{"product_id":"physical-chemistry-for-the-chemical-and-biological-sciences-isbn-9781891389061","title":"Physical Chemistry for the Chemical and Biological Sciences","description":"Phsyical Chemistry for the Chemical and Biological Sciences is an ideal choice for classes geared toward pre-medical and life sciences students.\u003cbr\u003eHailed by advance reviewers as “a kinder, gentler P. Chem. text,” this book meets the needs of a full-year course in physical chemistry. It is an ideal choice for classes geared toward pre-medical and life sciences students. Or, as stated in a May 2001 review in Journal of Chemical Education, “this text meets these students where they are and opens the door to physical chemistry from a perspective they can appreciate.”  Physical Chemistry for the Chemical and Biological Sciences offers a wealth of applications to chemical and biological problems, numerous chapter-ending exercises, and an accompanying solutions manual. Well known for his clear writing and careful pedagogical approach, Raymond Chang has developed yet another masterpiece in chemical education.Key Features:-a student-oriented, highly readable text-traditional and flexible organization-a functional and pleasing two-color format-many worked examples in text-@1000 chapter-ending problems-an overview of key equations in each chapter-a glossary of key terms-answers provided to even-numbered computational problemsTranslated into Italian, Japanese, Korean, Spanish \u0026amp; PortugeseTable of ContentsChapter 1 Introduction1.1 Nature of Physical Chemistry1.2 UnitsForcePressureEnergy1.3 Atomic Mass, Molecular Mass, and the Chemical MoleChapter 2 The Gas Laws2.1 Some Basic Definitions2.2 An Operational Definition of Temperature2.3 Boyle's Law2.4 Charles' and Gay-Lussac's Law2.5 Avogadro's Law2.6 The Ideal Gas Equation2.7 Dalton's Law of Partial Pressures2.8 Real GasesThe van der Waals EquationThe Virial Equation of State2.9 Condensation of Gases and the Critical StateChapter 3 Kinetic Theory of Gases3.1 The Model3.2 Pressure of a Gas3.3 Kinetic Energy and Temperature3.4 The Maxwell Distribution Laws3.5 Molecular Collisions and the Mean Free Path3.6 Gas Viscosity3.7 Graham's Laws of Diffusion and Effusion3.8 Equipartition of EnergyAppendix 3.1 Derivation of Equation (3.24)Appendix 3.2 Total and Partial DifferentiationChapter 4 The First Law of Thermodynamics4.1 Work and HeatWorkHeat4.2 The First Law of Thermodynamics4.3 Enthalpy4.4 A Closer Look at Heat Capacities4.5 Gas ExpansionIsothermal ExpansionAdiabatic Expansion4.6 ThermochemistryStandard Enthalpy of FormationDependence of Enthalpy of Reaction on Temperature4.7 Bond Energies and Bond EnthalpiesBond Enthalpy and Bond Dissociation EnthalpyAppendix 4.1 Exact and Inexact DifferentialsChapter 5 The Second Law of Thermodynamics5.1 Spontaneous Processes5.2 EntropyStatistical Definition of EntropyThermodynamic Definition of Entropy5.3 The Carnot Heat EngineThermodynamic EfficiencyThe Entropy FunctionRefrigerators, Air Conditioners, and Heat Pumps5.4 The Second Law of Thermodynamics5.5 Entropy ChangesEntropy Change due to Mixing of Ideal GasesEntropy Change due to Phase TransitionsEntropy Change due to Heating5.6 The Third Law of ThermodynamicsThird-Law or Absolute EntropiesEntropy of Chemical Reactions5.7 Residual EntropyAppendix 5.1 Statements of the Second Law of ThermodynamicsChapter 6 Gibbs and Helmholtz Energies and Their Applications6.1 Gibbs and Helmholtz Energies6.2 Meaning of Helmholtz and Gibbs EnergiesHelmholtz EnergyGibbs Energy6.3 Standard Molar Gibbs Energy of Formation (ÆfG°)6.4 Dependence of Gibbs Energy on Temperature and PressureDependence of G on TemperatureDependence of G on Pressure6.5 Gibbs Energy and Phase EquilibriaThe Clapeyron and Clausius-Clapeyron EquationsPhase DiagramsThe Phase Rule6.6 Thermodynamics of Rubber ElasticityAppendix 6.1 Some Thermodynamic RelationshipsAppendix 6.2 Derivation of the Phase RuleChapter 7 Nonelectrolyte Solutions7.1 Concentration UnitsPercent by WeightMole fraction (x)Molarity (M)Molality (m)7.2 Partial Molar QuantitiesPartial Molar VolumePartial Molar Gibbs Energy7.3 The Thermodynamics of Mixing7.4 Binary Mixtures