{"product_id":"organic-syntheses-volume-87-isbn-9781118005149","title":"Organic Syntheses, Volume 87","description":"Organic syntheses consists of protocols for the synthesis of useful chemical compounds. \u003ci\u003eOrganic Syntheses, Volume 87\u003c\/i\u003e provides carefully checked and edited experimental protocols that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated utility in organic synthesis. For each protocol, safety warnings are presented along with detailed experimental descriptions for the preparation, purification, and identification of the compound. Additionally, special reaction conditions are also detailed. This current volume continues the tradition of providing significant and interesting procedures for synthetic chemists working in increasingly diverse areas.  \u003cp\u003eMetal-Free One-Pot Oxidative Amination of Aromatic Aldehydes: Conversion of Benzaldehyde to N-Benzoyl Pyrrolidine 1\u003cbr\u003e \u003ci\u003eKekeli Ekoue-Kovi and Christian Wolf\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eA Practical and Scalable Synthesis of N-Halo Compounds: 2-Chloro-6,7-Dimethoxy-1,2,3,4-Tetrahydroisoquinoline 8\u003cbr\u003e \u003ci\u003eYong-Li Zhong and Paul G. Bulger\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eRegioselective C-4 Bromination of Oxazoles: 4-Bromo-5-(Thiophen-2-YL) Oxazole 16\u003cbr\u003e \u003ci\u003eBryan Li, Richard A. Buzon, and Zhijun Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Spiroborate Esters from 1,2-Aminoalcohols, Ethylene Glycol and Triisopropyl Borate: Preparation of (S)-1-(1,3,2-Dioxaborolan-2-Yloxy)-3-Methyl-1,1-Diphenylbutan-2-Amine 26\u003cbr\u003e \u003ci\u003eViatcheslav Stepanenko, Kun Huang and Margarita Ortiz-Marciales\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eCatalytic Enantioselective Borane Reduction of Benzyl Oximes: Preparation of (S)-1-Pyridin-3-YL-Ethylamine BIS Hydrochloride 36\u003cbr\u003e \u003ci\u003eKun Huang and Margarita Ortiz-Marciales\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eStereoselective Synthesis of 3-Arylacrylates by Copper-Catalyzed Syn Hydroarylation 53\u003cbr\u003e \u003ci\u003eNaohiro Kirai and Yoshihiko Yamamoto\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation of (S)-3,3’-BIS-Morpholinomethyl-5,5’,6,6’,7,7’,8,8’-Octahydro-1,1’-BI-2-Naphthol 59\u003cbr\u003e \u003ci\u003eMark Turlington and Lin Pu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eCatalytic Asymmetric Addition of an In-Situ Prepared Arylzinc to Cyclohexanecarboxaldehyde: (R)-(+)-α-Cyclohexyl-3-Methoxy-Benzenemethanol 68\u003cbr\u003e \u003ci\u003eAlbert M. DeBerardinis, Mark Turlington, and Lin Pu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eMicrowave-Assisted Synthesis of 1,3-Dimesitylimidazolinium Chloride 77\u003cbr\u003e \u003ci\u003eMorgan Hans and Lionel Delaude\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of (3-Chlorobutyl)Benzene by the Cobalt-Catalyzed Hydrochlorination of 4-Phenyl-1-Butene 88\u003cbr\u003e \u003ci\u003eBoris Gaspar, Jerome Waser, and Erick M. Carreira\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Substituted Indazoles via (3+2) Cycloaddition of Benzyne and Diazo Compounds 95\u003cbr\u003e \u003ci\u003eFeng Shi and Richard C. Larock\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePalladium-Catalyzed Cross-Coupling Using an Air-Stable Trimethylaluminum Source. Preparation of Ethyl 4-Methylbenzoate 104\u003cbr\u003e \u003ci\u003eAndrej Vinogradov and Simon Woodward\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Dimethyl 2-Phenycyclopropane-1,1-Dicarboxylate Using an Iodonium Ylide Derived from Dimethyl Malonate 115\u003cbr\u003e \u003ci\u003eSébastien R. Goudreau, David Marcoux and Andre B. Charette\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eNew, Convenient