{"product_id":"organic-chemistry-as-a-second-language-isbn-9781119837053","title":"Organic Chemistry as a Second Language","description":"\u003cp\u003eOrganic chemistry is a challenging subject, with many students expecting it to require many hours of memorization. Author David Klein's \u003ci\u003eSecond Language\u003c\/i\u003e books prove this is not true—organic chemistry is one continuous story that actually makes sense if you pay close attention. Klein’s books use a conversational tone making them more accessible and easier to read for students. \u003c\/p\u003e\u003cp\u003e\u003ci\u003eOrganic Chemistry as a Second Language: Second Semester Topics, 6e\u003c\/i\u003e builds on the principles explored in the first half of the course, delving deeper into molecular mechanisms, reactions, and analytical techniques. Using Klein’s one-of-a-kind SkillBuilder approach, the book includes hands-on exercises and thoroughly explained solutions designed to further reinforce student comprehension of chemical concepts and organic principles. An indispensable supplement to the primary text, this resource covers aromatic compounds, infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy, nucleophilic and electrophilic aromatic substitution, ketones and aldehydes, carboxylic acid derivatives, and much more. \u003c\/p\u003e\u003cp\u003e\u003ci\u003eOrganic Chemistry as a Second Language: Second Semester Topics, 6e \u003c\/i\u003eteaches students how to ask the right questions to solve problems, study more efficiently, and learn to speak the language of organic chemistry. Like its first-semester companion title, it is an essential ‘guide on the side’ for any organic chemistry student no matter what textbook or instructor-provided lecture material is used. The inclusion of new end of chapter problems, providing both practice and challenge, will prepare students and build confidence come exam time, as well as outside the classroom. \u003c\/p\u003e\u003cp\u003eContents\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1 Aromaticity 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction to Aromatic Compounds 1\u003c\/p\u003e \u003cp\u003e1.2 Nomenclature of Aromatic Compounds 2\u003c\/p\u003e \u003cp\u003e1.3 Criteria for Aromaticity 6\u003c\/p\u003e \u003cp\u003e1.4 Lone Pairs 9\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 11\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2 IR Spectroscopy 14\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Vibrational Excitation 14\u003c\/p\u003e \u003cp\u003e2.2 IR Spectra 16\u003c\/p\u003e \u003cp\u003e2.3 Wavenumber 16\u003c\/p\u003e \u003cp\u003e2.4 Signal Intensity 21\u003c\/p\u003e \u003cp\u003e2.5 Signal Shape 22\u003c\/p\u003e \u003cp\u003e2.6 Analyzing an IR Spectrum 29\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 36\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3 NMR Spectroscopy 39\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Chemical Equivalence 39\u003c\/p\u003e \u003cp\u003e3.2 Chemical Shift (Benchmark Values) 42\u003c\/p\u003e \u003cp\u003e3.3 Integration 47\u003c\/p\u003e \u003cp\u003e3.4 Multiplicity 50\u003c\/p\u003e \u003cp\u003e3.5 Pattern Recognition 52\u003c\/p\u003e \u003cp\u003e3.6 Complex Splitting 54\u003c\/p\u003e \u003cp\u003e3.7 No Splitting 55\u003c\/p\u003e \u003cp\u003e3.8 Hydrogen Deficiency Index (Degrees of Unsaturation) 56\u003c\/p\u003e \u003cp\u003e3.9 Analyzing a Proton NMR Spectrum 59\u003c\/p\u003e \u003cp\u003e3.10 13 C NMR Spectroscopy 63\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 65\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4 Electrophilic Aromatic Substitution 78\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Halogenation and the Role of Lewis Acids 79\u003c\/p\u003e \u003cp\u003e4.2 Nitration 83\u003c\/p\u003e \u003cp\u003e4.3 Friedel–Crafts Alkylation and Acylation 85\u003c\/p\u003e \u003cp\u003e4.4 Sulfonation 92\u003c\/p\u003e \u003cp\u003e4.5 Activation and Deactivation 96\u003c\/p\u003e \u003cp\u003e4.6 Directing Effects 98\u003c\/p\u003e \u003cp\u003e4.7 Identifying Activators and Deactivators 107\u003c\/p\u003e \u003cp\u003e4.8 Predicting and Exploiting Steric Effects 117\u003c\/p\u003e \u003cp\u003e4.9 Synthesis Strategies 124\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 