of Volatile Liquids7.5 Real SolutionsThe Solvent ComponentThe Solute Component7.6 Phase Equilibria of Two-Component SystemsDistillationSolid-Liquid Equilibria7.7 Colligative PropertiesVapor-Pressure LoweringBoiling-Point ElevationFreezing-Point DepressionOsmotic PressureChapter 8 Electrolyte Solutions8.1 Electrical Conduction in SolutionSome Basic DefinitionsDegree of DissociationIonic MobilityApplications of Conductance Measurements8.2 A Molecular View of the Solution Process8.3 Thermodynamics of Ions in SolutionEnthalpy, Entropy, and Gibbs Energy of Formation of Ions in Solution8.4 Ionic Activity8.5 Debye-Huckel Theory of ElectrolytesThe Salting-In and Salting-Out Effects8.6 Colligative Properties of Electrolyte SolutionsThe Donnan Effect8.7 Biological MembranesMembrane TransportAppendix 8.1 Notes on ElectrostaticsAppendix 8.2 The Donnan Effect Involving Proteins Bearing Multiple ChargesChapter 9 Chemical Equilibrium9.1 Chemical Equilibrium in Gaseous SystemsIdeal GasesReal Gases9.2 Reactions in Solution9.3 Heterogeneous Equilibria9.4 The Influence of Temperature, Pressure, and Catalysts on the Equilibrium ConstantThe Effect of TemperatureThe Effect of PressureThe Effect of a Catalyst9.5 Binding of Ligands and Metal Ions to MacromoleculesOne Binding Site per Macromoleculen Equivalent Binding Sites per MacromoleculeEquilibrium Dialysis9.6 BioenergeticsThe Standard State in BiochemistryATP - The Currency of EnergyPrinciples of Coupled ReactionsGlycolysisSome Limitations of ThermodynamicsAppendix 9.1 The Relationship Between Fugacity and PressureAppendix 9.2 The Relationships Between K1 and K2 and the Intrinsic Dissociation Constant KChapter 10 Electrochemistry10.1 Electrochemical Cells10.2 Single-Electrode Potential10.3 Thermodynamics of Electrochemical CellsThe Nernst EquationTemperature Dependence of EMF10.4 Types of ElectrodesMetal ElectrodesGas ElectrodesMetal-Insoluble Salt ElectrodesGas ElectrodesThe Glass ElectrodeIon-Selective Electrodes10.5 Types of Electrochemical CellsConcentration CellsFuel Cells10.6 Applications of EMF MeasurementsDetermination of Activity CoefficientsDetermination of pH10.7 Potentiometric Titration of Redox Reactions10.8 Biological OxidationThe Chemiosmotic Theory of Oxidative Phosphorylation10.9 Membrane PotentialThe Goldman EquationThe Action PotentialChapter 11 Acids and Bases11.1 Definitions of Acids and Bases11.2 Dissociation of Acids and BasesThe Ion Product of Water and the pH scaleThe Relationship Between the Dissociation Constant of An Acid and Its Conjugate Base11.3 Salt Hydrolysis11.4 Acid-Base TitrationsAcid-Base Indicators11.5 Diprotic and Polyprotic Acids11.6 Amino AcidsDissociation of Amino AcidsIsoelectric Point11.7 Buffer SolutionsEffect of Ionic Strength and Temperature on Buffer SolutionsPreparing a Buffer Solution With a Specific pHBuffer Capacity11.8 Maintaining the pH of BloodAppendix 11.1 A More Exact Treatment of Acid-Base EquilibriaChapter 12 Chemical Kinetics12.1 Reaction Rate12.2 Reaction OrderZero-Order ReactionsFirst-Order ReactionsSecond-Order ReactionsDetermination of Reaction Order12.3 Molecularity of a ReactionUnimolecular ReactionsBimolecular ReactionsTermolecular Reactions12.4 More Complex ReactionsReversible ReactionsConsecutive ReactionsChain Reactions12.5 Effect of Temperature on Reaction RatesThe Arrhenius Equation12.6 Potential-Energy Surfaces12.7 Theories of Reaction RatesCollision TheoryTransition-State TheoryThermodynamic Formulation of the Transition-State Theory12.8 Isotope Effects in Chemical Reactions12.9 Reactions in Solution12.10 Fast Reactions in SolutionThe Flow MethodThe Relaxation Method12.10 Oscillating ReactionsAppendix 12.1 Derivation of Equation (12.9)Appendix 12.2 Derivation of Equation (12.38)Chapter 13 Enzyme Kinetics13.1 General Principles of CatalysisEnzyme Catalysis13.2 The Equations of Enzyme KineticsMichaelis-Menten KineticsSteady-State KineticsThe Significance of KM and Vmax13.3 Chymotrypsin: A Case Study13.4 Multisubstrate SystemsThe Sequential MechanismThe Nonsequential or \"Ping-Pong\" Mechanism13.5 Enzyme InhibitionReversible InhibitionIrreversible Inhibitions13.6 Allosteric InteractionsOxygen Binding to