{"product_id":"multiphase-catalytic-reactors-isbn-9781118115763","title":"Multiphase Catalytic Reactors","description":"\u003cul\u003e \u003cli\u003eProvides a holistic approach to multiphase catalytic reactors from their modeling and design to their applications in industrial manufacturing of chemicals\u003c\/li\u003e \u003cli\u003eCovers theoretical aspects and examples of fixed-bed, fluidized-bed, trickle-bed, slurry, monolith and microchannel reactors\u003c\/li\u003e \u003cli\u003eIncludes chapters covering experimental techniques and practical guidelines for lab-scale testing of multiphase reactors\u003c\/li\u003e \u003cli\u003eIncludes mathematical content focused on design equations and empirical relationships characterizing different multiphase reactor types together with an assortment of computational tools\u003c\/li\u003e \u003cli\u003eInvolves detailed coverage of multiphase reactor applications such as Fischer-Tropsch synthesis, fuel processing for fuel cells, hydrotreating of oil fractions and biofuels processing\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eList of Contributors, x\u003c\/p\u003e \u003cp\u003ePreface, xii\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 1 Principles of catalytic reaction engineering\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Catalytic reactor types and their industrial significance, 3\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eZeynep Ilsen Önsan and Ahmet Kerim Avci\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction, 3\u003c\/p\u003e \u003cp\u003e1.2 Reactors with fixed bed of catalysts, 3\u003c\/p\u003e \u003cp\u003e1.2.1 Packed-bed reactors, 3\u003c\/p\u003e \u003cp\u003e1.2.2 Monolith reactors, 8\u003c\/p\u003e \u003cp\u003e1.2.3 Radial flow reactors, 9\u003c\/p\u003e \u003cp\u003e1.2.4 Trickle-bed reactors, 9\u003c\/p\u003e \u003cp\u003e1.2.5 Short contact time reactors, 10\u003c\/p\u003e \u003cp\u003e1.3 Reactors with moving bed of catalysts, 11\u003c\/p\u003e \u003cp\u003e1.3.1 Fluidized-bed reactors, 11\u003c\/p\u003e \u003cp\u003e1.3.2 Slurry reactors, 13\u003c\/p\u003e \u003cp\u003e1.3.3 Moving-bed reactors, 14\u003c\/p\u003e \u003cp\u003e1.4 Reactors without a catalyst bed, 14\u003c\/p\u003e \u003cp\u003e1.5 Summary, 16\u003c\/p\u003e \u003cp\u003eReferences, 16\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Microkinetic analysis of heterogeneous catalytic systems, 17\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eZeynep Ilsen Önsan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Heterogeneous catalytic systems, 17\u003c\/p\u003e \u003cp\u003e2.1.1 Chemical and physical characteristics of solid catalysts, 18\u003c\/p\u003e \u003cp\u003e2.1.2 Activity, selectivity, and stability, 21\u003c\/p\u003e \u003cp\u003e2.2 Intrinsic kinetics of heterogeneous reactions, 22\u003c\/p\u003e \u003cp\u003e2.2.1 Kinetic models and mechanisms, 23\u003c\/p\u003e \u003cp\u003e2.2.2 Analysis and correlation of rate data, 27\u003c\/p\u003e \u003cp\u003e2.3 External (interphase) transport processes, 32\u003c\/p\u003e \u003cp\u003e2.3.1 External mass transfer: Isothermal conditions, 33\u003c\/p\u003e \u003cp\u003e2.3.2 External temperature effects, 35\u003c\/p\u003e \u003cp\u003e2.3.3 Nonisothermal conditions: Multiple steady states, 36\u003c\/p\u003e \u003cp\u003e2.3.4 External effectiveness factors, 38\u003c\/p\u003e \u003cp\u003e2.4 Internal (intraparticle) transport processes, 39\u003c\/p\u003e \u003cp\u003e2.4.1 Intraparticle mass and heat transfer, 39\u003c\/p\u003e \u003cp\u003e2.4.2 Mass transfer with chemical reaction: Isothermal effectiveness, 41\u003c\/p\u003e \u003cp\u003e2.4.3 Heat and mass transfer with chemical reaction, 45\u003c\/p\u003e \u003cp\u003e2.4.4 Impact of internal transport