{"product_id":"microscale-inorganic-chemistry-isbn-9780471619963","title":"Microscale Inorganic Chemistry","description":"This text is intended to provide students with instruction and valuable laboratory experience in the often neglected area of inorganic chemistry. Divided into four main parts, the book covers chemistry of the main group elements, chemistry of the transition metals, organometallic chemistry, and bioinorganic chemistry. Recognizing the high cost of materials, difficulties in waste disposal, and dangers of toxicity, the authors have adopted a ``microscale'' approach to experiments in the book, thereby also reducing the time students spend in preparation. With over 45 experiments, Microscale Inorganic Chemistry incorporates the use of a broad sampling of elements and also covers such topics as laboratory safety, equipment, report writing, and literature searching. \u003cp\u003eList of Tables xvii\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIntroduction 1–3\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eA. A Brief History of Inorganic Chemistry 1\u003c\/p\u003e \u003cp\u003eB. The Microscale Approach 2\u003c\/p\u003e \u003cp\u003eC. A Word to the Student 3\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1 Safety in the Laboratory 5–17\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.A General Safety Rules 5\u003c\/p\u003e \u003cp\u003e1.A.1 Introduction 5\u003c\/p\u003e \u003cp\u003e1.A.2 Before the Laboratory 6\u003c\/p\u003e \u003cp\u003e1.A.3 Safety Rules in the Laboratory 6\u003c\/p\u003e \u003cp\u003e1.B Planning for Chemicaly Safety 8\u003c\/p\u003e \u003cp\u003e1.B.1 Introduction 8\u003c\/p\u003e \u003cp\u003e1.B.2 Use of MSD Sheets 8\u003c\/p\u003e \u003cp\u003e1.B.3 The Merck Index 12\u003c\/p\u003e \u003cp\u003e1.B.4 Compressed Gas Cylinders and Lecture Bottles 13\u003c\/p\u003e \u003cp\u003e1.B.5 Fire Safety 16\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2 Laboratory Equipment 19–29\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.A Glassware 19\u003c\/p\u003e \u003cp\u003e2.B Other Locker Equipment 21\u003c\/p\u003e \u003cp\u003e2.C Measuring Quantities of Chemicals 22\u003c\/p\u003e \u003cp\u003e2.C.1 Weighing 22\u003c\/p\u003e \u003cp\u003e2.C.2 Liquid Volumes 22\u003c\/p\u003e \u003cp\u003e2.D Heating Methods 25\u003c\/p\u003e \u003cp\u003e2.D.1 The Microburner 25\u003c\/p\u003e \u003cp\u003e2.D.2 Steam Bath 25\u003c\/p\u003e \u003cp\u003e2.D.3 Oil Baths 25\u003c\/p\u003e \u003cp\u003e2.D.4 Infrared Lamp 26\u003c\/p\u003e \u003cp\u003e2.D.5 Sand Bath or Aluminum Block with Magnetic Stirring Hot Plate 26\u003c\/p\u003e \u003cp\u003e2.E Stirring 27\u003c\/p\u003e \u003cp\u003e2.F Reflux and Distillation 27\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3 Writing Laboratory Reports 31–35\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.A Introduction 31\u003c\/p\u003e \u003cp\u003e3.B Maintenance of the Laboratory Notebook 31\u003c\/p\u003e \u003cp\u003e3.C The Laboratory Report 34\u003c\/p\u003e \u003cp\u003e3.D Proper Citation and Plagiarism 35\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4 