Myoglobin and HemoglobinThe Hill EquationThe Concerted ModelThe Sequential ModelConformational Changes in Hemoglobin Induced by Oxygen Binding13.7 pH Effects on Enzyme KineticsAppendix 13.1 Kinetic Analysis of the Hydrolysis of p-Nitrophenyl Trimethylacetate Catalyzed by ChymotrypsinAppendix 13.2 Derivations of Equations (13.17) and (13.19)Appendix 13.3 Derivation of Equation (13.32)Chapter 14 Quantum Mechanics14.1 The Wave Theory of Light14.2 Planck's Quantum Theory14.3 The Photoelectric Effect14.4 Bohr's Theory of Hydrogen Emission Spectra14.5 de Broglie's Postulate14.6 The Heisenberg Uncertainty Principle14.7 The Schrodinger Wave Equation14.8 Particle in a One Dimensional BoxElectronic Spectra of Polyenes14.9 Quantum-Mechanical Tunneling14.10 The Schrodinger Wave Equation for the Hydrogen AtomAtomic Orbitals14.11 Many-Electron Atoms and the Periodic TableElectron ConfigurationsVariations in Periodic PropertiesChapter 15 The Chemical Bond15.1 Lewis Structures15.2 Valence Bond Theory15.3 Hybridization of Atomic OrbitalsMethane (CH4)Ethylene (C2H4)Acetylene (C2H2)15.4 Electronegativity and Dipole MomentsElectronegativityDipole Moment15.5 Molecular Orbital Theory15.6 Diatomic MoleculesHomonuclear Diatomic Molecules of the Second-Period ElementsHeteronuclear Diatomic Molecules of the First and Second-Period Elements15.7 Resonance and Electron DelocalizationThe Peptide Bond15.8 Coordination CompoundsCrystal Field TheoryMolecular Orbital TheoryValence Bond Theory15.9 Coordination Compounds in Biological SystemsChapter 16 Intermolecular Forces16.1 Intermolecular Interactions16.2 The Ionic Bond16.3 Types of Intermolecular ForcesDipole-Dipole InteractionIon-Dipole InteractionIon-Induced Dipole and Dipole-Induced Dipole InteractionsDispersion or London InteractionsRepulsive and Total InteractionsThe Role of Dispersion Forces in Sickle-Cell Anemia16.4 The Hydrogen Bond16.5 Structure and Properties of WaterStructure of IceStructure of WaterSome Physiochemical Properties of Water16.4 The Hydrophobic InteractionChapter 17 Spectroscopy17.1 VocabularyAbsorption and EmissionUnitsRegions of the SpectrumLine WidthResolutionIntensitySelection RulesSignal-to-Noise RatioThe Beer-Lambert Law17.2 Microwave Spectroscopy17.3 Infrared SpectroscopySimultaneous Vibrational and Rotational Transitions17.4 Electronic SpectroscopyOrganic MoleculesTransition Metal ComplexesMolecules that Undergo Charge-Transfer InteractionsApplication of the Beer-Lambert Law17.5 Nuclear Magnetic Resonance SpectroscopyThe Boltzmann DistributionChemical ShiftsSpin-Spin CouplingNMR and Rate ProcessesNMR of Nuclei Other Than 1H17.6 Electron Spin Resonance Spectroscopy17.7 Fluorescence and PhosphorescenceFluorescencePhosphorescence17.8 LasersProperties and Applications of Laser LightAppendix 17.1 Fourier-Transform SpectroscopyChapter 18 Molecular Symmetry and Optical Activity18.1 Symmetry of MoleculesProper Rotation AxisPlane of SymmetryCenter of SymmetryImproper Rotation AxisMolecular Symmetry and Dipole MomentMolecular Symmetry and Optical Activity18.2 Polarized Light and Optical Rotation18.3 Optical Rotatory Dispersion and Circular DichroismChapter 19 Photochemistry and Photobiology19.1 IntroductionThermal versus Photochemical ReactionsPrimary versus Secondary ProcessesQuantum YieldsMeasurement of Light IntensityAction Spectrum19.2 Earth's AtmosphereComposition of the AtmosphereRegions of the AtmosphereResidence Time19.3 The Greenhouse Effect19.4 Photochemical SmogFormation of Nitrogen OxidesFormation of O3 • Formation of Hydroxyl RadicalFormation of Other Secondary PollutantsHarmful Effects and Prevention of Photochemical Smog19.5 The Essential Role of Ozone in the StratosphereFormation of the Ozone LayerDestruction of OzonePolar Ozone HolesWays to Curb Ozone Depletion19.6 PhotosynthesisThe ChloroplastChlorophyll and Other Pigment MoleculesThe Reaction CenterPhotosystems I and IIDark Reactions19.7 VisionStructure of RhodopsinMechanism of VisionRotation About the C=C Bond19.8 Biological Effects of RadiationSunlight and Skin CancerLight-Activated DrugsChapter 20 The Solid State20.1 Classification of Crystal Systems20.2 The Bragg Equation20.3 Structural