limitations on kinetic studies, 47\u003c\/p\u003e \u003cp\u003e2.5 Combination of external and internal transport effects, 48\u003c\/p\u003e \u003cp\u003e2.5.1 Isothermal overall effectiveness, 48\u003c\/p\u003e \u003cp\u003e2.5.2 Nonisothermal conditions, 49\u003c\/p\u003e \u003cp\u003e2.6 Summary, 50\u003c\/p\u003e \u003cp\u003eNomenclature, 50\u003c\/p\u003e \u003cp\u003eGreek letters, 51\u003c\/p\u003e \u003cp\u003eReferences, 51\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 2 Two-phase catalytic reactors\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Fixed-bed gas–solid catalytic reactors, 55\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJoão P. Lopes and Alírio E. Rodrigues\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction and outline, 55\u003c\/p\u003e \u003cp\u003e3.2 Modeling of fixed-bed reactors, 57\u003c\/p\u003e \u003cp\u003e3.2.1 Description of transport–reaction phenomena, 57\u003c\/p\u003e \u003cp\u003e3.2.2 Mathematical model, 59\u003c\/p\u003e \u003cp\u003e3.2.3 Model reduction and selection, 61\u003c\/p\u003e \u003cp\u003e3.3 Averaging over the catalyst particle, 61\u003c\/p\u003e \u003cp\u003e3.3.1 Chemical regime, 64\u003c\/p\u003e \u003cp\u003e3.3.2 Diffusional regime, 64\u003c\/p\u003e \u003cp\u003e3.4 Dominant fluid–solid mass transfer, 66\u003c\/p\u003e \u003cp\u003e3.4.1 Isothermal axial flow bed, 67\u003c\/p\u003e \u003cp\u003e3.4.2 Non-isothermal non-adiabatic axial flow bed, 70\u003c\/p\u003e \u003cp\u003e3.5 Dominant fluid–solid mass and heat transfer, 70\u003c\/p\u003e \u003cp\u003e3.6 Negligible mass and thermal dispersion, 72\u003c\/p\u003e \u003cp\u003e3.7 Conclusions, 73\u003c\/p\u003e \u003cp\u003eNomenclature, 74\u003c\/p\u003e \u003cp\u003eGreek letters, 75\u003c\/p\u003e \u003cp\u003eReferences, 75\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Fluidized-bed catalytic reactors, 80\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJohn R. Grace\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction, 80\u003c\/p\u003e \u003cp\u003e4.1.1 Advantages and disadvantages of fluidized-bed reactors, 80\u003c\/p\u003e \u003cp\u003e4.1.2 Preconditions for successful fluidized-bed processes, 81\u003c\/p\u003e \u003cp\u003e4.1.3 Industrial catalytic processes employing fluidized-bed reactors, 82\u003c\/p\u003e \u003cp\u003e4.2 Key hydrodynamic features of gas-fluidized beds, 83\u003c\/p\u003e \u003cp\u003e4.2.1 Minimum fluidization velocity, 83\u003c\/p\u003e \u003cp\u003e4.2.2 Powder group and minimum bubbling velocity, 84\u003c\/p\u003e \u003cp\u003e4.2.3 Flow regimes and transitions, 84\u003c\/p\u003e \u003cp\u003e4.2.4 Bubbling fluidized beds, 84\u003c\/p\u003e \u003cp\u003e4.2.5 Turbulent fluidization flow regime, 85\u003c\/p\u003e \u003cp\u003e4.2.6 Fast fluidization and dense suspension upflow, 85\u003c\/p\u003e \u003cp\u003e4.3 Key properties affecting reactor performance, 86\u003c\/p\u003e \u003cp\u003e4.3.1 Particle mixing, 86\u003c\/p\u003e \u003cp\u003e4.3.2 Gas mixing, 87\u003c\/p\u003e \u003cp\u003e4.3.3 Heat transfer and temperature uniformity, 87\u003c\/p\u003e \u003cp\u003e4.3.4 Mass transfer, 88\u003c\/p\u003e \u003cp\u003e4.3.5 Entrainment, 88\u003c\/p\u003e \u003cp\u003e4.3.6 Attrition, 89\u003c\/p\u003e \u003cp\u003e4.3.7 Wear, 89\u003c\/p\u003e \u003cp\u003e4.3.8 Agglomeration and fouling, 89\u003c\/p\u003e \u003cp\u003e4.3.9 Electrostatics and other interparticle forces, 89\u003c\/p\u003e \u003cp\u003e4.4 Reactor modeling, 89\u003c\/p\u003e \u003cp\u003e4.4.1 Basis for reactor modeling, 89\u003c\/p\u003e \u003cp\u003e4.4.2 Modeling of bubbling and slugging flow regimes, 90\u003c\/p\u003e \u003cp\u003e4.4.3 Modeling of reactors operating in high-velocity flow regimes, 91\u003c\/p\u003e \u003cp\u003e4.5 