{"product_id":"handbook-of-transition-metal-polymerization-catalysts-isbn-9781119242130","title":"Handbook of Transition Metal Polymerization Catalysts","description":"Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity.\u003cbr\u003e\u003cbr\u003e•    Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications\u003cbr\u003e•    Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers \u003cbr\u003e•    Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized\u003cbr\u003e•    Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization \u003cp\u003eNotes on Contributors xvii\u003c\/p\u003e \u003cp\u003ePreface xxix\u003c\/p\u003e \u003cp\u003eAcknowledgments xxxiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Industrial Metal Alkyls and Their Use in Polyolefin Catalysts 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eDennis B. Malpass\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Metal Alkyls in Ziegler–Natta Catalysts 2\u003c\/p\u003e \u003cp\u003e1.3 Aluminum Alkyls 4\u003c\/p\u003e \u003cp\u003e1.4 Manufacturers of Aluminum Alkyls 10\u003c\/p\u003e \u003cp\u003e1.5 Pricing and Selection Criteria for Aluminum Alkyls 11\u003c\/p\u003e \u003cp\u003e1.6 Methylaluminoxanes 13\u003c\/p\u003e \u003cp\u003e1.7 Magnesium Alkyls 18\u003c\/p\u003e \u003cp\u003e1.8 Organoboron Compounds 24\u003c\/p\u003e \u003cp\u003e1.9 Organozinc Compounds 26\u003c\/p\u003e \u003cp\u003eReferences 27\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Porous Silica in Transition Metal Polymerization Catalysts 31\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eThomas J. Pullukat and Robert E. Patterson\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 31\u003c\/p\u003e \u003cp\u003e2.2 Production of Silica Gel Catalysts 33\u003c\/p\u003e \u003cp\u003e2.3 Influence of Silica Gel Properties and Polymerization Conditions on Catalyst Performance 36\u003c\/p\u003e \u003cp\u003e2.4 Conclusions 52\u003c\/p\u003e \u003cp\u003eReferences 53\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Activator Supports for Metallocene and Related Catalysts 57\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRay Hoff\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 57\u003c\/p\u003e \u003cp\u003e3.2 Activator Support Studies 58\u003c\/p\u003e \u003cp\u003e3.3 Activator Support Patents 60\u003c\/p\u003e \u003cp\u003e3.4 Conclusion 62\u003c\/p\u003e \u003cp\u003eReferences 64\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Computational Modeling of Polymerization Catalysts 67\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMonika Srebro Hooper and Artur Michalak\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 67\u003c\/p\u003e \u003cp\u003e4.2 Computational Modeling of Chemical Reactions 68\u003c\/p\u003e \u003cp\u003e4.3 Modeling the Catalyst Properties and the Polymerization Processes 76\u003c\/p\u003e \u003cp\u003e4.4 Concluding Remarks 116\u003c\/p\u003e \u003cp\u003eAcknowledgment 117\u003c\/p\u003e \u003cp\u003eReferences 117\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Computational Studies of Chromium: Silica Catalysts 131\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eZhen Liu and Boping Liu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 131\u003c\/p\u003e \u003cp\u003e5.2 Mechanistic Proposals for Phillips Catalyst 132\u003c\/p\u003e \u003cp\u003e5.3 Theoretical Study on Phillips Catalyst 137\u003c\/p\u003e \u003cp\u003e5.4 The Limitation of the Current Computations and a Prospect for the Future 156\u003c\/p\u003e \u003cp\u003eReferences 157\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Laboratory Reactors and Procedures for Catalyst Evaluation 161\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRinaldo Schiffino\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 161\u003c\/p\u003e \u003cp\u003e6.2 Setup in the Fume Hood 162\u003c\/p\u003e \u003cp\u003e6.3 Autoclave Reactors and