{"product_id":"mossbauer-spectroscopy-isbn-9781118057247","title":"Mössbauer Spectroscopy","description":"Providing a modern update of the field, \u003ci\u003eMossbauer Spectroscopy\u003c\/i\u003e focuses on applications across a broad range of fields, including analysis of inorganic elements, nanoparticles, metalloenzymyes, biomolecules (including proteins), glass, coal, and iron. Ideal for a broad range of scientists, this one-stop reference presents advances gained in the field over past two decades, including a detailed theoretical description of Mossbauer spectroscopy, an extensive treatment of Mossbauer spectroscopy in applied areas, and challenges and future opportunities for the further development of this technique.  \u003cp\u003e\u003ci\u003ePreface xix\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eContributors xxi\u003c\/i\u003e\u003cbr\u003e \u003cb\u003e\u003cbr\u003e Chapter 1\u003c\/b\u003e \u003cb\u003e\u003ca id=\"OLE_LINK2\" name=\"OLE_LINK2\"\u003e\u003c\/a\u003eIn-Situ Mössbauer Spectroscopy with Synchrotron Radiation on Thin Films 3\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eS Stankov, T Ślęzak, M Zając, M Ślęzak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J Łażewski, K Parliński, and J Korecki\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1 1 Introduction 3\u003c\/p\u003e \u003cp\u003e1.2 Instrumentation 4\u003c\/p\u003e \u003cp\u003e1.3 Synchrotron radiation-based Mössbauer techniques 10\u003c\/p\u003e \u003cp\u003eReferences 39\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth’s Lower Mantle 43\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJung-Fu Lin, Zhu Mao, and Ercan E Alp\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 43\u003c\/p\u003e \u003cp\u003e2.2 Synchrotron Mössbauer Spectroscopy at High Pressures and Temperatures 44\u003c\/p\u003e \u003cp\u003e2.3 Crystal Field Theory on the 3\u003ci\u003ed\u003c\/i\u003e Electronic States 46\u003c\/p\u003e \u003cp\u003e2.4 Conclusion 54\u003c\/p\u003e \u003cp\u003eAcknowledgments 55\u003c\/p\u003e \u003cp\u003eReferences 55\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3 In-beam Mössbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eYoshio Kobayashi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 I\u003ci\u003entroduction 58\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.2 57Mn (→ \u003csup\u003e57\u003c\/sup\u003eFe) Implantation Mössbauer Spectroscopy 61\u003c\/p\u003e \u003cp\u003e3.3 Neutron in-beam Mössbauer Spectroscopy 66\u003c\/p\u003e \u003cp\u003e3 .4 Summary 66\u003c\/p\u003e \u003cp\u003eReferences 67\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart II Radionuclides 71\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4 Lanthanides(\u003csup\u003e151\u003c\/sup\u003eEu and \u003csup\u003e155\u003c\/sup\u003eGd)-Mössbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eNakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 73\u003c\/p\u003e \u003cp\u003e4.2 Defect-crystal-Chemistry (DCC) Lattice-parameter Model 76\u003c\/p\u003e \u003cp\u003e4.3 Lns Mössbauer and Lattice-parameter Data of DF Oxides 79\u003c\/p\u003e \u003cp\u003e4.4 DCC-Model Lattice-parameter and Lns-Mössbauer Data Analysis 84\u003c\/p\u003e \u003cp\u003eConclusion 92\u003c\/p\u003e \u003cp\u003eReferences 93\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 95\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eT Nakamoto, A Nakamura and M Takeda\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 95\u003c\/p\u003e \u003cp\u003e5.2 237Np Mössbauer Spectroscopy 96\u003c\/p\u003e \u003cp\u003e5.3 Magnetic Property of Neptunyl Monocation (NpO\u003csub\u003e2\u003c\/sub\u003e\u003csup\u003e+\u003c\/sup\u003e) 