Scale-up, pilot testing, and practical issues, 91\u003c\/p\u003e \u003cp\u003e4.5.1 Scale-up issues, 91\u003c\/p\u003e \u003cp\u003e4.5.2 Laboratory and pilot testing, 91\u003c\/p\u003e \u003cp\u003e4.5.3 Instrumentation, 92\u003c\/p\u003e \u003cp\u003e4.5.4 Other practical issues, 92\u003c\/p\u003e \u003cp\u003e4.6 Concluding remarks, 92\u003c\/p\u003e \u003cp\u003eNomenclature, 93\u003c\/p\u003e \u003cp\u003eGreek letters, 93\u003c\/p\u003e \u003cp\u003eReferences, 93\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 3 Three-phase catalytic reactors\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Three-phase fixed-bed reactors, 97\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eIon Iliuta and Faïçal Larachi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction, 97\u003c\/p\u003e \u003cp\u003e5.2 Hydrodynamic aspects of three-phase fixed-bed reactors, 98\u003c\/p\u003e \u003cp\u003e5.2.1 General aspects: Flow regimes, liquid holdup, two-phase pressure drop, and wetting efficiency, 98\u003c\/p\u003e \u003cp\u003e5.2.2 Standard two-fluid models for two-phase downflow and upflow in three-phase fixed-bed reactors, 100\u003c\/p\u003e \u003cp\u003e5.2.3 Nonequilibrium thermomechanical models for two-phase flow in three-phase fixed-bed reactors, 102\u003c\/p\u003e \u003cp\u003e5.3 Mass and heat transfer in three-phase fixed-bed reactors, 104\u003c\/p\u003e \u003cp\u003e5.3.1 Gas–liquid mass transfer, 105\u003c\/p\u003e \u003cp\u003e5.3.2 Liquid–solid mass transfer, 105\u003c\/p\u003e \u003cp\u003e5.3.3 Heat transfer, 106\u003c\/p\u003e \u003cp\u003e5.4 Scale-up and scale-down of trickle-bed reactors, 108\u003c\/p\u003e \u003cp\u003e5.4.1 Scaling up of trickle-bed reactors, 108\u003c\/p\u003e \u003cp\u003e5.4.2 Scaling down of trickle-bed reactors, 109\u003c\/p\u003e \u003cp\u003e5.4.3 Salient conclusions, 110\u003c\/p\u003e \u003cp\u003e5.5 Trickle-bed reactor\/bioreactor modeling, 110\u003c\/p\u003e \u003cp\u003e5.5.1 Catalytic hydrodesulfurization and bed clogging in hydrotreating trickle-bed reactors, 110\u003c\/p\u003e \u003cp\u003e5.5.2 Biomass accumulation and clogging in trickle-bed bioreactors for phenol biodegradation, 115\u003c\/p\u003e \u003cp\u003e5.5.3 Integrated aqueous-phase glycerol reforming and dimethyl ether synthesis into an allothermal dual-bed reactor, 121\u003c\/p\u003e \u003cp\u003eNomenclature, 126\u003c\/p\u003e \u003cp\u003eGreek letters, 127\u003c\/p\u003e \u003cp\u003eSubscripts, 128\u003c\/p\u003e \u003cp\u003eSuperscripts, 128\u003c\/p\u003e \u003cp\u003eAbbreviations, 128\u003c\/p\u003e \u003cp\u003eReferences, 128\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Three-phase slurry reactors, 132\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eVivek V. Buwa, Shantanu Roy and Vivek V. Ranade\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction, 132\u003c\/p\u003e \u003cp\u003e6.2 Reactor design, scale-up methodology, and reactor selection, 134\u003c\/p\u003e \u003cp\u003e6.2.1 Practical aspects of reactor design and scale-up, 134\u003c\/p\u003e \u003cp\u003e6.2.2 Transport effects at particle level, 139\u003c\/p\u003e \u003cp\u003e6.3 Reactor models for design and scale-up, 143\u003c\/p\u003e \u003cp\u003e6.3.1 Lower order models, 143\u003c\/p\u003e \u003cp\u003e6.3.2 Tank-in-series\/mixing cell models, 144\u003c\/p\u003e \u003cp\u003e6.4 Estimation of transport and hydrodynamic parameters, 145\u003c\/p\u003e \u003cp\u003e6.4.1 Estimation of transport parameters, 145\u003c\/p\u003e \u003cp\u003e6.4.2 Estimation of hydrodynamic parameters, 146\u003c\/p\u003e \u003cp\u003e6.5 Advanced computational fluid dynamics (CFD)-based models, 147\u003c\/p\u003e \u003cp\u003e6.6 Summary and closing remarks, 149\u003c\/p\u003e \u003cp\u003eAcknowledgments, 152\u003c\/p\u003e \u003cp\u003eNomenclature, 152\u003c\/p\u003e \u003cp\u003eGreek letters, 153\u003c\/p\u003e \u003cp\u003eSubscripts, 153\u003c\/p\u003e \u003cp\u003eReferences, 153\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Bioreactors, 156\u003c\/b\u003e\u003cbr\u003e\u003ci\u003ePedro Fernandes and Joaquim M.S. Cabral\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction, 156\u003c\/p\u003e \u003cp\u003e7.2 Basic concepts, configurations, and modes of operation, 156\u003c\/p\u003e \u003cp\u003e7.2.1 Basic concepts, 156\u003c\/p\u003e \u003cp\u003e7.2.2 Reactor configurations and modes of operation, 157\u003c\/p\u003e \u003cp\u003e7.3 Mass balances and reactor equations, 159\u003c\/p\u003e \u003cp\u003e7.3.1 Operation with enzymes, 159\u003c\/p\u003e \u003cp\u003e7.3.2 Operation with living cells, 160\u003c\/p\u003e \u003cp\u003e7.4 Immobilized enzymes and cells, 164\u003c\/p\u003e \u003cp\u003e7.4.1 Mass transfer effects, 164\u003c\/p\u003e \u003cp\u003e7.4.2 Deactivation effects, 166\u003c\/p\u003e \u003cp\u003e7.5 Aeration, 166\u003c\/p\u003e \u003cp\u003e7.6 Mixing, 166\u003c\/p\u003e \u003cp\u003e7.7 Heat transfer, 167\u003c\/p\u003e \u003cp\u003e7.8 Scale-up, 167\u003c\/p\u003e \u003cp\u003e7.9 Bioreactors for animal cell cultures, 167\u003c\/p\u003e \u003cp\u003e7.10 Monitoring and control of bioreactors, 168\u003c\/p\u003e \u003cp\u003eNomenclature, 168\u003c\/p\u003e \u003cp\u003eGreek letters, 169\u003c\/p\u003e \u003cp\u003eSubscripts, 169\u003c\/p\u003e \u003cp\u003eReferences, 169\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 4 Structured reactors\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Monolith reactors, 173\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJoão P. Lopes and Alírio E. Rodrigues\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction, 173\u003c\/p\u003e \u003cp\u003e8.1.1 Design concepts, 174\u003c\/p\u003e \u003cp\u003e8.1.2 Applications, 178\u003c\/p\u003e \u003cp\u003e8.2 Design of wall-coated monolith channels, 179\u003c\/p\u003e \u003cp\u003e8.2.1 Flow in monolithic channels, 179\u003c\/p\u003e \u003cp\u003e8.2.2 Mass transfer and wall reaction, 182\u003c\/p\u003e \u003cp\u003e8.2.3 Reaction and diffusion in the catalytic washcoat, 190\u003c\/p\u003e \u003cp\u003e8.2.4 Nonisothermal operation, 194\u003c\/p\u003e \u003cp\u003e8.3 Mapping and evaluation of operating regimes, 197\u003c\/p\u003e \u003cp\u003e8.3.1 Diversity in the operation of a monolith reactor, 197\u003c\/p\u003e \u003cp\u003e8.3.2 Definition of operating regimes, 199\u003c\/p\u003e \u003cp\u003e8.3.3 Operating diagrams for linear kinetics, 201\u003c\/p\u003e \u003cp\u003e8.3.4 Influence of nonlinear reaction kinetics, 202\u003c\/p\u003e \u003cp\u003e8.3.5 Performance evaluation, 203\u003c\/p\u003e \u003cp\u003e8.4 Three-phase processes, 204\u003c\/p\u003e \u003cp\u003e8.5 Conclusions, 207\u003c\/p\u003e \u003cp\u003eNomenclature, 207\u003c\/p\u003e \u003cp\u003eGreek letters, 208\u003c\/p\u003e \u003cp\u003eSuperscripts, 208\u003c\/p\u003e \u003cp\u003eSubscripts, 208\u003c\/p\u003e \u003cp\u003eReferences, 209\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Microreactors for catalytic reactions, 213\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eEvgeny Rebrov and Sourav Chatterjee\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction, 213\u003c\/p\u003e \u003cp\u003e9.2 Single-phase catalytic microreactors, 213\u003c\/p\u003e \u003cp\u003e9.2.1 Residence time distribution, 213\u003c\/p\u003e \u003cp\u003e9.2.2 Effect of flow maldistribution, 214\u003c\/p\u003e \u003cp\u003e9.2.3 Mass transfer, 215\u003c\/p\u003e \u003cp\u003e9.2.4 Heat transfer, 215\u003c\/p\u003e \u003cp\u003e9.3 Multiphase microreactors, 