Determination by X-ray DiffractionThe Powder MethodDetermination of the Crystal Structure of NaClThe Structure FactorNeutron Diffraction20.4 Types of CrystalsMetallic CrystalsIonic CrystalsCovalent CrystalsMolecular CrystalsAppendix 20.1 Derivation of Equation (20.3)Chapter 21 The Liquid State21.1 Structure of Liquids21.2 Viscosity21.3 Surface TensionThe Capillary-Rise MethodSurface Tension in the Lungs21.4 DiffusionFick's Laws of Diffusion21.5 Liquid CrystalsThermotropic Liquid CrystalsLyotropic Liquid CrystalsAppendix 21.1 Derivation of Equation (21.13)Chapter 22 Macromolecules22.1 Methods for Determining the Size, Shape, and Molar Mass of MacromoleculesMolar Mass of MacromoleculesSedimentation in the UltracentrifugeViscosityElectrophoresis22.2 Structure of Synthetic PolymersConfiguration and ConformationThe Random-Walk Model22.3 Structure of Proteins and DNAProteinsDNA22.4 Protein StabilityThe Hydrophobic InteractionDenaturationProtein FoldingAppendix 22.1 DNA FingerprintingChapter 23 Statistical Thermodynamics23.1 Macrostates and Microstates23.2 The Boltzmann Distribution Law23.3 The Partition Function23.4 Molecular Partition FunctionTranslational Partition FunctionRotational Partition FunctionVibrational Partition FunctionElectronic Partition Function23.5 Thermodynamic Quantities from Partition FunctionsInternal Energy and Heat CapacityEntropy23.6 Chemical Equilibrium23.7 Transition-State TheoryAppendix 23.1 Justification of Q = qN\/N! for Indistinguishable ParticlesAppendicesA. Review of Mathematics and PhysicsB. Thermodynamic DataGlossaryAnswers to Even-Numbered Numerical ProblemsIndex\"A distinct and excellent publication worth recommending to biological chemists…I have learnt something new about biology, [the book] is very refreshing in its aims and clarity.\" --The Times Higher \u003cbr\u003e\u003cbr\u003e\"I adopted the P Chem text by Raymond Chang here at McGill two years ago, for a course populated with ~180 biochemistry and biology students, many of them ‘pre-med.’ I had formerly used a well-known text by a different author, but I (and the students) found it a little short on good explanations, and there were many errors in the end-of-chapter problems and answers. I am very pleased with how the Chang text approaches thermodynamics, especially applications, such as in the chapter on macromolecules. Similarly, I very much appreciate the biological emphasis in this text, and especially the relevance of the problems. Overall, I consider this to be an excellent text.\" --Christopher J. Barrett, McGill University \u003cbr\u003e\u003cbr\u003e\"I have found Ray Chang’s P Chem book to be the ideal textbook for students from the life sciences. Whereas so many other textbooks seem to be written for the instructor, this text works well with students who have traditionally struggled with this course.\" --George Bodner, Purdue University \u003cbr\u003e\u003cbr\u003e\"This book offers an alternative approach to physical chemistry that is particularly well suited for those who want to pursue a course of study more focused on the biological sciences.\" --Journal of Chemical EducationRaymond Chang was born in Hong Kong and grew up in Shanghai and Hong Kong, China. He received his B.Sc. degree in chemistry from London University, England and his Ph.D. in physical chemistry from Yale University. After doing postdoctoral research at Washington University and teaching for a year at Hunter College of the City University of New York, he joined the chemistry department at Williams College. Chang has served on the American Chemical Society Examination Committee and the Graduate Record Examination (GRE) Committee. He has also served as editor of The Chemical Educator and has authored books on general chemistry and spectroscopy.","brand":"University Science Books","offers":[{"title":"Default Title","offer_id":48233475113189,"sku":"NP9781891389061","price":150.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781891389061.jpg?v=1767734757","url":"https:\/\/k12savings.com\/es\/products\/physical-chemistry-for-the-chemical-and-biological-sciences-isbn-9781891389061","provider":"K12savings","version":"1.0","type":"link"}