Literature Searching and the Inorganic Literature 37–47\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.A Literature Searching 37\u003c\/p\u003e \u003cp\u003e4.A.1 Chemical Abstracts Method 37\u003c\/p\u003e \u003cp\u003eSearching a Topic in Chemical Abstracts 38\u003c\/p\u003e \u003cp\u003eUse of the Formula Index 38\u003c\/p\u003e \u003cp\u003eUse of the General Subject Index 40\u003c\/p\u003e \u003cp\u003eCAS Online 40\u003c\/p\u003e \u003cp\u003eAdvantages and Disadvatages of Chemical Abstracts 40\u003c\/p\u003e \u003cp\u003e4.A.2 Use of the Science Citation Index 41\u003c\/p\u003e \u003cp\u003eSearching Using the Printed Science Citation Index 41\u003c\/p\u003e \u003cp\u003eSearching Using the Compact Disc Science Citation Index 42\u003c\/p\u003e \u003cp\u003eSearching Using the Citation Index 42\u003c\/p\u003e \u003cp\u003eAdvantages and Disadvatages of the Science Citation Index 44\u003c\/p\u003e \u003cp\u003e4.A.3 Comparison of the Two Methods 44\u003c\/p\u003e \u003cp\u003e4.B The Inorganic Chemical Literature 44\u003c\/p\u003e \u003cp\u003e4.B.1 Introduction 44\u003c\/p\u003e \u003cp\u003e4.B.2 Purely Inorganic Journals 44\u003c\/p\u003e \u003cp\u003e4.B.3 General Coverage Journals 45\u003c\/p\u003e \u003cp\u003e4.B.4 Review Journals and Monographs Covering Inorganic Chemistry 45\u003c\/p\u003e \u003cp\u003e4.B.5 Major Comprehensive Books on Inorganic Chemistry 46\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5 Inorganic Microscale Laboratory Techniques 49–105\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.A Microscale Determination of Magnetic Susceptibility 49\u003c\/p\u003e \u003cp\u003e5.A.1 Introduction 49\u003c\/p\u003e \u003cp\u003e5.A.2 Measurement of Magnetic Susceptibility 50\u003c\/p\u003e \u003cp\u003e5.A.3 Calculation of Magnetic Moment from Magnetic Susceptibility 52\u003c\/p\u003e \u003cp\u003e5.A.4 Operation of the Evans–Johnson Matthey Balance for Solids 54\u003c\/p\u003e \u003cp\u003e5.A.5 Operation for Liquids and Solutions 55\u003c\/p\u003e \u003cp\u003e5.A.6 Determining Magnetic Susceptibility by NMR Spectroscopy 56\u003c\/p\u003e \u003cp\u003e5.B Thermal Analysis 57\u003c\/p\u003e \u003cp\u003e5.B.1 Introduction 57\u003c\/p\u003e \u003cp\u003e5.B.2 Differential Scanning Calorimetry and Differential Thermal Analysis 57\u003c\/p\u003e \u003cp\u003e5.B.3 Thermogravimetric Analysis 58\u003c\/p\u003e \u003cp\u003e5.B.4 Variables in Thermal Analysis 58\u003c\/p\u003e \u003cp\u003e5.B.5 Analysis of the Thermogram 59\u003c\/p\u003e \u003cp\u003e5.B.6 Theoretical Aspects 60\u003c\/p\u003e \u003cp\u003e5.B.7 Applications 61\u003c\/p\u003e \u003cp\u003e5.C Vacuum and Inert Atmosphere Techniques 62\u003c\/p\u003e \u003cp\u003eIntroduction 62\u003c\/p\u003e \u003cp\u003e5.C.1 Purging with an Inert Gas 62\u003c\/p\u003e \u003cp\u003e5.C.2 Use of Manifold for Inert Gas or Vacuum 64\u003c\/p\u003e \u003cp\u003eRough Pump 64\u003c\/p\u003e \u003cp\u003eCold Trap 64\u003c\/p\u003e \u003cp\u003eManifold 65\u003c\/p\u003e \u003cp\u003eMultiple Vacuum Lines in Series 65\u003c\/p\u003e \u003cp\u003eUse and Operation of Manifolds 