97\u003c\/p\u003e \u003cp\u003e5.4 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 98\u003c\/p\u003e \u003cp\u003e5.5 Discussion 106\u003c\/p\u003e \u003cp\u003eConclusion 113\u003c\/p\u003e \u003cp\u003eAcknowledgment 113\u003c\/p\u003e \u003cp\u003eReferences 113\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 6\u003c\/b\u003e \u003cb\u003eMössbauer Spectroscopy of \u003csup\u003e161\u003c\/sup\u003eDy in Dysprosium Dicarboxylates 116\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eM Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless,\u003c\/i\u003e \u003ci\u003eLeopold May, T Misu, S G Sobel, M Takeda, and E Brown\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 116\u003c\/p\u003e \u003cp\u003e6.2 Experimental Methods 117\u003c\/p\u003e \u003cp\u003e6.3 Results and Discussion 117\u003c\/p\u003e \u003cp\u003eAcknowledgment 122\u003c\/p\u003e \u003cp\u003eReferences 122\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 7 Study of Exotic Uranium Compounds using \u003csup\u003e238\u003c\/sup\u003eU Mössbauer Spectroscopy 123\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eSatoshi Tsutsui\u003csup\u003e1,2\u003c\/sup\u003eand Masami Nakada\u003csup\u003e2\u003c\/sup\u003e\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 123\u003c\/p\u003e \u003cp\u003e7.2 Determination of Nuclear \u003ci\u003eg\u003c\/i\u003e-factor in the Excited State of \u003csup\u003e238\u003c\/sup\u003eU Nuclei 125\u003c\/p\u003e \u003cp\u003e7.3 Application of \u003csup\u003e238\u003c\/sup\u003eU Mössbauer Spectroscopy to Heavy Fermion 127\u003c\/p\u003e \u003cp\u003e7.4 Application to Two-dimensional (2D) Fermi Surface System of Uranium Dipnictides 134\u003c\/p\u003e \u003cp\u003eSummary 137\u003c\/p\u003e \u003cp\u003eAcknowledgment 138\u003c\/p\u003e \u003cp\u003eReferences 138\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart III\u003c\/b\u003e \u003cb\u003eSpin Dynamics 141\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 8 Reversible Spin-state Switching Involving a Structural Change 143\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eSatoru Nakashima\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 143\u003c\/p\u003e \u003cp\u003e8.2 Three Assembled Structures of Fe(NCX)\u003csub\u003e2\u003c\/sub\u003e(bpa)\u003csub\u003e2\u003c\/sub\u003e (X=S, Se) and Their Structural Change by Desorption of Propanol Molecules 144\u003c\/p\u003e \u003cp\u003e8.3 Occurrence of Spin-crossover Phenomenon in Assembled Complexes Fe(NCX)\u003csub\u003e2\u003c\/sub\u003e(bpa)\u003csub\u003e2\u003c\/sub\u003e (X=S, Se, BH\u003csub\u003e3\u003c\/sub\u003e) by Enclathrating Guest Molecules 145\u003c\/p\u003e \u003cp\u003e8.4 Reversible Structural Change of Host Framework of Fe(NCS)\u003csub\u003e2\u003c\/sub\u003e(bpp)\u003csub\u003e2\u003c\/sub\u003e•2(benzene) Triggered By Sorption of Benzene Molecules 147\u003c\/p\u003e \u003cp\u003e8.5 Reversible Spin-state Switching Involving a Structural Change of Fe(NCX)\u003csub\u003e2\u003c\/sub\u003e(bpp)\u003csub\u003e2\u003c\/sub\u003e•2(benzene) (X=Se, BH\u003csub\u003e3\u003c\/sub\u003e) Triggered By Sorption of Benzene Molecules 149\u003c\/p\u003e \u003cp\u003e8.6 Conclusion 150\u003c\/p\u003e \u003cp\u003eReferences 151\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge\u003c\/b\u003e\u003cbr\u003e \u003ci\u003e\u003cb\u003e152\u003c\/b\u003e\u003cbr\u003e N Kokima and A Sugahara\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 152\u003c\/p\u003e \u003cp\u003e9.2 Photo-induced Spin-crossover Phenomena 153\u003c\/p\u003e \u003cp\u003e9 3 Charge Transfer Phase Transition 161\u003c\/p\u003e \u003cp\u003e9 4 Spin Equilibrium and Succeeding Phenomena 168\u003c\/p\u003e \u003cp\u003eReferences 175\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State 177\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eMikio Nakamura and Masashi Takahashi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 177\u003c\/p\u003e \u003cp\u003e10.2 Methodology to Obtain Pure Intermediate-Spin Complexes 178\u003c\/p\u003e \u003cp\u003e10.3 Spin Crossover Involving the Intermediate-Spin State 189\u003c\/p\u003e \u003cp\u003e10.4 Spin Crossover Triangle in Iron(III) Porphyrins 195\u003c\/p\u003e \u003cp\u003e10.5 Conclusion 198\u003c\/p\u003e \u003cp\u003eAcknowledgments 198\u003c\/p\u003e \u003cp\u003eReferences 199\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mössbauer Spectroscopic Properties 202\u003cbr\u003e \u003c\/b\u003eGeorges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar\u003c\/p\u003e \u003cp\u003e11.1 Introduction  202\u003c\/p\u003e \u003cp\u003e11.2 Experimental 203\u003c\/p\u003e \u003cp\u003e11.3 Crystal Structures 204\u003c\/p\u003e \u003cp\u003e11.4 Tin Electronic Structure and Mössbauer Spectroscopy 208\u003c\/p\u003e \u003cp\u003e11.5 Application to the Structural Determination of α−SnF\u003csub\u003e2\u003c\/sub\u003e 213\u003csub\u003e     \u003c\/sub\u003e\u003c\/p\u003e \u003cp\u003e11.6 Application to the Structural Determination of the Highly Layered Structures of α−PbSnF\u003csub\u003e4\u003c\/sub\u003e and BaSnF\u003csub\u003e4\u003cbr\u003e \u003c\/sub\u003e216\u003c\/p\u003e \u003cp\u003e11.7 Application to the Structural Study of Disordered Phases 226\u003c\/p\u003e \u003cp\u003e11.8 Lone Pair Stereoactivity and Material Properties 241\u003c\/p\u003e \u003cp\u003e11.9 Conclusion 242\u003c\/p\u003e \u003cp\u003eAcknowledgments 243\u003c\/p\u003e \u003cp\u003eReferences 243\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart IV Biological Applications 247\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry 249\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eYisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 249\u003c\/p\u003e \u003cp\u003e12.2 Technical Background 250\u003c\/p\u003e \u003cp\u003e12.3 Applications in Bioinorganic Chemistry 258\u003c\/p\u003e \u003cp\u003e12.4 Summary and Prospects 269\u003c\/p\u003e \u003cp\u003eAcknowledgment 269\u003c\/p\u003e \u003cp\u003eReferences 269\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research 272\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eAlexander A Kamnev\u003csup\u003e1,\u003c\/sup\u003e*, Krisztina Kovács\u003csup\u003e2\u003c\/sup\u003e, Irina V Alenkina\u003csup\u003e3\u003c\/sup\u003e, and Michael I. Oshtrakh\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 272\u003c\/p\u003e \u003cp\u003e13.2 Microorganisms-related studies 273\u003c\/p\u003e \u003cp\u003e13.3 Plants 276\u003c\/p\u003e \u003cp\u003e13.4 Enzymes 280\u003c\/p\u003e \u003cp\u003e13.5 Hemogoblin 281\u003c\/p\u003e \u003cp\u003e13.6 Ferritin and Hemosiderin 283\u003c\/p\u003e \u003cp\u003e13.7 Tissues 284\u003c\/p\u003e \u003cp\u003e13.8 Pharmaceutical Products 286\u003c\/p\u003e \u003cp\u003e13.9 Conclusions 286\u003c\/p\u003e \u003cp\u003eAcknowledgments 287\u003c\/p\u003e \u003cp\u003eReferences 287\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292\u003cbr\u003e \u003c\/b\u003eVladimir I Vysotskii and Alla A Kornilova\u003c\/p\u003e \u003cp\u003e14.1 Introduction to the Problem of Controlled Spontaneous Gamma-decay 292\u003c\/p\u003e \u003cp\u003e14.2 General Consideration 293\u003c\/p\u003e \u003cp\u003e14.3 Controlled Spontaneous Gamma-decay of Excited Nucleus in the System of Mutually Uncorrelated Modes of Electromagnetic Vacuum 295\u003c\/p\u003e \u003cp\u003e14.4 Spontaneous Gamma-decay in the