{"product_id":"introduction-to-solid-state-nmr-spectroscopy-isbn-9781405109147","title":"Introduction to Solid-State NMR Spectroscopy","description":"\u003ci\u003eIntroduction to Solid State NMR Spectroscopy\u003c\/i\u003e is written for undergraduate and graduate students of chemistry, either taking a course in advanced or solid-state nuclear magnetic resonance spectroscopy or undertaking research projects where solid-state NMR is likely to be a major investigative technique. It will also serve as a practical introduction in industry, where the techniques can provide new or complementary information to supplement other investigative techniques.\u003cbr\u003e \u003cp\u003e\u003cbr\u003e \u003c\/p\u003e \u003cp\u003eBy covering solid-state NMR spectroscopy in a clear, straightforward and approachable way with detailed descriptions of the major solid-state NMR experiments focussing on what the experiments do and what they tell the researcher, this book will serve as an ideal introduction to the subject. These descriptions are backed up by separate mathematical explanations for those who wish to gain a more sophisticated quantitative understanding of the phenomena. With additional coverage of the practical implementation of solid-state NMR experiments integrated into the discussion, this book will be essential reading for all those using, or about to use, solid-state NMR spectroscopy.\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e\u003cb\u003eDr Melinda Duer\u003c\/b\u003e is a senior lecturer in the Department of Chemistry at the University of Cambridge, Cambridge, UK.\u003c\/p\u003e \u003cp\u003ePreface, xii\u003c\/p\u003e \u003cp\u003eAcknowledgements, xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The Basics of NMR, 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 The vector model of pulsed NMR, 1\u003c\/p\u003e \u003cp\u003e1.1.1 Nuclei in a static, uniform magnetic field, 2\u003c\/p\u003e \u003cp\u003e1.1.2 The effect of rf pulses, 3\u003c\/p\u003e \u003cp\u003e1.2 The quantum mechanical picture: hamiltonians and the Schrödinger equation, 5\u003c\/p\u003e \u003cp\u003eBox 1.1 Quantum mechanics and NMR, 6\u003c\/p\u003e \u003cp\u003eWavefunctions, 6\u003c\/p\u003e \u003cp\u003eOperators, physical observables and expectation values, 7\u003c\/p\u003e \u003cp\u003eSchrödinger’s equation, eigenfunctions and eigenvalues, 7\u003c\/p\u003e \u003cp\u003eSpin operators and spin states, 8\u003c\/p\u003e \u003cp\u003eDirac’s bra-ket notation, 11\u003c\/p\u003e \u003cp\u003eMatrices, 11\u003c\/p\u003e \u003cp\u003e1.2.1 Nuclei in a static, uniform field, 12\u003c\/p\u003e \u003cp\u003e1.2.2 The effect of rf pulses, 15\u003c\/p\u003e \u003cp\u003eBox 1.2 Exponential operators, rotation operators and rotations, 19\u003c\/p\u003e \u003cp\u003eRotation of vectors, wavefunctions and operators (active rotations), 20\u003c\/p\u003e \u003cp\u003eRotation of axis frames, 23\u003c\/p\u003e \u003cp\u003eRepresentation of rf fields, 25\u003c\/p\u003e \u003cp\u003eEuler angles, 25\u003c\/p\u003e \u003cp\u003eRotations with Euler angles, 26\u003c\/p\u003e \u003cp\u003eRotation of Cartesian axis frames, 27\u003c\/p\u003e \u003cp\u003e1.3 The density matrix representation and coherences, 29\u003c\/p\u003e \u003cp\u003e1.3.1 Coherences and populations, 30\u003c\/p\u003e \u003cp\u003e1.3.2 The density operator