65\u003c\/p\u003e \u003cp\u003e5.C.3 Cannula Techniques 66\u003c\/p\u003e \u003cp\u003e5.D Crystallization Techniques 67\u003c\/p\u003e \u003cp\u003e5.D.1 Introduction 67\u003c\/p\u003e \u003cp\u003e5.D.2 Crystallization from Solution 67\u003c\/p\u003e \u003cp\u003e5.D.3 Isolation of Crystalline Products (Suction Filtration) 69\u003c\/p\u003e \u003cp\u003e5.D.4 The Craig Tube Method 69\u003c\/p\u003e \u003cp\u003e5.D.5 Recrystallization Pipet 70\u003c\/p\u003e \u003cp\u003e5.D.6 Removal of Suspended Particles from Solution 71\u003c\/p\u003e \u003cp\u003e5.D.7 Washing of the Collected Crystals 71\u003c\/p\u003e \u003cp\u003e5.D.8 Decolorization 72\u003c\/p\u003e \u003cp\u003e5.D.9 Drying Techniques 73\u003c\/p\u003e \u003cp\u003e5.E Determination of Melting Points 74\u003c\/p\u003e \u003cp\u003e5.E.1 Introduction 74\u003c\/p\u003e \u003cp\u003e5.E.2 Theory 74\u003c\/p\u003e \u003cp\u003e5.E.3 Mixture Melting Point Determination 75\u003c\/p\u003e \u003cp\u003e5.E.4 Correcting Melting Points 76\u003c\/p\u003e \u003cp\u003e5.E.5 Determination of the Melting Point Range 77\u003c\/p\u003e \u003cp\u003e5.E.6 Melting Point Apparatus 78\u003c\/p\u003e \u003cp\u003eThe Thiele Tube 78\u003c\/p\u003e \u003cp\u003eThe Mel-Temp Apparatus 78\u003c\/p\u003e \u003cp\u003eThe Fisher–Johns Apparatus 78\u003c\/p\u003e \u003cp\u003eThe Thomas–Hoover Apparatus 81\u003c\/p\u003e \u003cp\u003e5.F Concentration of Solutions 81\u003c\/p\u003e \u003cp\u003e5.F.1 Introduction 81\u003c\/p\u003e \u003cp\u003e5.F.2 Evaporation Techniques 81\u003c\/p\u003e \u003cp\u003e5.F.3 Removal of Solvent Under Reduced Pressure 81\u003c\/p\u003e \u003cp\u003e5.G Chromatography 82\u003c\/p\u003e \u003cp\u003e5.G.1 Introduction 82\u003c\/p\u003e \u003cp\u003e5.G.2 Thin-Layer Chromatography 84\u003c\/p\u003e \u003cp\u003e5.G.3 Gas Chromatography: Introduction 86\u003c\/p\u003e \u003cp\u003eComponents of the Gas Chromatograph 87\u003c\/p\u003e \u003cp\u003e5.G.4 Liquid Chromatography 89\u003c\/p\u003e \u003cp\u003eIon and Ion Exchange Chromatography 89\u003c\/p\u003e \u003cp\u003eHigh-Performance Liquid Chromatography 90\u003c\/p\u003e \u003cp\u003e5.H Sublimation 92\u003c\/p\u003e \u003cp\u003e5.H.1 Introduction 92\u003c\/p\u003e \u003cp\u003e5.H.2 Theory 93\u003c\/p\u003e \u003cp\u003e5.H.3 Sublimation Technique 93\u003c\/p\u003e \u003cp\u003e5.I Solvent Extraction 94\u003c\/p\u003e \u003cp\u003e5.I.1 Introduction 94\u003c\/p\u003e \u003cp\u003e5.I.2 Theory 94\u003c\/p\u003e \u003cp\u003e5.I.3 Extraction Procedures: Simple Extraction 97\u003c\/p\u003e \u003cp\u003eUse of the Separatory Funnel 97\u003c\/p\u003e \u003cp\u003ePasteur Filter Pipet Extractions 99\u003c\/p\u003e \u003cp\u003e5.I.4 Continuous Extraction 100\u003c\/p\u003e \u003cp\u003e5.I.5 Drying of the Wet Organic Layer 100\u003c\/p\u003e \u003cp\u003e5.I.6 Drying of Organic Solvents 101\u003c\/p\u003e \u003cp\u003e5.J Conductivity Measurements 102\u003c\/p\u003e \u003cp\u003e5.J.1 Introduction 102\u003c\/p\u003e \u003cp\u003e5.J.2 Experimental Procedure 104\u003c\/p\u003e \u003cp\u003e5.J.3 Non-Aqueous Solutions 105\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 