{"product_id":"palladium-reagents-and-catalysts-isbn-9780470850329","title":"Palladium Reagents and Catalysts","description":"Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years.  \u003cp\u003eHighlighting the most recent discoveries in this rapidly expanding field, the book;\u003c\/p\u003e \u003cul\u003e \u003cli\u003eFocuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications\u003c\/li\u003e \u003cli\u003eInvestigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThis volume, together with \u003ci\u003eInnovations in Organic Synthesis,\u003c\/i\u003e Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePalladium Reagents and Catalysts: New Perspectives for the 21\u003c\/i\u003est Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds.\u003c\/p\u003e \u003cp\u003eThose studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.\u003c\/p\u003e  Preface.  \u003cp\u003eAbbreviations.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The Basic Chemistry of Organopalladium Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Characteristic Features of Pd-Promoted or –Catalyzed Reactions.\u003c\/p\u003e \u003cp\u003e1.2 Palladium Compounds, Complexes, and Ligands Widely Used in Organic Synthesis.\u003c\/p\u003e \u003cp\u003e1.3 Fundamental Reactions of Pd Compounds.\u003c\/p\u003e \u003cp\u003e1.3.1 ‘Oxidative’ Addition.\u003c\/p\u003e \u003cp\u003e1.3.2 Insertion.\u003c\/p\u003e \u003cp\u003e1.3.3 Transmetallation.\u003c\/p\u003e \u003cp\u003e1.3.4 Reductive Elimination.\u003c\/p\u003e \u003cp\u003e1.3.5 \u003ci\u003eβ\u003c\/i\u003e-H Elimination (\u003ci\u003eβ\u003c\/i\u003e-Elimination, Dehydropalladation).\u003c\/p\u003e \u003cp\u003e1.3.6 Elimination of \u003ci\u003eβ\u003c\/i\u003e-Heteroatom Groups and \u003ci\u003eβ\u003c\/i\u003e-Carbon.\u003c\/p\u003e \u003cp\u003e1.3.7 Electrophilic Attack by Organopalladium Species.\u003c\/p\u003e \u003cp\u003e1.3.8 Termination of Pd-Catalyzed or –Promoted Reactions and a Catalytic Cycle.\u003c\/p\u003e \u003cp\u003e1.3.9 Reactions Involving Pd(II) Compounds and Pd(0) Complexes.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Oxidative Reactions with Pd(II) Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Reactions of Alkenes.\u003c\/p\u003e \u003cp\u003e2.2.1 Introducti on.\u003c\/p\u003e \u003cp\u003e2.2.2 Reaction with Water.\u003c\/p\u003e \u003cp\u003e2.2.3 Reactions with Alcohols and Phenols.\u003c\/p\u003e \u003cp\u003e2.2.4 Reactions with Carboxylic Acids.\u003c\/p\u003e \u003cp\u003e2.2.5 Reactions with Amines.\u003c\/p\u003e \u003cp\u003e2.2.6 Reactions with Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e2.2.7 Oxidative Carbonylation.\u003c\/p\u003e \u003cp\u003e2.2.8 Reactions with Aromatic Compounds.\u003c\/p\u003e \u003cp\u003e2.2.9 Coupling of Alkenes with Organometallic Compounds.\u003c\/p\u003e \u003cp\u003e2.3 Stoichiometric Reactions of \u003ci\u003eπ\u003c\/i\u003e-Allyl Complexes.\u003c\/p\u003e \u003cp\u003e2.4 Reactions of Conjugated Dienes.\u003c\/p\u003e \u003cp\u003e2.5 Reactions of Allenes.\u003c\/p\u003e \u003cp\u003e2.6 Reaction of Alkynes.\u003c\/p\u003e \u003cp\u003e2.7 Homocoupling and Oxidative Substitution Reactions of Aromatic Compounds.\u003c\/p\u003e \u003cp\u003e2.8 Regioselective Reactions Based on Chelation and Participation of Heteroatoms.\u003c\/p\u003e \u003cp\u003e2.9 Oxidative Carbonylation of Alcohols and Amines.\u003c\/p\u003e \u003cp\u003e2.10 Oxidation of Alcohols.\u003c\/p\u003e \u003cp\u003e2.11 Enone Formation from Ketones and Cycloalkenylation.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Pd(0)-Catalyzed Reactions of sp\u003csup\u003e2\u003c\/sup\u003eOrganic Halides and Pseudohalides.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 Reactions with Alkenes (Mizoroki–Heck Reaction).\u003c\/p\u003e \u003cp\u003e3.2.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2.2 Catalysts and Ligands.