{"product_id":"the-organometallic-chemistry-of-the-transition-metals-isbn-9781119465881","title":"The Organometallic Chemistry of the Transition Metals","description":"\u003cp\u003e\u003cb\u003eProvides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eFully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eThe Organometallic Chemistry of the Transition Metals, Seventh Edition\u003c\/i\u003e provides new\/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more.\u003c\/p\u003e \u003cul\u003e \u003cli\u003eProvides an excellent foundation of the fundamentals of organometallic chemistry\u003c\/li\u003e \u003cli\u003eIncludes end-of-chapter problems and their solutions\u003c\/li\u003e \u003cli\u003eExpands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry\u003c\/li\u003e \u003cli\u003eFeatures all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e\u003ci\u003eThe Organometallic Chemistry of the Transition Metals, Seventh Edition\u003c\/i\u003e is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.\u003c\/p\u003e \u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003eAcknowledgments xiii\u003c\/p\u003e \u003cp\u003eList of Abbreviations xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Why Study Organometallic Chemistry? 1\u003c\/p\u003e \u003cp\u003e1.2 Coordination Chemistry 3\u003c\/p\u003e \u003cp\u003e1.3 Werner Complexes 3\u003c\/p\u003e \u003cp\u003e1.4 The Trans Effect 7\u003c\/p\u003e \u003cp\u003e1.5 Soft Versus Hard Ligands 9\u003c\/p\u003e \u003cp\u003e1.6 The Crystal Field 10\u003c\/p\u003e \u003cp\u003e1.7 The Ligand Field 17\u003c\/p\u003e \u003cp\u003e1.8 Two-Electron Three-Center Bonding 19\u003c\/p\u003e \u003cp\u003e1.9 Four-Electron Three-Center Bonding 20\u003c\/p\u003e \u003cp\u003e1.10 Back Bonding 22\u003c\/p\u003e \u003cp\u003e1.11 Trends in d Orbital Energies 26\u003c\/p\u003e \u003cp\u003e1.12 Types of Ligand 27\u003c\/p\u003e \u003cp\u003eReferences 32\u003c\/p\u003e \u003cp\u003eProblems 33\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Making Sense of Organometallics 35\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 The 18-Electron Rule 35\u003c\/p\u003e \u003cp\u003e2.2 Limitations of the 18-Electron Rule 43\u003c\/p\u003e \u003cp\u003e2.3 Electron Counting in Reactions 45\u003c\/p\u003e \u003cp\u003e2.4 The Oxidation State Concept and its Limitations 46\u003c\/p\u003e \u003cp\u003e2.5 Electroneutrality 52\u003c\/p\u003e \u003cp\u003e2.6 Coordination Number and Geometry 53\u003c\/p\u003e \u003cp\u003e2.7 Effects of Complexation 56\u003c\/p\u003e \u003cp\u003e2.8 Differences between Metals 58\u003c\/p\u003e \u003cp\u003eReferences 62\u003c\/p\u003e \u003cp\u003eProblems 63\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Alkyls and Hydrides 65\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Alkyls and Aryls 65\u003c\/p\u003e \u003cp\u003e3.2 Other σ-Bonded Ligands 79\u003c\/p\u003e \u003cp\u003e3.3 Metal Hydrides 80\u003c\/p\u003e \u003cp\u003e3.4 Sigma Complexes 83\u003c\/p\u003e \u003cp\u003e3.5 Bond Strengths 86\u003c\/p\u003e \u003cp\u003eReferences 88\u003c\/p\u003e \u003cp\u003eProblems 89\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Ligand Substitution 91\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Metal Carbonyls 91\u003c\/p\u003e \u003cp\u003e4.2 Phosphines 100\u003c\/p\u003e \u003cp\u003e4.3 \u003ci\u003eN\u003c\/i\u003e-Heterocyclic Carbenes 103\u003c\/p\u003e \u003cp\u003e4.4 Dissociative Substitution 105\u003c\/p\u003e \u003cp\u003e4.5 Associative Substitution 109\u003c\/p\u003e \u003cp\u003e4.6 Redox Effects and Interchange Substitution 111\u003c\/p\u003e \u003cp\u003e4.7 Photochemical Substitution 113\u003c\/p\u003e \u003cp\u003e4.8 Counterions and Solvents in Substitution 115\u003c\/p\u003e \u003cp\u003eReferences 116\u003c\/p\u003e \u003cp\u003eProblems 118\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Pi Complexes 121\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Alkene and Alkyne Complexes 121\u003c\/p\u003e \u003cp\u003e5.2 Allyl Complexes 126\u003c\/p\u003e \u003cp\u003e5.3 Diene Complexes 130\u003c\/p\u003e \u003cp\u003e5.4 Cyclopentadienyl Complexes 133\u003c\/p\u003e \u003cp\u003e5.5 Arenes and Other Alicyclic Ligands 140\u003c\/p\u003e \u003cp\u003e5.6 Metalacycles 143\u003c\/p\u003e \u003cp\u003e5.7 Stability of Polyene and Polyenyl