Handbook of Pyrrolidone and Caprolactam Based Materials, 6 Volume Set

Brings together, for the first time, a comprehensive review of all aspects of pyrrolidone- and caprolactam-based materials

This comprehensive, six-volume set describes the broad technical universe of γ- and ε- lactams, reviewing in-depth the chemistry of the small lactam-based molecules, uncovering their unique properties and showing how they have enabled a myriad of commercially important applications. From synthesis, through production and into applications, this extensive work targets significant and recent trends in γ- and ε-lactam science and technology and addresses all key aspects of pyrrolidone- and caprolactam-based materials to produce a definitive overview of the field.

Handbook of Pyrrolidone and Caprolactam Based Materials provides a detailed and modern portrait of the impact of pyrrolidone- and caprolactam-based materials on the world, as well as potential future possibilities.

• Volume One presents the chemistry of small lactam-based molecules and uncovers their unique properties.
• Volume Two covers polymeric materials, including polyvinyl pyrrolidone and polyvinyl caprolactam, and reviews homopolymerization, copolymerization, controlled radical polymermization and acrylate based pyrrolidone polymerizations.
• Volume Three examines the physical chemistry and molecular interactions of pyrrolidone and caprolactam based materials.
• Volume Four expands upon the characterization theme from the third volume, and includes detailed discussions of nuclear magnetic resonance (NMR) and Fourier transform-infrared (FT-IR) spectroscopy, thermal and mechanical properties, and imaging techniques.
• Volume Five explores pharmaceutical applications in both ingredients and materials, as well as the antimicrobial properties and applications of pyrrolidone and caprolactam-based materials, and their toxicology.
• Volume Six covers personal and home care, skin care, transdermal applications and wound care, oral care, adhesion related applications and digital applications such as inkjet technology.

Handbook of Pyrrolidone and Caprolactam Based Materials will appeal to industrial scientists and engineers interested in polymer development and manufacturing. It will also benefit academic researchers working in the fields of chemistry, materials science, and chemical and process engineering.Bietet erstmals eine umfassende Übersicht über alle Aspekte von auf Pyrrolidon und Caprolactam basierenden Materialien.

Das umfassende sechsbändige Werk beschreibt das breite technische Universum der Gamma- und Epsilon-Lactame. Dabei wird die Chemie der kleinen, auf Lactam basierenden Moleküle eingehend untersucht, ihre einzigartigen Eigenschaften werden dargestellt und es wird gezeigt, wie sie eine große Zahl wirtschaftlich wichtiger Anwendungen ermöglicht haben. Von der Synthese über die Produktion bis zur Anwendung werden in diesem umfangreichen Werk die wesentlichen und aktuellen Entwicklungen im Bereich der Gamma- und Epsilon-Lactam-Forschung und -Technologie aufgezeigt und alle wesentlichen Aspekte der auf Pyrrolidon und Caprolactam basierenden Materialien dargestellt, wodurch die Leser einen gründlichen Überblick über das gesamte Fachgebiet erhalten.

Das Handbook of Pyrrolidone and Caprolactam Based Materials: Synthesis, Characterization and Industrial Applications stellt in detaillierter und moderner Form dar, welchen Einfluss auf Pyrrolidon und Caprolactam basierende Materialien in der Welt haben und welche potenziellen Möglichkeiten für die Zukunft bestehen.

* In Band 1 wird die Chemie der kleinen Lactam-basierten Moleküle mit ihren einzigarten Eigenschaften dargestellt.
* In Band 2 werden polymere Materialien wie Polyvinylpyrrolidon und Polyvinylcaprolactam besprochen, zudem gibt der Autor einen Überblick über Homopolymerisation, Copolymerisation, die kontrollierte radikalische Polymerisation und die Polymerisation von Pyrrolidon auf Acrylatbasis.
* In Band 3 werden die physikalische Chemie und die molekularen Wechselwirkungen von auf Pyrrolidon und Caprolactam basierenden Materialien untersucht.
* In Band 4 wird das bereits in Band 3 angesprochene Thema der Charakterisierung erweitert, u. a. mit einer ausführlichen Darstellung der Magnetresonanztomographie (MRT) und der Fourier-Transform-Infrarot-Spektroskopie (FT-IR), der thermischen und mechanischen Eigenschaften sowie der bildgebenden Verfahren.
* In Band 5 befasst sich der Autor mit pharmazeutischen Anwendungen bei Inhaltsstoffen und Materialien sowie mit den antimikrobiellen Eigenschaften und Anwendungen von auf Pyrrolidon und Caprolactam basierenden Materialien und deren Toxikologie.
* In Band 6 werden die Bereiche Körperpflege- und Reinigungsprodukte, Hautpflege, transdermale Anwendungen und Wundpflege, Mundhygiene, Klebeanwendungen sowie digitale Anwendungen, darunter die Inkjet-Technologie, behandelt.
Das Handbook of Pyrrolidone and Caprolactam Based Materials richtet sich an Forscher und Ingenieure in der Industrie, die sich mit der Entwicklung und Herstellung von Polymeren beschäftigen. Es ist auch für Forscher in der Wissenschaft von Interesse, die in den Bereichen Chemie, Materialwissenschaften sowie Chemieingenieurwesen und Verfahrenstechnik tätig sind.