216\u003c\/p\u003e \u003cp\u003e9.3.1 Microstructured packed beds, 216\u003c\/p\u003e \u003cp\u003e9.3.2 Microchannel reactors, 218\u003c\/p\u003e \u003cp\u003e9.4 Conclusions and outlook, 225\u003c\/p\u003e \u003cp\u003eNomenclature, 226\u003c\/p\u003e \u003cp\u003eGreek letters, 227\u003c\/p\u003e \u003cp\u003eSubscripts, 227\u003c\/p\u003e \u003cp\u003eReferences, 228\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 5 Essential tools of reactor modeling and design\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Experimental methods for the determination of parameters, 233\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eRebecca R. Fushimi, John T. Gleaves and Gregory S. Yablonsky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction, 233\u003c\/p\u003e \u003cp\u003e10.2 Consideration of kinetic objectives, 234\u003c\/p\u003e \u003cp\u003e10.3 Criteria for collecting kinetic data, 234\u003c\/p\u003e \u003cp\u003e10.4 Experimental methods, 234\u003c\/p\u003e \u003cp\u003e10.4.1 Steady-state flow experiments, 235\u003c\/p\u003e \u003cp\u003e10.4.2 Transient flow experiments, 237\u003c\/p\u003e \u003cp\u003e10.4.3 Surface science experiments, 238\u003c\/p\u003e \u003cp\u003e10.5 Microkinetic approach to kinetic analysis, 241\u003c\/p\u003e \u003cp\u003e10.6 TAP approach to kinetic analysis, 241\u003c\/p\u003e \u003cp\u003e10.6.1 TAP experiment design, 242\u003c\/p\u003e \u003cp\u003e10.6.2 TAP experimental results, 244\u003c\/p\u003e \u003cp\u003e10.7 Conclusions, 248\u003c\/p\u003e \u003cp\u003eReferences, 249\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Numerical solution techniques, 253\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eAhmet Kerim Avci and Seda Keskin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Techniques for the numerical solution of ordinary differential equations, 253\u003c\/p\u003e \u003cp\u003e11.1.1 Explicit techniques, 253\u003c\/p\u003e \u003cp\u003e11.1.2 Implicit techniques, 254\u003c\/p\u003e \u003cp\u003e11.2 Techniques for the numerical solution of partial differential equations, 255\u003c\/p\u003e \u003cp\u003e11.3 Computational fluid dynamics techniques, 256\u003c\/p\u003e \u003cp\u003e11.3.1 Methodology of computational fluid dynamics, 256\u003c\/p\u003e \u003cp\u003e11.3.2 Finite element method, 256\u003c\/p\u003e \u003cp\u003e11.3.3 Finite volume method, 258\u003c\/p\u003e \u003cp\u003e11.4 Case studies, 259\u003c\/p\u003e \u003cp\u003e11.4.1 Indirect partial oxidation of methane in a catalytic tubular reactor, 259\u003c\/p\u003e \u003cp\u003e11.4.2 Hydrocarbon steam reforming in spatially segregated microchannel reactors, 261\u003c\/p\u003e \u003cp\u003e11.5 Summary, 265\u003c\/p\u003e \u003cp\u003eNomenclature, 266\u003c\/p\u003e \u003cp\u003eGreek letters, 267\u003c\/p\u003e \u003cp\u003eSubscripts\/superscripts, 267\u003c\/p\u003e \u003cp\u003eReferences, 267\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 6 Industrial applications of multiphase reactors\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Reactor approaches for Fischer–Tropsch synthesis, 271\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eGary Jacobs and Burtron H. Davis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction, 271\u003c\/p\u003e \u003cp\u003e12.2 Reactors to 1950, 272\u003c\/p\u003e \u003cp\u003e12.3 1950–1985 period, 274\u003c\/p\u003e \u003cp\u003e12.4 1985 to present, 276\u003c\/p\u003e \u003cp\u003e12.4.1 Fixed-bed reactors, 276\u003c\/p\u003e \u003cp\u003e12.4.2 Fluidized-bed reactors, 280\u003c\/p\u003e \u003cp\u003e12.4.3 Slurry bubble column reactors, 281\u003c\/p\u003e \u003cp\u003e12.4.4 Structured packings, 286\u003c\/p\u003e \u003cp\u003e12.4.5 Operation at supercritical conditions (SCF), 