Complexes 144\u003c\/p\u003e \u003cp\u003eReferences 145\u003c\/p\u003e \u003cp\u003eProblems 145\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Oxidative Addition and Reductive Elimination 147\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 147\u003c\/p\u003e \u003cp\u003e6.2 Concerted Additions 149\u003c\/p\u003e \u003cp\u003e6.3 S\u003csub\u003eN\u003c\/sub\u003e2 Pathways 152\u003c\/p\u003e \u003cp\u003e6.4 Radical Mechanisms 153\u003c\/p\u003e \u003cp\u003e6.5 Ionic Mechanisms 155\u003c\/p\u003e \u003cp\u003e6.6 Reductive Elimination 156\u003c\/p\u003e \u003cp\u003e6.7 Sigma Bond Metathesis 162\u003c\/p\u003e \u003cp\u003e6.8 Ligand-Assisted 1,2-Additions and Eliminations 163\u003c\/p\u003e \u003cp\u003e6.9 Oxidative Coupling 164\u003c\/p\u003e \u003cp\u003e6.10 Proton-Coupled Electron Transfer 165\u003c\/p\u003e \u003cp\u003eReferences 166\u003c\/p\u003e \u003cp\u003eProblems 167\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Insertion and Elimination 169\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 169\u003c\/p\u003e \u003cp\u003e7.2 1,1-Insertion 171\u003c\/p\u003e \u003cp\u003e7.3 1,2-Insertion 175\u003c\/p\u003e \u003cp\u003e7.4 Outer Sphere Insertions 179\u003c\/p\u003e \u003cp\u003e7.5 α-,β-,γ- and δ-Elimination 180\u003c\/p\u003e \u003cp\u003eReferences 182\u003c\/p\u003e \u003cp\u003eProblems 182\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Addition and Abstraction 185\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 185\u003c\/p\u003e \u003cp\u003e8.2 Nucleophilic Addition to CO 187\u003c\/p\u003e \u003cp\u003e8.3 Nucleophilic Addition to Polyenes and Polyenyls 189\u003c\/p\u003e \u003cp\u003e8.4 Nucleophilic Abstraction 196\u003c\/p\u003e \u003cp\u003e8.5 Electrophilic Addition and Abstraction 197\u003c\/p\u003e \u003cp\u003e8.6 Single-Electron Transfer and Radical Reactions 200\u003c\/p\u003e \u003cp\u003eReferences 201\u003c\/p\u003e \u003cp\u003eProblems 202\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Homogeneous Catalysis 205\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Catalytic Cycles 205\u003c\/p\u003e \u003cp\u003e9.2 Alkene Isomerization 211\u003c\/p\u003e \u003cp\u003e9.3 Hydrogenation 213\u003c\/p\u003e \u003cp\u003e9.4 Alkene Hydroformylation 221\u003c\/p\u003e \u003cp\u003e9.5 Alkene Hydrocyanation 223\u003c\/p\u003e \u003cp\u003e9.6 Alkene Hydrosilylation 224\u003c\/p\u003e \u003cp\u003e9.7 Coupling Reactions 225\u003c\/p\u003e \u003cp\u003e9.8 Organometallic Oxidation Catalysis 227\u003c\/p\u003e \u003cp\u003e9.9 Electrocatalysis 229\u003c\/p\u003e \u003cp\u003e9.10 Photoredox Catalysis 229\u003c\/p\u003e \u003cp\u003e9.11 Surface Supported Single-Atom and Cooperative Catalysis 231\u003c\/p\u003e \u003cp\u003eReferences 233\u003c\/p\u003e \u003cp\u003eProblems 235\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Physical Methods 239\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Mechanism 239\u003c\/p\u003e \u003cp\u003e10.2 1H NMR Spectroscopy 240\u003c\/p\u003e \u003cp\u003e10.3 13C NMR Spectroscopy 243\u003c\/p\u003e \u003cp\u003e10.4 31P NMR Spectroscopy 244\u003c\/p\u003e \u003cp\u003e10.5 Dynamic NMR 246\u003c\/p\u003e \u003cp\u003e10.6 Spin Saturation Transfer 249\u003c\/p\u003e \u003cp\u003e10.7 \u003ci\u003eT\u003c\/i\u003e\u003csub\u003e1\u003c\/sub\u003e and the Nuclear Overhauser Effect 250\u003c\/p\u003e \u003cp\u003e10.8 IR Spectroscopy 254\u003c\/p\u003e \u003cp\u003e10.9 Crystallography 256\u003c\/p\u003e \u003cp\u003e10.10 Electrochemistry and EPR 257\u003c\/p\u003e \u003cp\u003e10.11 Computation 259\u003c\/p\u003e \u003cp\u003e10.12 Other Methods 260\u003c\/p\u003e \u003cp\u003eReferences 262\u003c\/p\u003e \u003cp\u003eProblems 263\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 M–L Multiple Bonds 265\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Carbenes 265\u003c\/p\u003e \u003cp\u003e11.2 Schrock Carbenes 272\u003c\/p\u003e \u003cp\u003e11.3 Carbynes 276\u003c\/p\u003e \u003cp\u003e11.4 Bridging Carbenes and Carbynes 278\u003c\/p\u003e \u003cp\u003e11.5 \u003ci\u003eN\u003c\/i\u003e-Heterocyclic Carbenes 279\u003c\/p\u003e \u003cp\u003e11.6 Multiple Bonds to Heteroatoms 282\u003c\/p\u003e \u003cp\u003eReferences 285\u003c\/p\u003e \u003cp\u003eProblems 286\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Metathesis Polymerization