\u003c\/p\u003e \u003cp\u003e3.2.3 Reaction Conditions (Bases, Solvents, and Additives).\u003c\/p\u003e \u003cp\u003e3.2.4 Halides and Pseudohalides.\u003c\/p\u003e \u003cp\u003e3.2.5 Alkenes.\u003c\/p\u003e \u003cp\u003e3.2.6 Formation of Neopentylpalladium and its Termination by Anion Capture.\u003c\/p\u003e \u003cp\u003e3.2.7 Intramolecular Reactions.\u003c\/p\u003e \u003cp\u003e3.2.8. Asymmetric Reactions.\u003c\/p\u003e \u003cp\u003e3.2.9 Reactions with 1,2-, 1,3-, and 1,4-Dienes.\u003c\/p\u003e \u003cp\u003e3.2.10 Amino Heck Reactions of Oximes.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.3 Reactions of Aromatics and Heteroaromatics.\u003c\/p\u003e \u003cp\u003e3.3.1 Arylation of Heterocycles.\u003c\/p\u003e \u003cp\u003e3.3.2 Intermolecular Arylation of Phenols.\u003c\/p\u003e \u003cp\u003e3.3.3 Intermolecular Polyarylation of Ketones.\u003c\/p\u003e \u003cp\u003e3.3.4 Intramolecular Arylation of Aromatics.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.4 Reactions with Alkynes.\u003c\/p\u003e \u003cp\u003e3.4.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.4.2 Reactions of Terminal Alkynes to Form Aryl- and Alkenylalkynes (Sonogashira Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.4.3 Reactions of Internal and Terminal Alkynes with Aryl and Alkenyl Halides via Insertion.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.5 Carbonylation and Reactions of Acyl Chlorides.\u003c\/p\u003e \u003cp\u003e3.5.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.5.2 Formation of Carboxylic Acids, Esters, and Amides.\u003c\/p\u003e \u003cp\u003e3.5.3 Formation of Aldehydes and Ketones.\u003c\/p\u003e \u003cp\u003e3.5.4 Reactions of Acyl Halides and Related Compounds.\u003c\/p\u003e \u003cp\u003e3.5.5 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.6 Cross-Coupling Reactions with Organometallic Compounds of the Main Group Metals via Transmetallation.\u003c\/p\u003e \u003cp\u003e3.6.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.6.2 Organoboron Compounds (Suzuki–Miyaura Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.6.3 Organostannanes (Kosugi–Migita–Stille Coupling).\u003c\/p\u003e \u003cp\u003e3.6.4 Organozinc Compounds (Negishi Coupling).\u003c\/p\u003e \u003cp\u003e3.6.5 Organomagnesium Compounds.\u003c\/p\u003e \u003cp\u003e3.6.6 Organosilicon Compounds (Hiyama Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7 Arylation and Alkenylation of C, N, O, S, and P Nucleophiles.\u003c\/p\u003e \u003cp\u003e3.7.1 \u003ci\u003eα\u003c\/i\u003e-Arylation and \u003ci\u003eα\u003c\/i\u003e-Alkenylation of Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e3.7.2 Intramolecular Attack of Aryl Halides on Carbonyl Groups.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.3 Arylation of Nitrogen Nucleophiles.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.4 Arylation of Phenols, Alcohols, and Thiols.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.7.5 Arylation of Phosphines, Phosphonates, and Phosphinates.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8 Miscellaneous Reactions of Aryl Halides.\u003c\/p\u003e \u003cp\u003e3.8.1 The Catellani Reactions using Norbornene as a Template for \u003ci\u003eortho\u003c\/i\u003e-Substitution.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8.2 Reactions of Alcohols with Aryl Halides Involving \u003ci\u003eβ\u003c\/i\u003e-Carbon Elimination.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e3.8.3 Hydrogenolysis with Various Hydrides.\u003c\/p\u003e \u003cp\u003e3.8.4 Homocoupling of Organic Halides (Reductive Coupling).\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Pd(0)-Catalyzed Reactions of Allylic Compounds via \u003ci\u003eΠ\u003c\/i\u003e-Allylpalladium Complexes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction and Range of Leaving Groups.\u003c\/p\u003e \u003cp\u003e4.2 Allylation.\u003c\/p\u003e \u003cp\u003e4.2.1 Stereo- and Regiochemistry of Allylation.