at thermal equilibrium, 33\u003c\/p\u003e \u003cp\u003e1.3.3 Time evolution of the density matrix, 34\u003c\/p\u003e \u003cp\u003e1.4 Nuclear spin interactions, 37\u003c\/p\u003e \u003cp\u003e1.4.1 Interaction tensors, 41\u003c\/p\u003e \u003cp\u003e1.5 General features of Fourier transform NMR experiments, 43\u003c\/p\u003e \u003cp\u003e1.5.1 Multidimensional NMR, 43\u003c\/p\u003e \u003cp\u003e1.5.2 Phase cycling, 46\u003c\/p\u003e \u003cp\u003e1.5.3 Quadrature detection, 48\u003c\/p\u003e \u003cp\u003eBox 1.3 The NMR spectrometer, 53\u003c\/p\u003e \u003cp\u003eGenerating rf pulses, 53\u003c\/p\u003e \u003cp\u003eDetecting the NMR signal, 56\u003c\/p\u003e \u003cp\u003eNotes, 58\u003c\/p\u003e \u003cp\u003eReferences, 59\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Essential Techniques for Solid-State NMR, 60\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction, 60\u003c\/p\u003e \u003cp\u003e2.2 Magic-angle spinning (MAS), 61\u003c\/p\u003e \u003cp\u003e2.2.1 Spinning sidebands, 62\u003c\/p\u003e \u003cp\u003e2.2.2 Rotor or rotational echoes, 67\u003c\/p\u003e \u003cp\u003e2.2.3 Removing spinning sidebands, 67\u003c\/p\u003e \u003cp\u003e2.2.4 Setting the magic-angle and spinning rate, 72\u003c\/p\u003e \u003cp\u003e2.2.5 Magic-angle spinning for homonuclear dipolar couplings, 75\u003c\/p\u003e \u003cp\u003e2.3 Heteronuclear decoupling, 77\u003c\/p\u003e \u003cp\u003e2.3.1 High-power decoupling, 78\u003c\/p\u003e \u003cp\u003e2.3.2 Other heteronuclear decoupling sequences, 81\u003c\/p\u003e \u003cp\u003e2.4 Homonuclear decoupling, 83\u003c\/p\u003e \u003cp\u003e2.4.1 Implementing homonuclear decoupling sequences, 83\u003c\/p\u003e \u003cp\u003eBox 2.1 Average hamiltonian theory and the toggling frame, 86\u003c\/p\u003e \u003cp\u003eAverage hamiltonian theory, 86\u003c\/p\u003e \u003cp\u003eThe toggling frame and the WAHUHA pulse sequence, 89\u003c\/p\u003e \u003cp\u003e2.5 Cross-polarization, 96\u003c\/p\u003e \u003cp\u003e2.5.1 Theory, 97\u003c\/p\u003e \u003cp\u003e2.5.2 Setting up the cross-polarization experiment, 101\u003c\/p\u003e \u003cp\u003eBox 2.2 Cross-polarization and magic-angle spinning, 106\u003c\/p\u003e \u003cp\u003e2.6 Echo pulse sequences, 110\u003c\/p\u003e \u003cp\u003eNotes, 113\u003c\/p\u003e \u003cp\u003eReferences, 114\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Shielding and Chemical Shift: Theory and Uses, 116\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Theory, 116\u003c\/p\u003e \u003cp\u003e3.1.1 Introduction, 116\u003c\/p\u003e \u003cp\u003e3.1.2 The chemical shielding hamiltonian, 117\u003c\/p\u003e \u003cp\u003e3.1.3 Experimental manifestations of the shielding tensor, 120\u003c\/p\u003e \u003cp\u003e3.1.4 Definition of the chemical shift, 123\u003c\/p\u003e \u003cp\u003e3.2 The relationship between the shielding tensor and electronic structure, 125\u003c\/p\u003e \u003cp\u003e3.3 Measuring chemical shift anisotropies, 131\u003c\/p\u003e \u003cp\u003e3.3.1 Magic-angle spinning with recoupling pulse sequences, 132\u003c\/p\u003e \u003cp\u003e3.3.2 Variable-angle spinning experiments, 135\u003c\/p\u003e \u003cp\u003e3.3.3 Magic-angle turning, 138\u003c\/p\u003e \u003cp\u003e3.3.4 Two-dimensional separation of spinning sideband patterns, 141\u003c\/p\u003e \u003cp\u003e3.4 Measuring the orientation of chemical shielding tensors in the