System of Synchronized Modes of Electromagnetic Vacuum 302\u003c\/p\u003e \u003cp\u003e14.5 Experimental Study of the Phenomenon of Controlled Gamma-decay of Mossbauer Nuclei 303\u003c\/p\u003e \u003cp\u003e14.6 Experimental Study of the Phenomenon of Controlled Gamma-decay by Investigation of Space Anisotropy and Self-focusing of Mossbauer Radiation 309\u003c\/p\u003e \u003cp\u003e14.7 Direct Experimental Observation and Study of the Process of Controlled Radioactive and Excited Nuclei Radiative Gamma-decay by the Delayed Gamma-gamma Coincidence Method 311\u003c\/p\u003e \u003cp\u003e14.8 Conclusion 314\u003c\/p\u003e \u003cp\u003eReferences 314\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 15 Natural's Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates 315\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eKednerlin Dornevil and Aimin Liu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Two Oxidizing Equivalents Stored at a Ferric Heme 315\u003c\/p\u003e \u003cp\u003e15.2 Oxidation of L-Tryptophan by Heme-Based Enzymes 316\u003c\/p\u003e \u003cp\u003e15.3 The Chemical Reaction Catalyzed by MauG 318\u003c\/p\u003e \u003cp\u003e15.4 A High-Valent \u003ci\u003ebis\u003c\/i\u003e-Fe(IV) Intermediate in MauG 319\u003c\/p\u003e \u003cp\u003e15.5 High-Valent Fe Intermediate of Tryptophan 2,3-Dioxygenase 319\u003c\/p\u003e \u003cp\u003e15.6 Concluding Remarks 321\u003c\/p\u003e \u003cp\u003eReferences 322\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 16 Iron in Neurodegeneration 324\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eJolanta Gałązka-Friedman, Erika R Bauminger, and Andrzej Friedman\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 324\u003c\/p\u003e \u003cp\u003e16.2 Neurodegeneration and Oxidative Stress 324\u003c\/p\u003e \u003cp\u003e16.3 Mössbauer Studies of Healthy Brain Tissue 325\u003c\/p\u003e \u003cp\u003e16.4 Properties of Ferritin and Hemosiderin Present in Healthy Brain Tissue 327\u003c\/p\u003e \u003cp\u003e16.5 Concentration of Iron Present in Healthy and Diseased Brain Issue 328\u003c\/p\u003e \u003cp\u003e16.6 Asymmetry of the Mössbauer Spectra of Healthy and Diseased Brain Tissue 330\u003c\/p\u003e \u003cp\u003e16.7 Conclusion – the Possible Role of Iron in Neurodegeneration 331\u003c\/p\u003e \u003cp\u003eReferences 331\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 17 Emission (\u003csup\u003e57\u003c\/sup\u003eCo) Mössbauer Spectroscopy: Biology-related Applications, Potentials and Prospects 333\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eAlexander A Kamnev\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 333\u003c\/p\u003e \u003cp\u003e17.2 Methodology 334\u003c\/p\u003e \u003cp\u003e17.3 Microbiological Applications 336\u003c\/p\u003e \u003cp\u003e17.4 Enzymological Applications 340\u003c\/p\u003e \u003cp\u003e17.5 Conclusions and Outlook 345\u003c\/p\u003e \u003cp\u003eAcknowledgments 345\u003c\/p\u003e \u003cp\u003eReferences 346\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart V Iron Oxides 349\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes 351\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJiří Tuček, Libor Machala, Jiří Frydrych, Jiří Pechoušek, and Radek Zbořil\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 351\u003c\/p\u003e \u003cp\u003e18.2 Polymorphs of Iron (III) Oxide, Their Crystal Structures, Magnetic Properties, and Polymorphous Phase Transformations 352\u003c\/p\u003e \u003cp\u003e18.3 Use of \u003csup\u003e57\u003c\/sup\u003eFe Mössbauer Spectroscopy in Monitoring Solid State Reaction Mechanisms towards Iron Oxides 371\u003c\/p\u003e \u003cp\u003e18.4 Various Mössbauer Spectroscopy Techniques in Study of Applications