Route for Trifluoromethylation of Steroidal Molecules 126\u003cbr\u003e \u003ci\u003eXiang-Shu Fei, Wei-Sheng Tian, Kai Ding, Yun Wang and Qing-Yun Chen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation of Ethyl 1-Benzyl-4-Fluoropiperidine-4-Carboxylate 137\u003cbr\u003e \u003ci\u003eJianshe Kong, Tao Meng, Pauline Ting, and Jesse Wong\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eLithium Amides as Homochiral Ammonia Equivalents for Conjugate Additions to α,ß-Unsaturated Esters: Asymmetric Synthesis of (S)-ß-Leucine 143\u003cbr\u003e \u003ci\u003eStephen G. Davies, Ai M. Fletcher, and Paul M. Roberts\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eCyclohexene Imine (7-Aza-Bicyclo[4.1.0]Heptane) 161\u003cbr\u003e \u003ci\u003eIain D. G. Watson, Nicholas Afagh and Andrei K. Yudin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation of (E)-(2-Iodovinyl)Benzene From Benzyl Bromide and Diiodomethane 170\u003cbr\u003e \u003ci\u003eJames A. Bull, James J. Mousseau and André B. Charette\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Tetraorganosilanes: (Chloromethyl)Dimethylphenylsilane 178\u003cbr\u003e Submitted by \u003ci\u003eKei Murakami, Hideki Yorimitsu, and Koichiro Oshima\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eA General Method for Copper-Catalyzed Arylation of Acidic Arene C-H Bonds. Preparation of 2-Chloro-5-(3-Methylphenyl)-Thiophene 184\u003cbr\u003e \u003ci\u003eJoseph Alvarado, Hien-Quang Do, and Olafs Daugulis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1,3,5-Triacetylbenzene 192\u003cbr\u003e \u003ci\u003ePeter J. Alaimo, Amanda-Lynn Marshall, David M. Andrews and Joseph M. Langenhan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eOrganocatalytic α-Methylenation of Aldehydes: Preparation of 3,7-Dimethyl-2-Methylene-6-Octenal 201\u003cbr\u003e \u003ci\u003eMeryem Benohoud, Anniina Erkkilä, and Petri M. Pihko\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eRuthenium-Catalyzed Arylation of Ortho C-H Bond in an Aromatic with an Arylboronate: 8-Phenyl-1-Tetralone 209\u003cbr\u003e \u003ci\u003eKentaroh Kitazawa, Takuya Kochi, and Fumitoshi Kakiuchi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eAmide Formation by Decarboxylative Condensation of Hydroxylamines and α-Ketoacids: N-[(1S)-1 Phenylethyl]-Benzeneacetamide 218\u003cbr\u003e \u003ci\u003eLei Ju and Jeffrey W. Bode\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eOne-Pot Diazotization and Heck Reaction of Methyl Anthranilate: 2-(3-Oxopropyl) Benzoic Acid Methyl Ester 226\u003cbr\u003e \u003ci\u003eFlorencio Zaragoza\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Ynamides by Copper-Mediated Coupling of 1,1-Dibromo-1-Alkenes with Nitrogen Nucleophiles. Preparation of 4-Methyl-N-(2-Phenylethynyl)-N-(Phenylmethyl)Benzenesulfonamide 231\u003cbr\u003e \u003ci\u003eAlexis Coste, François Couty and Gwilherm Evano\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eDirect Fluorination of the Carbonyl Group of Benzophenones Using Deoxo-Fluor®: Preparation of BIS(4-Fluorophenyl) Difluoromethane 245\u003cbr\u003e \u003ci\u003eYing Chang, Hyelee Lee, Chulsung Bae\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation and [2+2] Cycloaddition of 1-Triisopropylsiloxy-1-Hexyne with Methyl Crotonate: 3-Butyl-4-Methyl-2-Triisopropylsiloxy-Cyclobut-2-Enecarboxylic Acid Methyl Ester 253\u003cbr\u003e \u003ci\u003eValeriy Shubinets, Michael P. Schramm, and Sergey A. Kozmin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePd(0)-Catalyzed Asymmetric Allylic and Homoallylic Diamination of 4-Phenyl-1-Butene with DI-Tert-Butyldiaziridinone 263\u003cbr\u003e \u003ci\u003eBaoguo Zhao, Haifeng Du, Renzhong Fu, and Yian