{"product_id":"molecular-spectroscopy-of-oxide-catalyst-surfaces-isbn-9780471987314","title":"Molecular Spectroscopy of Oxide Catalyst Surfaces","description":"As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet\/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated.\u003cbr\u003e The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented.\u003cbr\u003e This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides.Erst vor relativ kurzer Zeit entdeckte die Oberflächenwissenschaft Metalloxid-Spezies für sich; seit 1984 entwickelte sich dieses Gebiet jedoch rasant.\u003cbr\u003e \u003cbr\u003e Aus der spektroskopischen Untersuchung von Molekülen, die an Metalloxid-Oberflächen adsorbiert sind, lassen sich Informationen über die Natur dieser Flächen ableiten.\u003cbr\u003e \u003cbr\u003e Das Buch erklärt dem Nicht-Spektroskopiker alle wichtigen theoretischen Grundlagen und praktischen Details und ist damit von besonderem Interesse für Forscher aus der Katalysator- und Umwelttechnik. Preface.\u003cbr\u003e \u003cbr\u003e Symbols and abbreviations.\u003cbr\u003e \u003cbr\u003e Introduction.\u003cbr\u003e \u003cbr\u003e 1. Theoretical fundamentals and experimental considerations of spectroscopic methods used in surface chemistry.\u003cbr\u003e \u003cbr\u003e Electronic spectroscopy (ES).\u003cbr\u003e \u003cbr\u003e Vibrational spectroscopy.\u003cbr\u003e \u003cbr\u003e Electron energy loss spectroscopy (EELS).\u003cbr\u003e \u003cbr\u003e Inelastic electron tunneling spectroscopy (IETS).\u003cbr\u003e \u003cbr\u003e Inelastic neutron scattering spectroscopy (INS).\u003cbr\u003e \u003cbr\u003e Other vibrational spectroscopies.\u003cbr\u003e \u003cbr\u003e In situ measurements.\u003cbr\u003e \u003cbr\u003e Quantitative measurements.\u003cbr\u003e \u003cbr\u003e 2. Nature of oxide surface centers.\u003cbr\u003e \u003cbr\u003e Systems investigated.\u003cbr\u003e \u003cbr\u003e Spectral of oxide surfaces.\u003cbr\u003e \u003cbr\u003e Determination of the nature of surface sites and their chemical properties using the adsorption of simple molecules.\u003cbr\u003e \u003cbr\u003e Determination of acidic surface properties.\u003cbr\u003e \u003cbr\u003e Determination of basic surface properties.\u003cbr\u003e \u003cbr\u003e Surface defects.\u003cbr\u003e \u003cbr\u003e 3. Study of cation states by DRES and FT-IR spectroscopies of the probe molecules.\u003cbr\u003e \u003cbr\u003e Copper-containing systems.\u003cbr\u003e \u003cbr\u003e Nickel-containing systems.\u003cbr\u003e \u003cbr\u003e Co-containing systems.\u003cbr\u003e \u003cbr\u003e Iron-containing systems.\u003cbr\u003e \u003cbr\u003e Silver-containing systems.\u003cbr\u003e \u003cbr\u003e Palladium-containing systems.\u003cbr\u003e \u003cbr\u003e Rhenium-, Ruthenium-, and Rhodium-containing systems.\u003cbr\u003e \u003cbr\u003e Platinum-containing systems.\u003cbr\u003e \u003cbr\u003e Molybdenum-containing systems.\u003cbr\u003e \u003cbr\u003e Vanadium-containing systems.\u003cbr\u003e \u003cbr\u003e Chromium-containing systems.\u003cbr\u003e \u003cbr\u003e Effects of the state of adsorption sites on the stretching frequencies of adsorbed Carbon monoxide and Nitrous oxide and the problem of detecting the states of cations in oxide catalyst surfaces.\u003cbr\u003e \u003cbr\u003e 4. Interactions of inorganic compounds with oxide surface active sites.\u003cbr\u003e \u003cbr\u003e Organometallic complexes.\u003cbr\u003e \u003cbr\u003e Metal carbonyls and nitrosyls.\u003cbr\u003e \u003cbr\u003e Interaction with simple acids and bases.\u003cbr\u003e \u003cbr\u003e Heteropoly compounds Systems.\u003cbr\u003e \u003cbr\u003e Thermal stability of molybdenum compounds, decomposition mechanism and the role of modifiers.\u003cbr\u003e \u003cbr\u003e Cationic modification.\u003cbr\u003e \u003cbr\u003e 5. Formation of surface complexes of organic molecule.\u003cbr\u003e \u003cbr\u003e Complexation of Alkenes.\u003cbr\u003e \u003cbr\u003e Complexation of Aryls and aryl halides.\u003cbr\u003e \u003cbr\u003e Complexation of Alkynes.\u003cbr\u003e \u003cbr\u003e Complexation of Alkanes.\u003cbr\u003e \u003cbr\u003e Complexation of Nitriles.\u003cbr\u003e \u003cbr\u003e Complexation of Alcohols.\u003cbr\u003e \u003cbr\u003e Complexation of Aldehyde and ketone.\u003cbr\u003e \u003cbr\u003e Complexation of Acids.\u003cbr\u003e \u003cbr\u003e 6. The mechanisms of heterogeneous catalytic reactions.\u003cbr\u003e \u003cbr\u003e Reactions involving carbon monoxide.\u003cbr\u003e \u003cbr\u003e Reactions with participation of hydrocarbons.\u003cbr\u003e \u003cbr\u003e Transformations of aldehydes and ketones.\u003cbr\u003e \u003cbr\u003e Transformations of alcohols\u003cbr\u003e \u003cbr\u003e Transformations of nitrogen-containing compounds.\u003cbr\u003e \u003cbr\u003e References.\u003cbr\u003e \u003cbr\u003e Index. \"…this comprehensive book is truly indispensable as a reference text for researchers engaged in the surface chemistry of oxide surfaces.\" (\u003ci\u003eJournal of the American Chemical Society\u003c\/i\u003e, Vol. 126)  \u003cp\u003e\u003cstrong\u003eAnatoli Davydov\u003c\/strong\u003e is the author of \u003cem\u003eMolecular Spectroscopy of Oxide Catalyst Surfaces\u003c\/em\u003e, published by Wiley.  As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet\/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated.\u003cbr\u003e \u003cbr\u003e The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented.\u003cbr\u003e \u003cbr\u003e This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989649604837,"sku":"NP9780471987314","price":605.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780471987314.jpg?v=1761784958","url":"https:\/\/k12savings.com\/es\/products\/molecular-spectroscopy-of-oxide-catalyst-surfaces-isbn-9780471987314","provider":"K12savings","version":"1.0","type":"link"}