molecular frame for structure determination, 145\u003c\/p\u003e \u003cp\u003eNotes, 149\u003c\/p\u003e \u003cp\u003eReferences, 149\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Dipolar Coupling: Theory and Uses, 151\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Theory, 151\u003c\/p\u003e \u003cp\u003e4.1.1 Homonuclear dipolar coupling, 154\u003c\/p\u003e \u003cp\u003eBox 4.1 Basis sets for multispin systems, 156\u003c\/p\u003e \u003cp\u003e4.1.2 The effect of homonuclear dipolar coupling on a spin system, 157\u003c\/p\u003e \u003cp\u003e4.1.3 Heteronuclear dipolar coupling, 160\u003c\/p\u003e \u003cp\u003e4.1.4 The effect of heteronuclear dipolar coupling on the spin system, 162\u003c\/p\u003e \u003cp\u003e4.1.5 Heteronuclear spin dipolar coupled to a homonuclear network of spins, 163\u003c\/p\u003e \u003cp\u003e4.1.6 The spherical tensor form of the dipolar hamiltonian, 164\u003c\/p\u003e \u003cp\u003eBox 4.2 The dipolar hamiltonian in terms of spherical tensor operators, 164\u003c\/p\u003e \u003cp\u003eSpherical tensor operators, 165\u003c\/p\u003e \u003cp\u003eInteraction tensors, 167\u003c\/p\u003e \u003cp\u003eThe homonuclear dipolar hamiltonian under static and MAS conditions, 167\u003c\/p\u003e \u003cp\u003e4.2 Introduction to the uses of dipolar coupling, 172\u003c\/p\u003e \u003cp\u003e4.3 Techniques for measuring homonuclear dipolar couplings, 175\u003c\/p\u003e \u003cp\u003e4.3.1 Recoupling pulse sequences, 175\u003c\/p\u003e \u003cp\u003eBox 4.3 Analysis of the DRAMA pulse sequence, 180\u003c\/p\u003e \u003cp\u003eSimulating powder patterns from the DRAMA experiment, 184\u003c\/p\u003e \u003cp\u003e4.3.2 Double-quantum filtered experiments, 185\u003c\/p\u003e \u003cp\u003eBox 4.4 Excitation of double-quantum coherence under magic-angle spinning, 189\u003c\/p\u003e \u003cp\u003eThe form of the reconversion pulse sequence: the need for timereversal symmetry, 191\u003c\/p\u003e \u003cp\u003eAnalysis of the double-quantum filtered data, 195\u003c\/p\u003e \u003cp\u003eBox 4.5 Analysis of the C7 pulse sequence for exciting double-quantum coherence in dipolar-coupled spin pairs, 196\u003c\/p\u003e \u003cp\u003e4.3.3 Rotational resonance, 199\u003c\/p\u003e \u003cp\u003eBox 4.6 Theory of rotational resonance, 202\u003c\/p\u003e \u003cp\u003eEffect of H ˆ \u003csub\u003e∆\u003c\/sub\u003e term on the density operator, 203\u003c\/p\u003e \u003cp\u003eThe hamiltonian in the new rotated frame, 204\u003c\/p\u003e \u003cp\u003eThe average hamiltonian, 205\u003c\/p\u003e \u003cp\u003e4.4 Techniques for measuring heteronuclear dipolar couplings, 207\u003c\/p\u003e \u003cp\u003e4.4.1 Spin-echo double resonance (SEDOR), 207\u003c\/p\u003e \u003cp\u003e4.4.2 Rotational-echo double resonance (REDOR), 208\u003c\/p\u003e \u003cp\u003eBox 4.7 Analysis of the REDOR experiment, 210\u003c\/p\u003e \u003cp\u003e4.5 Techniques for dipolar-coupled quadrupolar–spin-1–2 pairs, 215\u003c\/p\u003e \u003cp\u003e4.5.1 Transfer of population in double resonance (TRAPDOR), 216\u003c\/p\u003e \u003cp\u003e4.5.2 Rotational-echo adiabatic-passage double-resonance (REAPDOR), 219\u003c\/p\u003e \u003cp\u003e4.6 Techniques for measuring dipolar couplings between quadrupolar nuclei, 220\u003c\/p\u003e \u003cp\u003e4.7 Correlation experiments, 221\u003c\/p\u003e \u003cp\u003e4.7.1 Homonuclear correlation experiments for