The Analytical Chemistry of Silicones

High-Resolution Solid-State NMR of Silicates and Zeolites Gunter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials." --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments. 1988 (0 471-91597-1) 485 pp. The Chemistry of Silica Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry Ralph K. Iler A major component of the earth's solid surface and the constituent of sand, silica--an ageless natural staple--is also integral to industries as diverse as chemistry, biology, medicine, agriculture, metallurgy, and mining. This landmark reference details the chemistry surrounding the research and development of silica as well as information on its production and production control. 1979 (0 471-02404-X) 866 pp. The Chemistry of Organic Silicon Compounds Parts 1 and 2 Edited by Saul Patai and Zvi Rappoport "This volume will probably become the first reference consulted for C-Si chemistry." --Choice This authoritative account of organic compounds containing carbon-silicon bonds brings specialists up-to-date to the field's latest innovative turns. The emphasis in this compilation of studies--from 17 prominent researchers--is on small molecules, single bonds, analysis, structure, synthesis, spectroscopy, and reaction mechanisms. Part 1:1989 (0 471-91441-X) 892 pp. Part 2:1989 (0 471-91992-6) 1,668 pp. THE PROBLEM-ORIENTED APPROACH.

The Analytical Chemistry of Organosilicon Materials (A.Smith).

Analysis of Polymers, Mixtures, and Compositions (N.Angelotti).

Trace Analysis Involving Silicones (A. Smith & R.Parker).

Analysis of Surfaces (M. Owen).

Personal Care Applications (H. Klimisch).

THE BASIC TECHNIQUES.

Physical Properties and Polymer Structure (O. Flaningam & N.Langley).

Chemical Analysis (M. Gaul & N. Angelotti).

Microscopical Characterization (H. Freeman & R. Durall).

Chromatographic Methods (R. Steinmeyer & M. Becker).

Infrared, Raman, Near-Infrared, and Ultraviolet Spectroscopy (E.Lipp & A. Smith).

Nuclear Magnetic Resonance Spectroscopy (R. Taylor, et al.).

Mass Spectrometry (J. Moore).

Atomic Spectroscopy (N. Lytle).

X-Ray Methods (D. Peterson, et al.).

Appendix.

References.

Index. About the editor Albert Lee Smith is Scientist Emeritus at Dow Corning Corporation. In the past he has served in a variety of capacities for Dow Corning, including manager of its analytical department, analytical scientist, and global analytical coordinator. Dr. Smith is a recipient of the Williams-Wright Award (1987) and the American Chemical Society Local Section Award for outstanding achievement and promotion of the chemical sciences (1988). He has been president of the Coblentz Society and chairman of the Joint Committee on Atomic and Molecular Physical Data. Dr. Smith received his PhD in physical chemistry from Ohio State University. He is the author of Applied Infrared Spectroscopy (Wiley, 1979). The new universe of innovative analytical techniques in chemistry—Fourier transform spectroscopy, near-infrared spectroscopy, a variety of surface analysis techniques, chemometrics and computerized instrumentation—has been matched in innovative velocity only by the phenomenal rise in uses for organosilicon materials. Indispensable as high-performance materials in industrial processes and products and in medical and biological applications, silicones offer a versatile new language for chemistry—whose syntax is understood through analytical technology. The Analytical Chemistry of Silicones is a guide to understanding the unique chemistry of organosilicon materials—a valuable compendium for chemists and engineers that covers techniques for analyzing, and analyzing for, organosilicon compounds. By frequently illustrating approaches with problems of current interest, the authors provide the reader with an up-to-the-minute glimpse into silicone chemistry’s full structural and analytical permutations. Inside, readers will find:

• Methods of analyzing for silicones —from parts per billion to 100%, both in bulk materials and on surfaces
• Analysis of products and formulations—from coatings and cosmetics to surfactants and textile treatments
• Analysis for traces of silicones—in foods, soil, water, air, medical devices, and biological samples
• Proven methods for analyzing organosilicon monomers and polymers for composition and structure
• Experimental methods for determining physical properties and polymer structure
• Microscopical characterization techniques—from optical to analytical electron microscopy
• Chromatographic, NMR, IR, mass spectrometric, atomic spectroscopic, and X-ray methods, and other key techniques—with emphasis on their uses in characterizing silicones
• Up-to-date tables of physical property data for many monomers and oligomers, GC response factors, IR group frequencies, and NMR shiftsA comprehensive bibliography of relevant literature citations, including titles

A synthesis of information and data heretofore unavailable in a single source, this first-of-a-kind resource allows chemical engineers or research chemists, analytical generalists, and analytical specialists—with varying degrees of familiarity with analytical chemistry or silicones—to become conversant with both the techniques of analysis and science of silicones, allowing for the swift and economical solution to analytical problems. Invaluable for its breadth of coverage and practical detail, The Analytical Chemistry of Silicones is the essential primer to the infinitely useful and unfolding chemistry of organosilicon materials. High-Resolution Solid-State NMR of Silicates and Zeolites Günter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials." —Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments. 1988 (0 471-91597-1) 485 pp. The Chemistry of Silica Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry Ralph K. Iler A major component of the earth’s solid surface and the constituent of sand, silica—an ageless natural staple—is also integral to industries as diverse as chemistry, biology, medicine, agriculture, metallurgy, and mining. This landmark reference details the chemistry surrounding the research and development of silica as well as information on its production and production control. 1979 (0 471-02404-X) 866 pp. The Chemistry of Organic Silicon Compounds Parts 1 and 2 Edited by Saul Patai and Zvi Rappoport "This volume will probably become the first reference consulted for C-Si chemistry…" —Choice This authoritative account of organic compounds containing carbon-silicon bonds brings specialists up-to-date to the field’s latest innovative turns. The emphasis in this compilation of studies—from 17 prominent researchers—is on small molecules, single bonds, analysis, structure, synthesis, spectroscopy, and reaction mechanisms. Part 1:1989 (0 471-91441-X) 892 pp. Part 2:1989 (0 471-91992-6) 1,668 pp.