Safety Relief Devices 163\u003c\/p\u003e \u003cp\u003e6.4 Purification Methods 164\u003c\/p\u003e \u003cp\u003e6.5 Modular Reactor System 165\u003c\/p\u003e \u003cp\u003e6.6 Catalyst Addition 168\u003c\/p\u003e \u003cp\u003e6.7 Temperature Control 170\u003c\/p\u003e \u003cp\u003e6.8 Autoclave Reactor Setup 172\u003c\/p\u003e \u003cp\u003e6.9 Copolymerization 173\u003c\/p\u003e \u003cp\u003e6.10 Gas-Phase Laboratory Reactors 175\u003c\/p\u003e \u003cp\u003eReferences 176\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Scale-Up of Catalyst Recipes to Commercial Production 177\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eChung Ping Cheng\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 177\u003c\/p\u003e \u003cp\u003e7.2 Fundamental of Process Scale-Up 178\u003c\/p\u003e \u003cp\u003e7.3 Considerations in Scaling Up a Laboratory Recipe 180\u003c\/p\u003e \u003cp\u003e7.4 A Modern Polymerization Catalyst Production Facility 182\u003c\/p\u003e \u003cp\u003e7.5 Other Scale-Up Considerations 187\u003c\/p\u003e \u003cp\u003eReferences 187\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Supported Titanium\/Magnesium Ziegler Catalysts for the Production of Polyethylene 189\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYury V. Kissin, Thomas E. Nowlin, and Robert I. Mink\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 189\u003c\/p\u003e \u003cp\u003e8.2 Particle-Form Technology 192\u003c\/p\u003e \u003cp\u003e8.3 General Architecture and Preparation of Supported Catalysts 193\u003c\/p\u003e \u003cp\u003e8.4 Nonuniformity of Active Centers in Supported Ziegler Catalysts 205\u003c\/p\u003e \u003cp\u003e8.5 Kinetics and Mechanism of Ethylene Polymerization Reactions with Ziegler Catalysts 209\u003c\/p\u003e \u003cp\u003e8.6 Kinetic Interpretation of Ethylene Polymerization Reactions 217\u003c\/p\u003e \u003cp\u003e8.7 Active Centers in Ziegler Catalysts 221\u003c\/p\u003e \u003cp\u003eReferences 224\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Stereospecific α-Olefin Polymerization with Heterogeneous Catalysts 229\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJohn Severn and Robert L. Jones, JR\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 229\u003c\/p\u003e \u003cp\u003e9.2 Traditional Ziegler–Natta Catalyst Systems 241\u003c\/p\u003e \u003cp\u003e9.3 Stereospecific Single Site Catalysts 266\u003c\/p\u003e \u003cp\u003e9.4 Conclusion 295\u003c\/p\u003e \u003cp\u003eReferences 296\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Olefin Polymerization by Vanadium Complex Catalysts 313\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKotohiro Nomura and Xiaohua Hou\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction: Classical Ziegler-Type Vanadium Catalyst Systems 313\u003c\/p\u003e \u003cp\u003e10.2 Vanadium Complexes Designed for Olefin Coordination Insertion Polymerization 315\u003c\/p\u003e \u003cp\u003e10.3 Outlook 332\u003c\/p\u003e \u003cp\u003eReferences 333\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 MgCl2-Supported Ti Catalysts for the Production of Morphology-Controlled Polyethylene 339\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLong Wu and Sieghard Wanke\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 339\u003c\/p\u003e \u003cp\u003e11.2 Preparation of Morphology-Controlled MgCl2\/TiCl4 Catalysts 342\u003c\/p\u003e \u003cp\u003e11.3 Polymerization Processes 345\u003c\/p\u003e \u003cp\u003e11.4 Effect of Prepolymerization on Activity Profiles and Prepolymer Properties 349\u003c\/p\u003e \u003cp\u003e11.5 Polymerization Behavior 358\u003c\/p\u003e \u003cp\u003e11.6 Summary and Conclusions 364\u003c\/p\u003e \u003cp\u003eReferences 365\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Product Morphology in Olefin Polymerization with Polymer-Supported Metallocene Catalysts 369\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLong Wu and Sieghard