\u003c\/p\u003e \u003cp\u003e4.2.2 Asymmetric Allylation.\u003c\/p\u003e \u003cp\u003e4.2.3 Allylation of Stabilized Carbon Nucleophiles.\u003c\/p\u003e \u003cp\u003e4.2.4 Allylation of Oxygen and Nitrogen Nucleophiles.\u003c\/p\u003e \u003cp\u003e4.2.5 Allylation with Bis-Allylic Compounds and Cycloadditions.\u003c\/p\u003e \u003cp\u003e4.3 Reactions with Main Group Organometallic Compounds via Transmetallation.\u003c\/p\u003e \u003cp\u003e4.3.1 Cross-Coupling with Main Group Organometallic Compounds.\u003c\/p\u003e \u003cp\u003e4.3.2 Formation of Allylic Metal Compounds.\u003c\/p\u003e \u003cp\u003e4.3.3 Allylation Involving Umpolung.\u003c\/p\u003e \u003cp\u003e4.3.4 Reactions of Amphiphilic Bis-\u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Compounds.\u003c\/p\u003e \u003cp\u003e4.4 Carbonylation Reactions.\u003c\/p\u003e \u003cp\u003e4.5 Intramolecular Reactions with Alkenes and Alkynes.\u003c\/p\u003e \u003cp\u003e4.6 Hydrogenolysis of Allylic Compounds.\u003c\/p\u003e \u003cp\u003e4.6.1 Preparation of 1-Alkenes by Hydrogenolysis with Formates.\u003c\/p\u003e \u003cp\u003e4.6.2 Hydrogenolysis of Internal and Cyclic Allylic Compounds.\u003c\/p\u003e \u003cp\u003e4.7 Allyl Group as a Protecting Group.\u003c\/p\u003e \u003cp\u003e4.8 1,4-Elimination.\u003c\/p\u003e \u003cp\u003e4.9 Reactions via \u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Enolates.\u003c\/p\u003e \u003cp\u003e4.9.1 Generation of \u003ci\u003eπ\u003c\/i\u003e -Allylpalladium Enolates from Silyl and Tin Enolates.\u003c\/p\u003e \u003cp\u003e4.9.2 Reactions of Allyl \u003ci\u003eβ\u003c\/i\u003e-Keto Carboxylates and Related Compounds.\u003c\/p\u003e \u003cp\u003e4.10 Pd(0) and Pd(II)-Catalyzed Allylic Rearrangement.\u003c\/p\u003e \u003cp\u003e4.11 Reactions of 2,3-Alkadienyl Derivatives via Methylene-\u003ci\u003eπ\u003c\/i\u003e -allylpalladiums.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Pd(0)-Catalyzed Reactions of 1,3-Dienes, 1,2-Dienes (Allenes), and Methylenecyclopropanes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Reactions of Conjugated Dienes.\u003c\/p\u003e \u003cp\u003e5.2 Reactions of Allenes.\u003c\/p\u003e \u003cp\u003e5.2.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.2.2 Reactions with Pronucleophiles.\u003c\/p\u003e \u003cp\u003e5.2.3 Carbonylation.\u003c\/p\u003e \u003cp\u003e5.2.4 Hydrometallation and Dimetallation.\u003c\/p\u003e \u003cp\u003e5.2.5 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003e5.3 Reactions of Methylenecyclopropanes.\u003c\/p\u003e \u003cp\u003e5.3.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.3.2 Hydrostannation and Dimetallation.\u003c\/p\u003e \u003cp\u003e5.3.3 Hydrocarbonation and Hydroamination.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Pd(0)-Catalyzed Reactions of Propargyl Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction and Classification of Reactions.\u003c\/p\u003e \u003cp\u003e6.2 Reactions via Insertion of Alkenes and Alkynes.\u003c\/p\u003e \u003cp\u003e6.3 Carbonylations.\u003c\/p\u003e \u003cp\u003e6.4 Reactions of Main Group Metal Compounds.\u003c\/p\u003e \u003cp\u003e6.5 Reactions of Terminal Alkynes; Formation of 1,2-Alkadien-4-ynes.\u003c\/p\u003e \u003cp\u003e6.6 Reactions of Nucleophiles on Central sp Carbon of Allenylpalladium Intermediates.\u003c\/p\u003e \u003cp\u003e6.7 Hydrogenolysis and Elimination of Propargyl Compounds.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Pd(0)- and Pd(II)-Catalyzed Reactions of Alkynes and Benzynes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Reactions of Alkynes.\u003c\/p\u003e \u003cp\u003e7.1.1 Carbonylation.\u003c\/p\u003e \u003cp\u003e7.1.2 Hydroarylation.\u003c\/p\u003e \u003cp\u003e7.1.3 Hydroamination, Hydrocarbonation, and Related Reactions.\u003c\/p\u003e \u003cp\u003e7.1.4 Hydrometallation and Hydro-Heteroatom Addition.\u003c\/p\u003e \u003cp\u003e7.1.5 Dimetallation and Related Reactions.