Volume 1: Synthesis Reactions

Chapter 1 Introduction to Pyrrolidone and Caprolactam

Chapter 2 Synthesis of Pyrrolidones and Caprolactams by Intramolecular Cyclization of Linear Precursors
Samuel D. Arthur and H. Keith Chenault

Chapter 3 Synthesis of Pyrrolidones and Caprolactams by Ring Modification or Multi-Component Ring-Forming Reaction
H. Keith Chenault

Chapter 4 Synthesis and Manufacturing of N-Vinyl Pyrrolidone and N-Vinyl Caprolactam
David K. Hood

Chapter 5 Transformations of N-Vinyl Pyrrolidone and N-Vinyl Caprolactam in Organic Chemistry
Fan Wu and Osama M. Musa

Volume 2: Polymerization Reactions

Chapter 6 Conventional Free Radical Polymerization of N-Vinyl pyrrolidone Homopolymers
Michael A. Tallon and Osama M. Musa

Chapter 7 Conventional Free Radical Polymerization of N-Vinyl caprolactam Homopolymers
Michael A. Tallon and Osama M. Musa

Chapter 8 Polymerization of N-vinyl lactam with (Meth)acrylate Based comonomers
Michael Tallon and Osama M. Musa

Chapter 9 Polymerization of N-vinyl lactam with Reactive Monomers
Michael A. Tallon and Osama M. Musa

Chapter 10 Synthesis of N-vinyl lactam copolymers by controlled radical polymerizations
Zheng Li; Sounak Sarkar, Yejia Li, Michael A. Tallon, and Osama M. Musa

Chapter 11 Pyrrolidone Monomers with Acrylate Functionality and their Polymers
Alan Fernyhough, David Petty, Victoria J. Cunningham, Steven P. Armes and Osama M. Musa

Chapter 12 Pyrrolidone and Caprolactam Functionalized Natural and Synthetic Polymers
Kelly A. Brush, Osama M. Musa

Volume 3: Physical Chemistry and Molecular Interactions

Chapter 13 Hydration Behaviour of Polylactam Clathrate Hydrate Inhibitors and their Small-Molecule Model Compounds
Luke I. Chambers, Amy V. Hall, Osama M. Musa, Jonathan W. Steed

Chapter 14 Cocrystals, Coamorphous Phases and Coordination Complexes of γ- and ε Lactams
Amy V. Hall, Luke I. Chambers, Osama M. Musa, Jonathan W. Steed

Chapter 15 Physicochemical, Solution, and Colloidal Properties of Pyrrolidone and Caprolactam-based Polymers
Roger L. McMullen, Raymond B. Clark, Seher Ozkan, and Laurence Senak

Chapter 16 Dilute Solution Properties and Characterization of N-Vinyl Pyrrolidone Based Polymers
Laurence Senak and Roger L. McMullen

Chapter 17 Computational Chemistry of Pyrrolidone and Caprolactam Based Materials
Solomon H. Jacobson and Osama M. Musa

Volume 4: Physical and Chemical Characterization

Chapter 18 Nuclear Magnetic Resonance Spectroscopic and Infrared Spectroscopic Characterization of Poly(N-Vinyl Pyrrolidone) and Poly(N-Vinyl Caprolactam) Polymers
Raymond B. Clark and Roger L. McMullen

Chapter 19 Rheological Characterization of N-Vinyl Pyrrolidone and N-Vinyl Caprolactam-based Polymers
Seher Ozkan and Roger L. McMullen

Chapter 20 Thermal and Mechanical Analysis of N-Vinyl Pyrrolidone and N-Vinyl Caprolactam-based Polymers
Valencia S. Johnson and Roger L. McMullen