129\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5 Nucleophilic Aromatic Substitution 134\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Criteria for Nucleophilic Aromatic Substitution 134\u003c\/p\u003e \u003cp\u003e5.2 S N Ar Mechanism 136\u003c\/p\u003e \u003cp\u003e5.3 Elimination–Addition 142\u003c\/p\u003e \u003cp\u003e5.4 Mechanism Strategies 148\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 151\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 6 Ketones and Aldehydes 154\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Preparation of Ketones and Aldehydes 154\u003c\/p\u003e \u003cp\u003e6.2 Stability and Reactivity of C===O Bonds 157\u003c\/p\u003e \u003cp\u003e6.3 H-Nucleophiles 159\u003c\/p\u003e \u003cp\u003e6.4 O-Nucleophiles 164\u003c\/p\u003e \u003cp\u003e6.5 S-Nucleophiles 174\u003c\/p\u003e \u003cp\u003e6.6 N-Nucleophiles 176\u003c\/p\u003e \u003cp\u003e6.7 C-Nucleophiles 184\u003c\/p\u003e \u003cp\u003e6.8 Exceptions to the Rule 193\u003c\/p\u003e \u003cp\u003e6.9 How to Approach Synthesis Problems 197\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 203\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 7 Carboxylic Acid Derivatives 207\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Reactivity of Carboxylic Acid Derivatives 207\u003c\/p\u003e \u003cp\u003e7.2 General Rules 208\u003c\/p\u003e \u003cp\u003e7.3 Acid Halides 212\u003c\/p\u003e \u003cp\u003e7.4 Acid Anhydrides 220\u003c\/p\u003e \u003cp\u003e7.5 Esters 222\u003c\/p\u003e \u003cp\u003e7.6 Amides and Nitriles 231\u003c\/p\u003e \u003cp\u003e7.7 Synthesis Problems 240\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 247\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 8 Enols and Enolates 253\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Alpha Protons 253\u003c\/p\u003e \u003cp\u003e8.2 Keto-Enol Tautomerism 255\u003c\/p\u003e \u003cp\u003e8.3 Reactions Involving Enols 259\u003c\/p\u003e \u003cp\u003e8.4 Making Enolates 262\u003c\/p\u003e \u003cp\u003e8.5 Haloform Reaction 265\u003c\/p\u003e \u003cp\u003e8.6 Alkylation of Enolates 268\u003c\/p\u003e \u003cp\u003e8.7 Aldol Reactions 272\u003c\/p\u003e \u003cp\u003e8.8 Claisen Condensation 278\u003c\/p\u003e \u003cp\u003e8.9 Decarboxylation 285\u003c\/p\u003e \u003cp\u003e8.10 Michael Reactions 292\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 299\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 9 Amines 303\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Nucleophilicity and Basicity of Amines 303\u003c\/p\u003e \u003cp\u003e9.2 Preparation of Amines Through S N 2 Reactions 305\u003c\/p\u003e \u003cp\u003e9.3 Preparation of Amines Through Reductive Amination 308\u003c\/p\u003e \u003cp\u003e9.4 Acylation of Amines 313\u003c\/p\u003e \u003cp\u003e9.5 Reactions of Amines with Nitrous Acid 316\u003c\/p\u003e \u003cp\u003e9.6 Aromatic Diazonium Salts 319\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 322\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 10 Diels-alder Reactions 325\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction and Mechanism 325\u003c\/p\u003e \u003cp\u003e10.2 The Dienophile 328\u003c\/p\u003e \u003cp\u003e10.3 The Diene 329\u003c\/p\u003e \u003cp\u003e10.4 Other Pericyclic Reactions 335\u003c\/p\u003e \u003cp\u003eEnd-of-Chapter Problems 336\u003c\/p\u003e \u003cp\u003eDetailed Solutions S-1\u003c\/p\u003e \u003cp\u003eIndex I-1\u003c\/p\u003e \u003cp\u003e\u003cb\u003eDavid Klein\u003c\/b\u003e is a lecturer at Johns Hopkins University where he teaches Organic and General Chemistry. He is a dynamic and creative teacher and uses analogy to help students grasp difficult topics. Klein's unique informal voice and manner of presentation help students truly master key topics in this course. He is also the author of \u003ci\u003eOrganic Chemistry as a Second Language\u003c\/i\u003e; response to this book has been phenomenal.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989726347493,"sku":"NP9781119837053","price":40.5,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119837053.jpg?v=1761785266","url":"https:\/\/k12savings.com\/es\/products\/organic-chemistry-as-a-second-language-isbn-9781119837053","provider":"K12savings","version":"1.0","type":"link"}