Related to Nanocrystalline Iron Oxides 378\u003c\/p\u003e \u003cp\u003e18.5 Conclusion 389\u003c\/p\u003e \u003cp\u003eAcknowledgment 389\u003c\/p\u003e \u003cp\u003eReferences 389\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 19 Transmission and Emission \u003csup\u003e57\u003c\/sup\u003eFe Mössbauer Studies on Perovskites and Related Oxide Systems 393\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eZoltán Homonnay and Zoltán Németh\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 393\u003c\/p\u003e \u003cp\u003e19.2 Study of high-\u003ci\u003eT\u003c\/i\u003e\u003csub\u003ec\u003c\/sub\u003e superconductors 394\u003c\/p\u003e \u003cp\u003e19.3 Study of Strontium ferrate and its substituted analogues 401\u003c\/p\u003e \u003cp\u003e19.4 Pursuing Colossal Magnetoresistance in Doped Lanthanum Cobaltates 407\u003c\/p\u003e \u003cp\u003eReferences 413\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 20 Enhancing the Possibilities of \u003csup\u003e57\u003c\/sup\u003eFe Mössbauer Spectrometry to Study the Inherent Properties of Rust Layers 415\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eKaren E García, César A Barrero, Alvaro L Morales, and Jean-Marc Greneche\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 415\u003c\/p\u003e \u003cp\u003e20.2 Mössbauer Characterization of Some Iron Phases Presented in the Rust Layers 416\u003c\/p\u003e \u003cp\u003e20.3 Determining Inherent Properties of Rust Layers by Mössbauer Spectrometry 421\u003c\/p\u003e \u003cp\u003e20.4 Final Remarks 426\u003c\/p\u003e \u003cp\u003eAcknowledgments 426\u003c\/p\u003e \u003cp\u003eReferences 426\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 21 Application of Mössbauer Spectroscopy in Nanomagnetics 429\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eLakshmi Nambakkat\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction 429\u003c\/p\u003e \u003cp\u003e21.2 Spinel Ferrites 430\u003c\/p\u003e \u003cp\u003e21.3 Nano Sized Fe-Al Alloys Synthesized by High Energy Ball Milling 441\u003c\/p\u003e \u003cp\u003e21.4 Magnetic Thin Films\/Multilayer Systems: \u003csup\u003e57\u003c\/sup\u003eFe\/Al MLS 446\u003c\/p\u003e \u003cp\u003eConclusion 452\u003c\/p\u003e \u003cp\u003eAcknowledgment 453\u003c\/p\u003e \u003cp\u003eReferences 453\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 22 Mössbauer Spectroscopy and Surface Analysis 455\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJosé F Marco, J Ramón Gancedo, Matteo Monti and Juan de la Figuera\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e22.1 Introduction 455\u003c\/p\u003e \u003cp\u003e22.2 The Physical Basis: How and Why Electrons Appear in Mössbauer Spectroscopy 456\u003c\/p\u003e \u003cp\u003e22.3 Increasing Surface Sensitivity in Electron Mössbauer Spectroscopy 458\u003c\/p\u003e \u003cp\u003e22.4 The Practical Way: Experimental Low Energy Electron Mössbauer Spectroscopy 460\u003c\/p\u003e \u003cp\u003e22.5 Mössbauer Surface Imaging Techniques 465\u003c\/p\u003e \u003cp\u003e22.6 Recent Surface Mössbauer Studies in an \"ancient\" Material: Fe\u003csub\u003e3\u003c\/sub\u003eO\u003csub\u003e4\u003c\/sub\u003e 466\u003c\/p\u003e \u003cp\u003eAcknowledgments 468\u003c\/p\u003e \u003cp\u003eReferences 468\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 23 \u003csup\u003e57\u003c\/sup\u003eFe Mössbauer Spectroscopy in the Investigation of the Precipitation of Iron Oxides\u003cbr\u003e 470\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eSvetozar Musić, Mira Ristić, and Stjepko Krehula\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e23.1 Introduction 470\u003c\/p\u003e \u003cp\u003e23.2 Complexation of Iron Ions by Hydrolysis 470\u003c\/p\u003e \u003cp\u003e23.3 Precipitation of Iron Oxides by Hydrolysis Reactions 472\u003c\/p\u003e \u003cp\u003e23.4 Precipitation of \u003ci\u003eIron Oxides\u003c\/i\u003e from Dense -FeOOH Suspensions 480\u003c\/p\u003e \u003cp\u003e23.5 Precipitation and Properties of Some Other Iron Oxides 483\u003c\/p\u003e \u003cp\u003e23.6 Influence of Cations on the Precipitation of Iron Oxides 490\u003c\/p\u003e \u003cp\u003eAcknowledgment 496\u003c\/p\u003e \u003cp\u003eReferences 497\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 24 Ferrates (IV, V, and VI): Mössbauer Spectroscopy Characterization 505\u003c\/b\u003e\u003cbr\u003e \u003ci\u003eVirender K Sharma, Yurii Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e24.1 Introduction 505\u003c\/p\u003e \u003cp\u003e24.2 Spectroscopic Characterization 506\u003c\/p\u003e \u003cp\u003e24.3 Mössbauer Spectroscopy Characterization 508\u003c\/p\u003e \u003cp\u003eAcknowledgments 517\u003c\/p\u003e \u003cp\u003eReferences 517\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 25 Characterization of Dilute Iron-Doped Yttrium Aluminum Garnets by Mössbauer Spectrometry 521\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eKiyoshi Nomura and Zoltán Németh\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e25.1 Introduction 521\u003c\/p\u003e \u003cp\u003e25.2 Sample Preparations by sol-gel Method 523\u003c\/p\u003e \u003cp\u003e25.3 X-ray Diffraction and EXAFS Analysis 523\u003c\/p\u003e \u003cp\u003e25.4 Magnetic Properties 525\u003c\/p\u003e \u003cp\u003e25.5 Mössbauer Analysis of YAG Doped with Dilute Iron 526\u003c\/p\u003e \u003cp\u003e25.6 Micro-discharge Treatment of Iron Doped YAG 528\u003c\/p\u003e \u003cp\u003eConclusion 531\u003c\/p\u003e \u003cp\u003eAcknowledgment 532\u003c\/p\u003e \u003cp\u003eReferences 532\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart VI Industrial Applications 533\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 26 Some Mössbauer Studies of Fe-As Based High Temperature Superconductors 535\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eAmar Nath and Airat Khasanov\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e26.1 Introduction 535\u003c\/p\u003e \u003cp\u003e26.2 Experimental 535\u003c\/p\u003e \u003cp\u003e26.3 Where Do the Injected Electrons Go? 537\u003c\/p\u003e \u003cp\u003e26.4 New Electron-rich Species in Ni-doped Single Crystals: Is it Superconducting? 538\u003c\/p\u003e \u003cp\u003e26.5 Can O\u003csub\u003e2\u003c\/sub\u003e play an Important Role? 539\u003c\/p\u003e \u003cp\u003eAcknowledgment 541\u003c\/p\u003e \u003cp\u003eReferences 541\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 27 Mossbauer Study of New Electrically Conductive Glass 542\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eTetsuaki Nishida and Shiro Kubuki\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e27.1 Introduction 542\u003c\/p\u003e \u003cp\u003e27.2 Structural Relaxation of Electrically Conductive Vanadate Glass 544\u003c\/p\u003e \u003cp\u003eAcknowledgments 551\u003c\/p\u003e \u003cp\u003eReferences 551\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 28 Applications of Mössbauer Spectroscopy in the Study of Lithium Battery Materials 552\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eRicardo Alcántara, Pedro Lavela, Carlos Pérez Vicente, José L Tirado\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e28.1 Introduction 552\u003c\/p\u003e \u003cp\u003e28.2 Cathode Materials for Li-ion Batteries 554\u003c\/p\u003e \u003cp\u003e28.3 Anode Materials for Li-ion Batteries 556\u003c\/p\u003e \u003cp\u003eConclusions 561\u003c\/p\u003e \u003cp\u003eAcknowledgment 561\u003c\/p\u003e \u003cp\u003eReferences 