Shi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Enamides from Ketones: Preparation of N-(3,4-Dihydronaphthalene-1-YL)Acetamide 275\u003cbr\u003e \u003ci\u003eHang Zhao, Charles P. Vandenbossche, Stefan G. Koenig, Surendra P. Singh, and Roger P. Bakale\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSafe and Scalable Preparation of Barluenga’s Reagent 288\u003cbr\u003e \u003ci\u003eJustin M. Chalker, Amber L. Thompson, and Benjamin G. Davis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePalladium-Catalyzed Alkyl-Alkyl Suzuki Cross-Couplings of Primary Alkyl Bromides at Room Temperature: (13-Chlorotridecyloxy)Triethylsilane 299\u003cbr\u003e \u003ci\u003eSha Lou and Gregory C. Fu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of Chiral Pyridine Bis(Oxazoline) Ligands for Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary allylic Chlorides with Alkylzincs:2,6-BIS[(4R)-4,5-Dihydro-4-(2-Phenylethyl)-2-Oxazolyl]-Pyridine 310\u003cbr\u003e \u003ci\u003eSha Lou and Gregory C. Fu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eNickel-Catalyzed Asymetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs: (S,E)-Ethyl 6-(1,3-Dioxolan-2-YL)-4-Methylhex-2-Enoate 317\u003cbr\u003e \u003ci\u003eSha Lou and Gregory C. Fu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eNickel-Catalyzed Enantioselective Negishi Cross-Couplings of Racemic Secondary a-Bromo Amides with Alkylzinc Reagents: (s)-N-Benzyl-7-Cyano-2-Ethyl-N-Phenylheptanamide 330\u003cbr\u003e \u003ci\u003eSha Lou and Gregory C. Fu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eOne-Pot Synthesis of 5H-Indazolo-[3,2-b] Benzo[d]-1,3-Oxazine: Two Efficient Preparative Methods 339\u003cbr\u003e \u003ci\u003eDanielle M. Solano, Jeffrey D. Butler, Makhluf J. Haddadin and Mark J. Kurth\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation of Chiral and Achiral Triazolium Salts: Carbene Precursors with Demonstrated Synthesis Utility 350\u003cbr\u003e \u003ci\u003eHarit U. Vora, Stephen P. Lathrop, Nathan T. Reynolds, Mark S. kerr, Javier Read de Alaniz, and Tomislav Rovis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eSynthesis of A N-Mesityl Substituted Aminoindanol-Derived Triazolium Salt 362\u003cbr\u003e \u003ci\u003eJustin R. Struble and Jeffrey W. Bode\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003ePreparation of O-Allyl-N-(9-Anthracenyl-Methyl)-Cinchonidium Bromide as a Phase Transfer Catalyst 377\u003cbr\u003e E. J. Corey and Mark C. Noe\u003c\/p\u003e  \"Organic Syntheses, Volume 87 provides carefully checked and edited experimental protocols that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated uitlity in organic synthesis.\" (Book Circle, 1 September 2011)  \u003cp\u003e \u003c\/p\u003e  \u003cp\u003e\u003cstrong\u003ePeter Wipf\u003c\/strong\u003e is the Director of the Combinatorial Chemistry Center (CCC) and the Center for Chemical Methodologies and Library Development (UPCMLD) which are involved in many collaborative projects in Chemical Biology. He is also a founding member of the Center for Medical Countermeasures Against Radiation (CMCR) and the University of Pittsburgh Center for Chemical Diversity (UPCDC). He has served on the organizing committee of several conferences and workshops, including the NSF Workshop on Organic Synthesis. He is a member of several editorial boards, including Medicinal Chemistry Letters (ACS MCL), Organic Reactions (OR), and Organic Syntheses (OS).\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989733884133,"sku":"NP9781118005149","price":96.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781118005149.jpg?v=1761785293","url":"https:\/\/k12savings.com\/products\/organic-syntheses-volume-87-isbn-9781118005149","provider":"K12savings","version":"1.0","type":"link"}