\u003c\/p\u003e \u003cp\u003e7.1.6 Cyclization of 1,6-Enynes and 1,7-Diynes.\u003c\/p\u003e \u003cp\u003e7.1.7 Benzannulation.\u003c\/p\u003e \u003cp\u003e7.1.8 Homo- and Cross-Coupling of Alkynes.\u003c\/p\u003e \u003cp\u003e7.1.9 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003e7.2 Reactions of Benzynes.\u003c\/p\u003e \u003cp\u003e7.2.1 Cyclotrimerization and Cocyclization.\u003c\/p\u003e \u003cp\u003e7.2.2 Addition Reactions of Arynes 595 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Pd(0)-Catalyzed Reactions of Alkenes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Carbonylation.\u003c\/p\u003e \u003cp\u003e8.2 Hydroamination.\u003c\/p\u003e \u003cp\u003e8.3 Hydrometallation.\u003c\/p\u003e \u003cp\u003e8.4 Miscellaneous Reactions.\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Pd(0)-Catalyzed Miscellaneous Reactions of Carbon Monoxide.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Miscellaneous Reactions Catalyzed by Chiral and Achiral Pd(II) Complexes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eReferences.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eTables 1.1 to 1.18.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\"... covers the vast amount of innovation that has occurred in this important chemistry field in the last several years.\" (\u003ci\u003eE-STREAMS\u003c\/i\u003e, September 2005)\u003c\/p\u003e \u003cp\u003e\"This book is beautifully illustrated, very well referenced and covers a wide range of exciting synthetic methods....\" (\u003ci\u003eApplied Organometallic Chemistry\u003c\/i\u003e, March 2005)\u003c\/p\u003e \u003cp\u003e\"...amazing that a single book of such scope could actually be written...achieved just the right balance...\" (www.organische-chemie.ch, 08 June 2004)\u003c\/p\u003e \u003cp\u003e\"...For the modest price, this book should find its way onto the shelves of all good chemistry libraries....\" (\u003ci\u003eChemistry \u0026amp; Industry\u003c\/i\u003e, No.22 15\u003csup\u003eth\u003c\/sup\u003e November, 2004)\u003c\/p\u003e  \u003cstrong\u003eJiro Tsuji\u003c\/strong\u003e is the author of Palladium Reagents and Catalysts: New Perspectives for the 21st Century, published by Wiley.   Since Jiro Tsuji wrote \u003ci\u003ePalladium Reagents and Catalysts: Innovations in\u003c\/i\u003e \u003ci\u003eOrganic Synthesis\u003c\/i\u003e in 1995, the field of organopalladium chemistry has continued to expand at a remarkable rate.  \u003cp\u003e\u003ci\u003ePalladium Reagents and Catalysts: New Perspectives for the 21\u003c\/i\u003est Century has been written to address this explosive growth, and in particular to cover the developments of the last five years.\u003c\/p\u003e \u003cp\u003eWith extensive reference to the primary literature, the present volume highlights:\u003c\/p\u003e \u003cdiv\u003e \u003cul\u003e \u003cli\u003e \u003cdiv\u003eNew aspects on organopalladium chemistry, putting emphasis on synthetic applications.\u003c\/div\u003e \u003c\/li\u003e \u003cli\u003e \u003cdiv\u003eNew perspectives on the synthetic usefulness of contemporary organopalladium chemistry for synthetic organic chemists.\u003c\/div\u003e \u003c\/li\u003e \u003c\/ul\u003e \u003c\/div\u003e \u003cp\u003eThis volume, together with \u003ci\u003eInnovations in Organic Synthesis\u003c\/i\u003e provides complete coverage of over 40 years of organopalladium chemistry.\u003c\/p\u003e \u003cp\u003e\u003ci\u003ePalladium Reagents and Catalysts: New Perspectives for the 21\u003c\/i\u003est Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds.\u003c\/p\u003e \u003cp\u003eThose studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989748400357,"sku":"NP9780470850329","price":169.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780470850329.jpg?v=1761785338","url":"https:\/\/k12savings.com\/es\/products\/palladium-reagents-and-catalysts-isbn-9780470850329","provider":"K12savings","version":"1.0","type":"link"}