spin-1–2 systems, 221\u003c\/p\u003e \u003cp\u003e4.7.2 Homonuclear correlation experiments for quadrupolar spin systems, 224\u003c\/p\u003e \u003cp\u003e4.7.3 Heteronuclear correlation experiments for spin-1–2, 226\u003c\/p\u003e \u003cp\u003e4.8 Spin-counting experiments, 227\u003c\/p\u003e \u003cp\u003e4.8.1 The formation of multiple-quantum coherences, 228\u003c\/p\u003e \u003cp\u003e4.8.2 Implementation of spin-counting experiments, 231\u003c\/p\u003e \u003cp\u003eNotes, 232\u003c\/p\u003e \u003cp\u003eReferences, 233\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Quadrupole Coupling: Theory and Uses, 235\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction, 235\u003c\/p\u003e \u003cp\u003e5.2 Theory, 237\u003c\/p\u003e \u003cp\u003e5.2.1 The quadrupole hamiltonian, 237\u003c\/p\u003e \u003cp\u003eBox 5.1 The quadrupole hamiltonian in terms of spherical tensor operators: the effect of the rotating frame and magic-angle spinning, 242\u003c\/p\u003e \u003cp\u003eThe quadrupole hamiltonian in terms of spherical tensor operators, 242\u003c\/p\u003e \u003cp\u003eThe effect of the rotating frame: first- and second-order average hamiltonians for the quadrupole interaction, 243\u003c\/p\u003e \u003cp\u003eThe energy levels under quadrupole coupling, 248\u003c\/p\u003e \u003cp\u003eThe effect of magic-angle spinning, 248\u003c\/p\u003e \u003cp\u003e5.2.2 The effect of rf pulses, 249\u003c\/p\u003e \u003cp\u003e5.2.3 The effects of quadrupolar nuclei on the spectra of spin-1–2 nuclei, 252\u003c\/p\u003e \u003cp\u003e5.3 High-resolution NMR experiments for half-integer quadrupolar nuclei, 255\u003c\/p\u003e \u003cp\u003e5.3.1 Magic-angle spinning (MAS), 256\u003c\/p\u003e \u003cp\u003e5.3.2 Double rotation (DOR), 259\u003c\/p\u003e \u003cp\u003e5.3.3 Dynamic-angle spinning (DAS), 260\u003c\/p\u003e \u003cp\u003e5.3.4 Multiple-quantum magic-angle spinning (MQMAS), 263\u003c\/p\u003e \u003cp\u003e5.3.5 Satellite transition magic-angle spinning (STMAS), 268\u003c\/p\u003e \u003cp\u003e5.3.6 Recording two-dimensional datasets for DAS, MQMAS and STMAS, 275\u003c\/p\u003e \u003cp\u003e5.4 Other techniques for half-integer quadrupole nuclei, 280\u003c\/p\u003e \u003cp\u003e5.4.1 Quadrupole nutation, 282\u003c\/p\u003e \u003cp\u003e5.4.2 Cross-polarization, 285\u003c\/p\u003e \u003cp\u003eNotes, 290\u003c\/p\u003e \u003cp\u003eReferences, 291\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 NMR Techniques for Studying Molecular Motion in Solids, 293\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction, 293\u003c\/p\u003e \u003cp\u003e6.2 Powder lineshape analysis, 296\u003c\/p\u003e \u003cp\u003e6.2.1 Simulating powder pattern lineshapes, 297\u003c\/p\u003e \u003cp\u003e6.2.2 Resolving powder patterns, 305\u003c\/p\u003e \u003cp\u003e6.2.3 Using homonuclear dipolar-coupling lineshapes – the WISE experiment, 311\u003c\/p\u003e \u003cp\u003e6.3 Relaxation time studies, 313\u003c\/p\u003e \u003cp\u003e6.4 Exchange experiments, 316\u003c\/p\u003e \u003cp\u003e6.4.1 Achieving pure absorption lineshapes in exchange spectra, 318\u003c\/p\u003e \u003cp\u003e6.4.2 Interpreting two-dimensional exchange spectra, 320\u003c\/p\u003e \u003cp\u003e6.5 2H NMR, 322\u003c\/p\u003e \u003cp\u003e6.5.1 Measuring 2H NMR spectra, 323\u003c\/p\u003e \u003cp\u003e6.5.2 2H lineshape simulations, 328\u003c\/p\u003e \u003cp\u003e6.5.3 Relaxation time studies, 329\u003c\/p\u003e \u003cp\u003e6.5.4 2H exchange experiments, 330\u003c\/p\u003e \u003cp\u003e6.5.5 Resolving 2H powder patterns, 332\u003c\/p\u003e \u003cp\u003eNotes, 334\u003c\/p\u003e \u003cp\u003eReferences, 335\u003c\/p\u003e \u003cp\u003eAppendix A NMR Properties of Commonly Observed Nuclei, 336\u003c\/p\u003e \u003cp\u003eAppendix B The General Form of a Spin Interaction Hamiltonian in Terms of Spherical Tensors and Spherical Tensor Operators, 337\u003c\/p\u003e \u003cp\u003eReferences, 343\u003c\/p\u003e \u003cp\u003eIndex, 344 \u003c\/p\u003e  \"Overall this is an excellent book and one that I personally will find very useful. I will recommend it to my postgraduate students and prostdoctoral research fellows for its detailed and careful explanations of a wide range of experimental methods in solid-state NMR spectroscopy.\"\u003cbr\u003e \u003cp\u003e\"The book is clear and straightforward...the level of detail is very impressive and the author does not shirk her duty to explain some of the most notoriously difficult concepts in this area.\"\u003cbr\u003e \u003cb\u003eChemistry World, Vol 2, No 1, January 2005\u003c\/b\u003e\u003cbr\u003e \u003c\/p\u003e \u003cp\u003e\"The theoretical approaches, the description of methods and the demonstration of the applications are clearly given in this book, which can be recommended to students and researchers in physical, analytical and organic chemistry and also biology who need access to solid-state NMR for the characterization of structures and dynamics of chemical or biological compounds.”\u003cbr\u003e \u003cb\u003eMagnetic Resonance in Chemistry, 2004, vol 42\u003c\/b\u003e\u003c\/p\u003e \u003cb\u003eDr Melinda Duer\u003c\/b\u003e is a senior lecturer in the Department of Chemistry at the University of Cambridge, Cambridge, UK  \u003ci\u003eIntroduction to Solid State NMR Spectroscopy\u003c\/i\u003e is written for undergraduate and graduate students of chemistry, studying courses in nuclear magnetic resonance or undertaking research projects in this area. It will also serve as a useful introduction in industry, where researchers are turning to solid-state techniques to solve problems that are not amenable to other investigative techniques.\u003cbr\u003e \u003cp\u003eBy covering solid-state NMR spectroscopy in a clear, straightforward and approachable way with detailed descriptions of the major solid-state NMR experiments focussing on what the experiments do and what they tell the researcher, this book will serve as an ideal introduction to the subject. These descriptions are backed up by separate mathematical explanations for those who wish to gain a more sophisticated quantitative understanding of the phenomena. With additional coverage of the practical implementation of solid-state NMR experiments integrated into the discussion, this book will be essential reading for all those using, or about to use, solid-state NMR spectroscopy.\u003c\/p\u003e","brand":"Wiley-Blackwell","offers":[{"title":"Default Title","offer_id":47989466693861,"sku":"NP9781405109147","price":74.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781405109147.jpg?v=1761784215","url":"https:\/\/k12savings.com\/products\/introduction-to-solid-state-nmr-spectroscopy-isbn-9781405109147","provider":"K12savings","version":"1.0","type":"link"}