6 Spectroscopy 107–146\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.A Introduction 107\u003c\/p\u003e \u003cp\u003e6.A.1 Spectrometer Components 108\u003c\/p\u003e \u003cp\u003e6.B Visible Spectroscopy 109\u003c\/p\u003e \u003cp\u003e6.B.1 Introduction and Theory 109\u003c\/p\u003e \u003cp\u003e6.B.2 The Visible Spectrum 110\u003c\/p\u003e \u003cp\u003e6.B.3 Molar Absorbance and Color 111\u003c\/p\u003e \u003cp\u003e6.B.4 Size of the Crystal Field Splitting 112\u003c\/p\u003e \u003cp\u003e6.B.5 Energy Level Diagrams l12\u003c\/p\u003e \u003cp\u003e6.C Infrared Spectroscopy 114\u003c\/p\u003e \u003cp\u003e6.C.1 Introduction 114\u003c\/p\u003e \u003cp\u003e6.C.2 Sample Handling 115\u003c\/p\u003e \u003cp\u003e6.C.3 Bond Vibrations 1l6\u003c\/p\u003e \u003cp\u003e6.C.4 Vibrational Modes 119\u003c\/p\u003e \u003cp\u003e6.C.5 Inorganic Functional Groups 121\u003c\/p\u003e \u003cp\u003e6.C.6 Synergistic Effects 121\u003c\/p\u003e \u003cp\u003e6.C.7 Interpretation of IR Spectra 122\u003c\/p\u003e \u003cp\u003e6.C.8 Fourier Transform lnfrared 123\u003c\/p\u003e \u003cp\u003e6.D Nuclear Magnetic Resonance Spectroscopy 125\u003c\/p\u003e \u003cp\u003e6.D.1 Introduction 125\u003c\/p\u003e \u003cp\u003e6.D.2 Sample Preparation 128\u003c\/p\u003e \u003cp\u003e6.D.3 Reference Materials 129\u003c\/p\u003e \u003cp\u003e6.D.4 The Chemical Shift 129\u003c\/p\u003e \u003cp\u003e6.D.5 Integration 131\u003c\/p\u003e \u003cp\u003e6.D.6 Spin–Spin Coupling 132\u003c\/p\u003e \u003cp\u003e6.D.7 \u003csup\u003e13\u003c\/sup\u003eC-NMR Spectroscopy 133\u003c\/p\u003e \u003cp\u003e6.D.8 Quadrupolar Nuclei 136\u003c\/p\u003e \u003cp\u003e6.D.9 The Coupling Constant 136\u003c\/p\u003e \u003cp\u003e6.D.10 Interpretation of Inorganic Spectra 137\u003c\/p\u003e \u003cp\u003e6.D.11 Spectral Collapse l38\u003c\/p\u003e \u003cp\u003e6.D.12 Decoupling 139\u003c\/p\u003e \u003cp\u003e6.D.13 Identification of Isomers 139\u003c\/p\u003e \u003cp\u003e6.E Atomic Absorption Spectroscopy 141\u003c\/p\u003e \u003cp\u003e6.E.1 Introduction 141\u003c\/p\u003e \u003cp\u003e6.E.2 Theory 141\u003c\/p\u003e \u003cp\u003e6.E.3 The Instrument 142\u003c\/p\u003e \u003cp\u003eThe Flame 142\u003c\/p\u003e \u003cp\u003eThe Nebulizer Burner System 142\u003c\/p\u003e \u003cp\u003eThe Light Source 144\u003c\/p\u003e \u003cp\u003eThe Monochromator 144\u003c\/p\u003e \u003cp\u003eThe Detector 144\u003c\/p\u003e \u003cp\u003e6.E.4 Measurement of Concentration 144\u003c\/p\u003e \u003cp\u003e6.E.5 Other Considerations 145\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 7 Chemistry of the Main Group Elements 147–215\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExperiment 1 Preparation of Sodium Amide 148\u003c\/p\u003e \u003cp\u003eExperiment 2 Synthesis and Thermal Analysis of the Group 2 (IIA)\u003c\/p\u003e \u003cp\u003eMetal Oxalate Hydrates 152\u003c\/p\u003e \u003cp\u003eExperiment 3 Atomic Absorption Analysis of Magnesium and Calcium 155\u003c\/p\u003e \u003cp\u003eExperiment 4 Preparation of Trialkoxyborates 158\u003c\/p\u003e \u003cp\u003ePart A Preparation of Tri-n-propylborate 