Chapter 21 Classical and Advanced Imaging for the Characterization of Pyrrolidone and Caprolactam Based Materials
Germain Puccetti

Chapter 22 Atomic Force Microscopy, Transmission Electron Microscopy, Scanning Electron Microscopy, and Fourier Transform-Infrared Spectroscopic Imaging as Tools to Study Various Phenomena Involving Poly(vinylpyrrolidone)
Roger L. McMullen

Volume 5: Pharmaceutical Applications, Antimicrobial Properties, Safety and Toxicology

Chapter 23 Pyrrolidone and Caprolactam Based Materials in Active Pharmaceutical Ingredient (API) Applications
David K. Hood, Srinivasan Ananthraman and Osama M. Musa

Chapter 24 Development, Application, and Future trends of Pyrrolidone and Caprolactam Based Materials in the Pharmaceutical Industry
David K. Hood, Srinivasan Ananthraman and Osama M. Musa

Chapter 25 Antimicrobial Properties and Applications of Pyrrolidone and Caprolactam Based Materials
Karen Winkowski and Yevgeniy Turovskiy

Chapter 26 Safety and Toxicology of Caprolactams and Caprolactam-based Polymers
Sang-Tae Kim, Anthony Schatz, and Christopher Choi

Chapter 27 Safety and Toxicology of Pyrrolidones and Pyrrolidone-based Polymers
Sang-Tae Kim, Anthony Schatz, and Christopher Choi

Volume 6: Personal Care, Adhesives and Digital Printing

Chapter 28 Personal and Home Care Applications of Pyrrolidone- and Caprolactam-based Materials
Raymond Rigoletto and Roger L. McMullen

Chapter 29 Pyrrolidone Chemistry in Skin Care, Transdermal Delivery, and Wound Care
Roger L. McMullen

Chapter 30 Polyvinylpyrrolidone Applications in Oral Care
Petros Gebreselassie

Chapter 31 Pyrrolidone and Caprolactam Based Materials in Adhesion Related Applications
David K. Hood, Srinivasan Ananthraman and Osama M. Musa

Chapter 32 Application of Pyrrolidone and Caprolactam Based Materials in the Digital Age
David K. Hood

Osama M. Musa, PhD, is Senior Vice President and Chief Technology Officer for Ashland Inc. During his tenure at Ashland, he has led Research and Development efforts across all business segments and technical platforms, including consumer markets focused on pharmaceutical, nutraceutical, skin, hair, oral, and home care; nutrition; and agricultural and industrial markets focused on coatings, adhesives, and performance additives for energy, construction, and lithium ion batteries.

Brings together, for the first time, a comprehensive review of all aspects of pyrrolidone- and caprolactam-based materials

This comprehensive, six-volume set describes the broad technical universe of γ- and ε- lactams, reviewing in-depth the chemistry of the small lactam-based molecules, uncovering their unique properties and showing how they have enabled a myriad of commercially important applications. From synthesis, through production and into applications, this extensive work targets significant and recent trends in γ- and ε-lactam science and technology and addresses all key aspects of pyrrolidone- and caprolactam-based materials to produce a definitive overview of the field.

Handbook of Pyrrolidone and Caprolactam Based Materials: Synthesis, Characterization and Industrial Applications provides a detailed and modern portrait of the impact of pyrrolidone- and caprolactam-based materials on the world, as well as potential future possibilities.

• Volume One presents the chemistry of small lactam-based molecules and uncovers their unique properties.
• Volume Two covers polymeric materials, including polyvinyl pyrrolidone and polyvinyl caprolactam, and reviews homopolymerization, copolymerization, controlled radical polymermization and acrylate based pyrrolidone polymerizations.
• Volume Three examines the physical chemistry and molecular interactions of pyrrolidone and caprolactam based materials.
• Volume Four expands upon the characterization theme from the third volume, and includes detailed discussions of nuclear magnetic resonance (NMR) and Fourier transform-infrared (FT-IR) spectroscopy, thermal and mechanical properties, and imaging techniques.
• Volume Five explores pharmaceutical applications in both ingredients and materials, as well as the antimicrobial properties and applications of pyrrolidone and caprolactam-based materials, and their toxicology.
• Volume Six covers personal and home care, skin care, transdermal applications and wound care, oral care, adhesion related applications and digital applications such as inkjet technology.

Handbook of Pyrrolidone and Caprolactam Based Materials will appeal to industrial scientists and engineers interested in polymer development and manufacturing. It will also benefit academic researchers working in the fields of chemistry, materials science, and chemical and process engineering.