Wanke\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 369\u003c\/p\u003e \u003cp\u003e12.2 Preparation of Polymer-Supported Metallocene Catalysts 371\u003c\/p\u003e \u003cp\u003e12.3 Factors Affecting Morphology of Product Particles 379\u003c\/p\u003e \u003cp\u003e12.4 Factors Affecting Product Morphology 389\u003c\/p\u003e \u003cp\u003e12.5 Product Fines and Densities 394\u003c\/p\u003e \u003cp\u003e12.6 Conclusions 396\u003c\/p\u003e \u003cp\u003eReferences 396\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 A Review of the Phillips Chromium Catalyst for Ethylene Polymerization 401\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMax P. McDaniel\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Historical and Commercial Background 401\u003c\/p\u003e \u003cp\u003e13.2 Catalyst Preparation 404\u003c\/p\u003e \u003cp\u003e13.3 Control of Catalyst Activity 414\u003c\/p\u003e \u003cp\u003e13.4 Control of Molecular Weight and MW Distribution 439\u003c\/p\u003e \u003cp\u003e13.5 Control of Crystallinity 482\u003c\/p\u003e \u003cp\u003e13.6 Control of Elasticity 509\u003c\/p\u003e \u003cp\u003e13.7 Concluding Remarks 542\u003c\/p\u003e \u003cp\u003eReferences 546\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Silica-Supported Silyl Chromate-Based Ethylene Polymerization Catalysts 573\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKevin Cann\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 573\u003c\/p\u003e \u003cp\u003e14.2 Silyl Chromate Catalyst Development 573\u003c\/p\u003e \u003cp\u003e14.3 Catalyst Structure 575\u003c\/p\u003e \u003cp\u003e14.4 Polymerization Process 578\u003c\/p\u003e \u003cp\u003e14.5 Product Characterization and Applications 579\u003c\/p\u003e \u003cp\u003e14.6 Silica-Supported Reduced Silyl Chromate Catalyst Advancements 582\u003c\/p\u003e \u003cp\u003eAcknowledgements 588\u003c\/p\u003e \u003cp\u003eReferences 588\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Late Transition Metal Catalyzed Co- and Terpolymerization of α-Olefins with Carbon Monoxide:\u003c\/b\u003e \u003cb\u003eSynthesis and Modification 591\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eTimo M. J. Anselment, Manuela Zintl, Maria Leute, Rüdiger Nowack, and Bernhard Rieger\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction and Historical Overview 591\u003c\/p\u003e \u003cp\u003e15.2 Polyketone Synthesis: General Concept and Mechanism 593\u003c\/p\u003e \u003cp\u003e15.3 Influence of the Catalyst on the Polymer Structure in α-Olefin\/CO Copolymerization Reactions 599\u003c\/p\u003e \u003cp\u003e15.4 Other Olefins for the Copolymerization with CO 610\u003c\/p\u003e \u003cp\u003e15.5 Chemical Modification of Polyketones 616\u003c\/p\u003e \u003cp\u003eReferences 618\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Ethylene Polymerization and α-Olefin Oligomerization Using Catalysts Derived from Phosphoranes\u003c\/b\u003e \u003cb\u003eand Ni(II) or Ni(0) Precursors 623\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eScott Collins\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 623\u003c\/p\u003e \u003cp\u003e16.2 Starting Materials 626\u003c\/p\u003e \u003cp\u003eReferences 629\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Overview of Ring-Opening Metathesis Polymerizations (ROMP) and Acyclic Diene Metathesis\u003c\/b\u003e \u003cb\u003e(ADMET) Polymerizations with Selected Ruthenium and Molybdenum Complexes 631\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRobert T. Mathers\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 631\u003c\/p\u003e \u003cp\u003e17.2 Ruthenium Catalysts 634\u003c\/p\u003e \u003cp\u003e17.3 Molybdenum Complexes 646\u003c\/p\u003e \u003cp\u003e17.4 Summary 651\u003c\/p\u003e \u003cp\u003eReferences 651\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Copolymerization of Ethylene with Conjugated Dienes 661\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eIslem