562\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 29 Mössbauer Spectroscopic Investigations of Novel Bimetal Catalysts for Preferential CO Oxidation in H\u003csub\u003e2 \u003c\/sub\u003e 564\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eWansheng Zhang, Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e29.1 Introduction 564\u003c\/p\u003e \u003cp\u003e29.2 Experimental Section 564\u003c\/p\u003e \u003cp\u003e29.3 Results and Discussion 565\u003c\/p\u003e \u003cp\u003eConclusion 574\u003c\/p\u003e \u003cp\u003eAcknowledgments 574\u003c\/p\u003e \u003cp\u003eReferences 575\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 30 The use of Mossbauer Spectroscopy in Coal Research-Is it Relevant or Not? 576\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eF B Waanders\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e30.1 Introduction 576\u003c\/p\u003e \u003cp\u003e30.2 Experimental Procedures 577\u003c\/p\u003e \u003cp\u003e30.3 Results and Discussion 578\u003c\/p\u003e \u003cp\u003eConclusions 590\u003c\/p\u003e \u003cp\u003eReferences 591\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart VII Environmental Applications\u003c\/b\u003e \u003cb\u003e593\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 31 Water Purification and Characterization of Recycled Iron-Silicate Glass 595\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eShiro Kubuki and Tetsuaki Nishida\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e31.1 Introduction 595\u003c\/p\u003e \u003cp\u003e31.2 Property and Structure of Recycled Silicate Glasses 596\u003c\/p\u003e \u003cp\u003e31.3 Summary 605\u003c\/p\u003e \u003cp\u003eReference 606\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 32 Mössbauer Spectroscopy in the Study of Laterite Mineral Processing 608\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eEamonn Devlin, Michail Samouhos, Charalabos Zografidis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e32.1 Introduction 608\u003c\/p\u003e \u003cp\u003e32.2 Conventional Processing 609\u003c\/p\u003e \u003cp\u003e32.3 Microwave Processing 612\u003c\/p\u003e \u003cp\u003eReference 619\u003cbr\u003e \u003cbr\u003e \u003ci\u003eIndex 621\u003c\/i\u003e\u003c\/p\u003e  \u003cp\u003e\u003cstrong\u003eVIRENDER K. SHARMA\u003c\/strong\u003e received his Ph.D. in?Marine and Atmospheric Chemistry at the Florida Insitute of Technology after graduating from the Indian Institute of Technology in New Delhi, India with the Master in Technology.?He?is?currently?Professor of Chemistry at F.I.T. He was a visiting research scholar at Stanford University under the advisory of Professor Ed Solomon and won both the?ACS Faculty of the Year award in 2008 and the?Orlando Section Outstanding Chemist Award.?His research interests include the study of kinetics and mechanisms of oxidations by transition metals in higher oxidation states in aqueous solution, development of innovative and effective methods for reducing the level of contaminants in the aquatic environment, and the physical chemistry of natural waters. \u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eGOESTER KLINGELHOEFER\u003c\/strong\u003e is a professor?of inorganic and analytical chemistry and the University of Mainz, Germany. \u003c\/p\u003e\u003cp\u003e\u003cstrong\u003eTETSUAKI NISHIDA\u003c\/strong\u003e is professor of chemistry at?Kinki University, Japan.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989667791077,"sku":"NP9781118057247","price":209.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781118057247.jpg?v=1761785028","url":"https:\/\/k12savings.com\/products\/mossbauer-spectroscopy-isbn-9781118057247","provider":"K12savings","version":"1.0","type":"link"}