and Bond Activation 289\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Alkene Metathesis 289\u003c\/p\u003e \u003cp\u003e12.2 Alkene Dimerization, Oligomerization, and Polymerization 295\u003c\/p\u003e \u003cp\u003e12.3 Activation of CO and CO\u003csub\u003e2\u003c\/sub\u003e 301\u003c\/p\u003e \u003cp\u003e12.4 C−H Activation 305\u003c\/p\u003e \u003cp\u003e12.5 Dehydrogenative Oxidation and Hydrogen Borrowing 309\u003c\/p\u003e \u003cp\u003eReferences 311\u003c\/p\u003e \u003cp\u003eProblems 313\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Green Energy and Materials Applications 317\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Green Chemistry 317\u003c\/p\u003e \u003cp\u003e13.2 Energy Chemistry 320\u003c\/p\u003e \u003cp\u003e13.3 Clusters and Nanoparticles 323\u003c\/p\u003e \u003cp\u003e13.4 Organometallic Materials 325\u003c\/p\u003e \u003cp\u003eReferences 332\u003c\/p\u003e \u003cp\u003eProblems 334\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Organic Applications 337\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Carbon–Carbon and Carbon–Heteroatom Coupling 338\u003c\/p\u003e \u003cp\u003e14.2 Metathesis 343\u003c\/p\u003e \u003cp\u003e14.3 Cyclopropanation and C–H Insertion 345\u003c\/p\u003e \u003cp\u003e14.4 Hydrogenation 346\u003c\/p\u003e \u003cp\u003e14.5 Carbonylation 348\u003c\/p\u003e \u003cp\u003e14.6 Oxidation 350\u003c\/p\u003e \u003cp\u003e14.7 C–H Activation 352\u003c\/p\u003e \u003cp\u003e14.8 Click Chemistry and Cycloaddition 355\u003c\/p\u003e \u003cp\u003e14.9 Photoredox Catalysis 356\u003c\/p\u003e \u003cp\u003eReferences 359\u003c\/p\u003e \u003cp\u003eProblems 360\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Paramagnetic and High-Oxidation-State Complexes 363\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Magnetism and Spin States 364\u003c\/p\u003e \u003cp\u003e15.2 Cyclopentadienyl Complexes 371\u003c\/p\u003e \u003cp\u003e15.3 f-Block Complexes 373\u003c\/p\u003e \u003cp\u003eReferences 380\u003c\/p\u003e \u003cp\u003eProblems 381\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Bioorganometallic Chemistry 383\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 384\u003c\/p\u003e \u003cp\u003e16.2 Coenzyme B\u003csub\u003e12\u003c\/sub\u003e 388\u003c\/p\u003e \u003cp\u003e16.3 Nitrogen Fixation 394\u003c\/p\u003e \u003cp\u003e16.4 Nickel Enzymes 402\u003c\/p\u003e \u003cp\u003e16.5 Artificial Enzymes 407\u003c\/p\u003e \u003cp\u003e16.6 Biomedical and Biocatalytic Applications 407\u003c\/p\u003e \u003cp\u003eReferences 410\u003c\/p\u003e \u003cp\u003eProblems 412\u003c\/p\u003e \u003cp\u003eAppendix A: Useful Texts on Allied Topics 415\u003c\/p\u003e \u003cp\u003eAppendix B: Major Reaction Types 419\u003c\/p\u003e \u003cp\u003eSolutions to Problems 421\u003c\/p\u003e \u003cp\u003eIndex 437\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eRobert H. Crabtree F.R.S.\u003c\/b\u003e is Whitehead Professor of Chemistry at Yale, a Fellow of the Royal Society and of the American Chemical Society, and a member of the American Academy and of the National Academy of Sciences.   \u003c\/p\u003e\u003cp\u003e\u003cb\u003eProvides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eFully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry. \u003c\/p\u003e\u003cp\u003e\u003ci\u003eThe Organometallic Chemistry of the Transition Metals, Seventh Edition\u003c\/i\u003e provides new\/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more. \u003c\/p\u003e\u003cul\u003e \u003cli\u003eProvides an excellent foundation of the fundamentals of organometallic chemistry\u003c\/li\u003e \u003cli\u003eIncludes end-of-chapter problems and their solutions\u003c\/li\u003e \u003cli\u003eExpands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry\u003c\/li\u003e \u003cli\u003eFeatures all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e\u003ci\u003eThe Organometallic Chemistry of the Transition Metals, Seventh Edition\u003c\/i\u003e is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47990305816805,"sku":"NP9781119465881","price":94.5,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119465881.jpg?v=1761787283","url":"https:\/\/k12savings.com\/es\/products\/the-organometallic-chemistry-of-the-transition-metals-isbn-9781119465881","provider":"K12savings","version":"1.0","type":"link"}