated Intermediates in Synthesis\u003c\/i\u003e begins with a discussion of the principles and practice of photo-generated intermediates. Next, the book explores:\u003c\/p\u003e \u003cul\u003e \u003cli\u003ePhotogeneration of carbon-centered radicals\u003c\/li\u003e \u003cli\u003ePhotogeneration of heteroatom-centered radicals\u003c\/li\u003e \u003cli\u003ePhotogeneration of biradicals and radical pairs\u003c\/li\u003e \u003cli\u003ePhotochemical generation of radical ions\u003c\/li\u003e \u003cli\u003ePhotogeneration of carbocations and carbanions\u003c\/li\u003e \u003cli\u003ePhotogeneration of carbenes and nitrenes\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThe book's final chapter is dedicated to the photochemical manipulation of intermediates. Each chapter includes key kinetic data for typical intermediates as well as detailed case examples, giving readers all the tools needed to perform their own photochemical reactions. Comparisons to non-photochemical methods are offered whenever possible.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePhotochemically-Generated Intermediates in Synthesis\u003c\/i\u003e sets the stage for greater collaboration among photochemists and synthetic organic chemists, enabling these two research communities to fully leverage photochemistry in order to generate key intermediates needed for a broad range of synthetic reactions in organic chemistry.\u003c\/p\u003e \u003cp\u003ePreface vii\u003c\/p\u003e \u003cp\u003e1 Photogenerated Intermediates: Principles and Practice 1\u003c\/p\u003e \u003cp\u003e2 Photogeneration of Carbon-Centered Radicals 41\u003c\/p\u003e \u003cp\u003e3 Photogeneration of Heteroatom-Centered Radicals 91\u003c\/p\u003e \u003cp\u003e4 Photogeneration of Biradicals and Radical Pairs 131\u003c\/p\u003e \u003cp\u003e5 Photochemical Generation of Radical Ions 168\u003c\/p\u003e \u003cp\u003e6 Photogeneration of Carbocations and Carbanions 260\u003c\/p\u003e \u003cp\u003e7 Photogeneration of Carbenes and Nitrenes 302\u003c\/p\u003e \u003cp\u003e8 Manipulating Intermediates the Photochemical Way 328\u003c\/p\u003e \u003cp\u003eIndex 365\u003c\/p\u003e  \u003cp\u003e“In summary, this book provides a new and interesting perspective on this highly topical field of organic photochemistry, and it is strongly recommended as a source of motivation for all potential users.”  (\u003ci\u003eAngew. Chem. Int. Ed\u003c\/i\u003e, 1 May 2014)\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eANGELO ALBINI\u003c\/b\u003e is Professor of Organic Chemistry at the University of Pavia. His scientific investigations focus on many aspects of organic photochemistry. In addition to publishing original research articles, he has coauthored or edited three books, including \u003ci\u003eHandbook of Synthetic Photochemistry\u003c\/i\u003e (Wiley). Dr. Albini is the recipient of the Federchimica Prize, awarded for creativity in chemistry.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eMAURIZIO FAGNONI, PhD,\u003c\/b\u003e is Associate Professor of Chemistry at the University of Pavia. His research emphasizes the application of photochemistry to sustainable organic synthesis, encompassing photocatalysis and phenyl cation chemistry. Dr. Fagnoni coedited \u003ci\u003eHandbook of Synthetic Photochemistry\u003c\/i\u003e (Wiley) and is the recipient of the Exploration of New Research Frontiers Award from Cariplo Foundation.\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eExamines the latest applications of photochemistry to generate important intermediates\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003ePresenting the latest breakthroughs in the field of organic photochemistry, this book offers tested and proven photochemical approaches to synthesis, creating promising new possibilities and applications for photochemical reactions. It focuses on photoreactions involving an intermediate where mechanistic aspects control the course of the reaction and its synthetic value. Readers will discover new insights into the mechanisms and nature of photo-produced reactive intermediates for organic synthesis as well as the methods to generate them. Moreover, by focusing on highly efficient techniques for producing such species, the authors enable researchers to design and perform photoreactions within the framework of green, sustainable chemistry.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePhotochemically-Generated Intermediates in Synthesis\u003c\/i\u003e begins with a discussion of the principles and practice of photo-generated intermediates. Next, the book explores:\u003c\/p\u003e \u003cul\u003e \u003cli\u003ePhotogeneration of carbon-centered radicals\u003c\/li\u003e \u003cli\u003ePhotogeneration of heteroatom-centered radicals\u003c\/li\u003e \u003cli\u003ePhotogeneration of biradicals and radical pairs\u003c\/li\u003e \u003cli\u003ePhotochemical generation of radical ions\u003c\/li\u003e \u003cli\u003ePhotogeneration of carbocations and carbanions\u003c\/li\u003e \u003cli\u003ePhotogeneration of carbenes and nitrenes\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThe book's final chapter is dedicated to the photochemical manipulation of intermediates. Each chapter includes key kinetic data for typical intermediates as well as detailed case examples, giving readers all the tools needed to perform their own photochemical reactions. Comparisons to non-photochemical methods are offered whenever possible.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePhotochemically-Generated Intermediates in Synthesis\u003c\/i\u003e sets the stage for greater collaboration among photochemists and synthetic organic chemists, enabling these two research communities to fully leverage photochemistry in order to generate key intermediates needed for a broad range of synthetic reactions in organic chemistry.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989783855333,"sku":"NP9780470915349","price":179.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780470915349.jpg?v=1761785452","url":"https:\/\/k12savings.com\/products\/photochemically-generated-intermediates-in-synthesis-isbn-9780470915349","provider":"K12savings","version":"1.0","type":"link"}