288\u003c\/p\u003e \u003cp\u003e12.5 The future?, 288\u003c\/p\u003e \u003cp\u003eReferences, 291\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Hydrotreating of oil fractions, 295\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJorge Ancheyta, Anton Alvarez-Majmutov and Carolina Leyva\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction, 295\u003c\/p\u003e \u003cp\u003e13.2 The HDT process, 296\u003c\/p\u003e \u003cp\u003e13.2.1 Overview, 296\u003c\/p\u003e \u003cp\u003e13.2.2 Role in petroleum refining, 297\u003c\/p\u003e \u003cp\u003e13.2.3 World outlook and the situation of Mexico, 298\u003c\/p\u003e \u003cp\u003e13.3 Fundamentals of HDT, 300\u003c\/p\u003e \u003cp\u003e13.3.1 Chemistry, 300\u003c\/p\u003e \u003cp\u003e13.3.2 Reaction kinetics, 303\u003c\/p\u003e \u003cp\u003e13.3.3 Thermodynamics, 305\u003c\/p\u003e \u003cp\u003e13.3.4 Catalysts, 306\u003c\/p\u003e \u003cp\u003e13.4 Process aspects of HDT, 307\u003c\/p\u003e \u003cp\u003e13.4.1 Process variables, 307\u003c\/p\u003e \u003cp\u003e13.4.2 Reactors for hydroprocessing, 310\u003c\/p\u003e \u003cp\u003e13.4.3 Catalyst activation in commercial hydrotreaters, 316\u003c\/p\u003e \u003cp\u003e13.5 Reactor modeling and simulation, 317\u003c\/p\u003e \u003cp\u003e13.5.1 Process description, 317\u003c\/p\u003e \u003cp\u003e13.5.2 Summary of experiments, 317\u003c\/p\u003e \u003cp\u003e13.5.3 Modeling approach, 319\u003c\/p\u003e \u003cp\u003e13.5.4 Simulation of the bench-scale unit, 320\u003c\/p\u003e \u003cp\u003e13.5.5 Scale-up of bench-unit data, 323\u003c\/p\u003e \u003cp\u003e13.5.6 Simulation of the commercial unit, 324\u003c\/p\u003e \u003cp\u003eNomenclature, 326\u003c\/p\u003e \u003cp\u003eGreek letters, 327\u003c\/p\u003e \u003cp\u003eSubscripts, 327\u003c\/p\u003e \u003cp\u003eNon-SI units, 327\u003c\/p\u003e \u003cp\u003eReferences, 327\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Catalytic reactors for fuel processing, 330\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eGunther Kolb\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction—The basic reactions of fuel processing, 330\u003c\/p\u003e \u003cp\u003e14.2 Theoretical aspects, advantages, and drawbacks of fixed beds versus monoliths, microreactors, and membrane reactors, 331\u003c\/p\u003e \u003cp\u003e14.3 Reactor design and fabrication, 332\u003c\/p\u003e \u003cp\u003e14.3.1 Fixed-bed reactors, 332\u003c\/p\u003e \u003cp\u003e14.3.2 Monolithic reactors, 332\u003c\/p\u003e \u003cp\u003e14.3.3 Microreactors, 332\u003c\/p\u003e \u003cp\u003e14.3.4 Membrane reactors, 333\u003c\/p\u003e \u003cp\u003e14.4 Reformers, 333\u003c\/p\u003e \u003cp\u003e14.4.1 Fixed-bed reformers, 336\u003c\/p\u003e \u003cp\u003e14.4.2 Monolithic reformers, 337\u003c\/p\u003e \u003cp\u003e14.4.3 Plate heat exchangers and microstructured reformers, 342\u003c\/p\u003e \u003cp\u003e14.4.4 Membrane reformers, 344\u003c\/p\u003e \u003cp\u003e14.5 Water-gas shift reactors, 348\u003c\/p\u003e \u003cp\u003e14.5.1 Monolithic reactors, 348\u003c\/p\u003e \u003cp\u003e14.5.2 Plate heat exchangers and microstructured water-gas shift reactors, 348\u003c\/p\u003e \u003cp\u003e14.5.3 Water-gas shift in membrane reactors, 350\u003c\/p\u003e \u003cp\u003e14.6 Carbon monoxide fine cleanup: Preferential oxidation and selective methanation, 350\u003c\/p\u003e \u003cp\u003e14.6.1 Fixed-bed reactors, 352\u003c\/p\u003e \u003cp\u003e14.6.2 Monolithic reactors, 352\u003c\/p\u003e \u003cp\u003e14.6.3 Plate heat exchangers and microstructured reactors, 353\u003c\/p\u003e \u003cp\u003e14.7 Examples of complete fuel processors, 355\u003c\/p\u003e \u003cp\u003e14.7.1 Monolithic fuel processors, 355\u003c\/p\u003e \u003cp\u003e14.7.2 Plate heat exchanger fuel processors on the meso- and