Belaid, Vincent Monteil, and Christophe Boisson\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 661\u003c\/p\u003e \u003cp\u003e18.2 Conventional\u003cbr\u003eZiegler–Natta Catalysts 663\u003c\/p\u003e \u003cp\u003e18.3 Group\u003c\/p\u003e \u003cp\u003e4 Metallocene Systems 665\u003c\/p\u003e \u003cp\u003e18.4 Group 4 Post-metallocene Catalysts 670\u003c\/p\u003e \u003cp\u003e18.5 Vanadium Bis(imino)pyridyl Catalysts 673\u003c\/p\u003e \u003cp\u003e18.6 Group 8-, 9-, and 10-Based Catalysts 674\u003c\/p\u003e \u003cp\u003e18.7 Rare Earth Catalysts 675\u003c\/p\u003e \u003cp\u003e18.8 Conclusion 686\u003c\/p\u003e \u003cp\u003eReferences 687\u003c\/p\u003e \u003cp\u003eAppendix A: Pyrophoricity of Metal Alkyls 693\u003cbr\u003e\u003ci\u003eDennis B. Malpass\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eAppendix B: Rheological Terms for Polymerization Catalyst Chemists 705\u003cbr\u003e\u003ci\u003eGregory W. Kamykowski\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003eIndex 711\u003c\/p\u003e   \u003cp\u003e \u003cstrong\u003eRAY HOFF\u003c\/strong\u003e is a former research scientist in polymerization catalysts for B.F. Goodrich, Chemplex Company, and Quantum Chemical Corporation and was a member of the adjunct faculty at Roosevelt University in Schaumburg, Illinois.      \u003c\/p\u003e\u003cp\u003e \u003cstrong\u003eThe essential guide to the methods for developing and applying polymerization catalysts, revised and updated\u003c\/strong\u003e   \u003c\/p\u003e\u003cp\u003e Revised and updated, the second edition of \u003cem\u003eHandbook of Transition Metal Polymerization Catalysts,\u003c\/em\u003e offers an essential guide to the transition metal catalysts for the polymerization of olefins. The contributing authors offer information on the detailed synthetic approaches for various categories of catalysts presented in the text. The chapters show how to prepare the catalysts used in polymerization reactions and explores their specific applications in synthesis. The text covers a wide-range of topics and offers an informative guide to the most current methods and reagents.    \u003c\/p\u003e\u003cp\u003e New information is presented on aluminum alkyl and other organometallic compounds, at least one of which is part of every Ziegler-Natta system. This revised edition also includes information on one way to set up a laboratory to test catalysts primarily for ethylene polymerization and copolymerization and presents the subject of neodymium catalysts for ethylene-diene copolymerization. This completely revised edition of \u003cem\u003eHandbook of Transition Metal Polymerization Catalysts:\u003c\/em\u003e   \u003c\/p\u003e\u003cul\u003e \u003cli\u003eContains the valuable data needed to reproduce syntheses or use the catalyst for new applications\u003c\/li\u003e \u003cli\u003eOffers a guide to the design and synthesis of catalysts and their applications in synthesis of polymers\u003c\/li\u003e \u003cli\u003eIncludes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized\u003c\/li\u003e \u003cli\u003ePresents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization\u003c\/li\u003e \u003c\/ul\u003e \u003cbr\u003e  \u003cp\u003e Written for researchers and graduate students of polymer chemistry, polymer physics, organic chemistry and others, the revised second edition of \u003cem\u003eHandbook of Transition Metal Polymerization Catalysts,\u003c\/em\u003e offers an overview and guide to the various methods for developing and applying polymerization catalysts.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989343584485,"sku":"NP9781119242130","price":269.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119242130.jpg?v=1761783746","url":"https:\/\/k12savings.com\/products\/handbook-of-transition-metal-polymerization-catalysts-isbn-9781119242130","provider":"K12savings","version":"1.0","type":"link"}