microscale, 357\u003c\/p\u003e \u003cp\u003eNomenclature, 359\u003c\/p\u003e \u003cp\u003eReferences, 359\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Modeling of the catalytic deoxygenation of fatty acids in a packed bed reactor, 365\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eTeuvo Kilpiö, Päivi Mäki-Arvela, Tapio Salmi and Dmitry Yu. Murzin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction, 365\u003c\/p\u003e \u003cp\u003e15.2 Experimental data for stearic acid deoxygenation, 366\u003c\/p\u003e \u003cp\u003e15.3 Assumptions, 366\u003c\/p\u003e \u003cp\u003e15.4 Model equations, 367\u003c\/p\u003e \u003cp\u003e15.5 Evaluation of the adsorption parameters, 368\u003c\/p\u003e \u003cp\u003e15.6 Particle diffusion study, 369\u003c\/p\u003e \u003cp\u003e15.7 Parameter sensitivity studies, 369\u003c\/p\u003e \u003cp\u003e15.8 Parameter identification studies, 370\u003c\/p\u003e \u003cp\u003e15.9 Studies concerning the deviation from ideal plug flow conditions, 371\u003c\/p\u003e \u003cp\u003e15.10 Parameter estimation results, 372\u003c\/p\u003e \u003cp\u003e15.11 Scale-up considerations, 372\u003c\/p\u003e \u003cp\u003e15.12 Conclusions, 375\u003c\/p\u003e \u003cp\u003eAcknowledgments, 375\u003c\/p\u003e \u003cp\u003eNomenclature, 375\u003c\/p\u003e \u003cp\u003eGreek letters, 375\u003c\/p\u003e \u003cp\u003eReferences, 376\u003c\/p\u003e \u003cp\u003eIndex, 377\u003c\/p\u003e \u003cp\u003e\u003cb\u003eZeynep Ilsen Önsan\u003c\/b\u003e received her B.Sc degree (1968) in chemical engineering from former Robert College (now Bogazici University), Istanbul-Turkey, and her Ph.D. degree and D.I.C. (1972) in chemical engineering and heterogeneous catalysis from Imperial College, London-UK. She pioneered in establishing heterogeneous catalysis research in Turkey at Bogazici University, directed several sizeable research and institution-building projects, and has 40 years of teaching and research experience in heterogeneous catalysis and chemical reaction engineering and 25 years of research collaboration and teaching in bioreaction engineering. Dr. Önsan is a professor of chemical engineering at Bogazici University and has 85 research papers including 74 articles in \u003ci\u003eSCI\u003c\/i\u003e journals and a book chapter coauthored with Dr. Avci on reactor design for fuel processing.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eAhmet Kerim Avci\u003c\/b\u003e received BS, MS and PhD degrees in chemical engineering from Bogazici University in 1996, 1997 and 2003, respectively. He worked as an R\u0026amp;D manager in Procter \u0026amp; Gamble, Brussels-Belgium. In 2005, he joined chemical engineering department of Bogazici University, where he is currently a full professor. He is the leader of numerous research projects funded by governmental institutes and industry, and is the author of more than 25 papers in refereed \u003ci\u003eSCI\u003c\/i\u003e journals. He is the holder of Distinguished Young Scientist Fellowship (Turkish Academy of Sciences, 2009), Excellence in Research Award (Bogazici University Foundation, 2010), Eser Tumen Outstanding Achievement Award for Young Scientists (2011) and Professor Mustafa N. Parlar Research Incentive Award (2011).\u003c\/p\u003e \u003cp\u003e\u003cb\u003eThis book combines all aspects of multiphase catalytic reactors from modeling and design to their applications in industrial manufacturing of chemicals. \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eThe single irreplaceable component at the core of a chemical process is the chemical reactor where feed materials are converted into desirable products. The impact of heterogeneous catalysis is significant in this respect since petroleum refining, chemicals manufacturing and environmental clean-up, which are the three major areas of the world economy today, all require the effective use of solid catalysts. \u003ci\u003eMultiphase Catalytic Reactors: Theory, Design, Manufacturing and Applications\u003c\/i\u003e is a comprehensive up-to-date compilation on multiphase catalytic reactors.\u003c\/p\u003e \u003cp\u003eThe book covers topics starting from the first principles involved in macro-kinetic analysis of two- and three-phase catalytic reactors to their particular industrial applications. The main objective is to provide definitive accounts on academic aspects of multiphase catalytic reactor modeling and design along with detailed descriptions of some of the most recent industrial applications employing multiphase catalytic reactors.\u003c\/p\u003e \u003cp\u003eOrganized in six parts \u003ci\u003eMultiphase Catalytic Reactors \u003c\/i\u003efeatures:\u003c\/p\u003e \u003cul\u003e \u003cli\u003ePrinciples of Catalytic Reaction Engineering\u003c\/li\u003e \u003cli\u003eTwo-Phase Catalytic Reactors\u003c\/li\u003e \u003cli\u003eThree-Phase Catalytic Reactors\u003c\/li\u003e \u003cli\u003eStructured Reactors\u003c\/li\u003e \u003cli\u003eEssential Tools of Reactor Modeling and Design\u003c\/li\u003e \u003cli\u003eIndustrial Applications of Multiphase Reactors\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThe topics covered in individual chapters of this comprehensive book are written by leading experts in the field, and the book will serve as an excellent reference source for professors, graduate students, researchers and specialists both in academia and in industry.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eZeynep Ilsen Önsan\u003c\/b\u003e received her B.Sc degree (1968) in chemical engineering from former Robert College (now Bogazici University), Istanbul-Turkey, and her Ph.D. degree and D.I.C. (1972) in chemical engineering and heterogeneous catalysis from Imperial College, London-UK. She pioneered in establishing heterogeneous catalysis research in Turkey at Bogazici University, directed several sizeable research and institution-building projects, and has 40 years of teaching and research experience in heterogeneous catalysis and chemical reaction engineering and 25 years of research collaboration and teaching in bioreaction engineering. Dr. Önsan is a  professor of chemical engineering at Bogazici University and has 85 research papers including 74 articles in SCI journals  and a book chapter coauthored with Dr. Avci on reactor design for fuel processing.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eAhmet Kerim Avci\u003c\/b\u003e received BS, MS and PhD degrees in chemical engineering from Bogazici University in 1996, 1997 and 2003, respectively. He worked as an R\u0026amp;D manager in Procter \u0026amp; Gamble, Brussels-Belgium. In 2005, he joined chemical engineering department of Bogazici University, where he is currently a full professor. He is the leader of numerous research projects funded by governmental institutes and industry, and is the author of more than 25 papers in refereed SCI journals. He is the holder of Distinguished Young Scientist Fellowship (Turkish Academy of Sciences, 2009), Excellence in Research Award (Bogaziçi University Foundation, 2010), Eser Tumen Outstanding Achievement Award for Young Scientists (2011) and Prof. Mustafa N. Parlar Research Incentive Award (2011).\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989661827301,"sku":"NP9781118115763","price":163.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781118115763.jpg?v=1761785005","url":"https:\/\/k12savings.com\/es\/products\/multiphase-catalytic-reactors-isbn-9781118115763","provider":"K12savings","version":"1.0","type":"link"}