160\u003c\/p\u003e \u003cp\u003ePart B Preparation of a Poly(vinylalcohol)–Borate Copolymer 161\u003c\/p\u003e \u003cp\u003eExperiment 5 Synthesis of Tetrafluoroberyllate and\u003c\/p\u003e \u003cp\u003eTetrafluoroborate Complexes 163\u003c\/p\u003e \u003cp\u003ePart A Synthesis of Ammonium Tetrafluoroberyllate, (NH\u003csub\u003e4\u003c\/sub\u003e)\u003csub\u003e2\u003c\/sub\u003e[BeF\u003csub\u003e4\u003c\/sub\u003e] 164\u003c\/p\u003e \u003cp\u003ePart B Synthesis of Ammonium Tetrafluoroborate, NH\u003csub\u003e4\u003c\/sub\u003e[BF\u003csub\u003e4\u003c\/sub\u003e] 165\u003c\/p\u003e \u003cp\u003eExperiment 6 Synthesis of Dichlorophenylborane 167\u003c\/p\u003e \u003cp\u003eExperiment 7 Synthesis and Reactions of Carboranes 170\u003c\/p\u003e \u003cp\u003ePart A Preparation of Potassium Dodecahydro-7-8-dicarba-\u003ci\u003enido\u003c\/i\u003e-undecarborate(1-), a Carborane Anion 172\u003c\/p\u003e \u003cp\u003ePart B Preparation of 3-[η\u003csup\u003e5\u003c\/sup\u003e-Cyclopentadienyl)-1,2-dicarba-3-cobalta-\u003ci\u003ecloso\u003c\/i\u003e-dodecaborane(11), a Metal Carborane 173\u003c\/p\u003e \u003cp\u003eExperiment 8 Silicone Polymers: Preparation of Bouncing Putty 176\u003c\/p\u003e \u003cp\u003eExperiment 9 The Oxidation States of Tin 181\u003c\/p\u003e \u003cp\u003ePart A Preparation of Tin(IV) Iodide 183\u003c\/p\u003e \u003cp\u003ePart B Preparation of Tin(II) Iodide 184\u003c\/p\u003e \u003cp\u003eExperiment 10 Relative Stabilities of Tin(IV) and Lead(IV) 186\u003c\/p\u003e \u003cp\u003ePart A Preparation of Ammonium Hexachlorostannate(IV) 186\u003c\/p\u003e \u003cp\u003ePart B Preparation of Ammonium Hexachloroplumbate(IV) 187\u003c\/p\u003e \u003cp\u003eExperiment 11 Preparation of Substituted 1,2,3,4-Thiatriazoles 189\u003c\/p\u003e \u003cp\u003ePart A Preparation of 5-Anilino-1,2,3,4-thiatriazole 190\u003c\/p\u003e \u003cp\u003ePart B Preparation of 5-Amino-1,2,3,4-thiatriazole 191\u003c\/p\u003e \u003cp\u003eExperiment 12 Synthesis of Hexakis(4-nitrophenoxy) cyclotriphosphazene 193\u003c\/p\u003e \u003cp\u003ePart A Preparation of Potassium 4-Nitrophenoxide 194\u003c\/p\u003e \u003cp\u003ePart B Preparation of Hexakis(4-nitrophenoxy) cyclotriphosphazene 195\u003c\/p\u003e \u003cp\u003eExperiment 13 Synthesis of Ammonium Phosphoramidate 197\u003c\/p\u003e \u003cp\u003eExperiment 14 Preparation of an Explosive: Nitrogen Triiodide Ammoniate 199\u003c\/p\u003e \u003cp\u003eExperiment 15 Synthesis of Trichlorodiphenylantimony[V) Hydrate 201\u003c\/p\u003e \u003cp\u003eExperiment 16 Preparation of Tetrathionate 204\u003c\/p\u003e \u003cp\u003ePart A Determination of Reaction Quantities 205\u003c\/p\u003e \u003cp\u003ePart B Quantitative Preparation of Sodium Tetrathionate 206\u003c\/p\u003e \u003cp\u003eExperiment 17 Thione Complexes of Cobalt(II) Nitrate Hexahydrate 207\u003c\/p\u003e \u003cp\u003ePart A Synthesis of Co(mimt)\u003csub\u003e4\u003c\/sub\u003e(NO\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e2\u003c\/sub\u003e·H\u003csub\u003e2\u003c\/sub\u003eO 209\u003c\/p\u003e \u003cp\u003ePart B Synthesis of Co(mimt)\u003csub\u003e2\u003c\/sub\u003e(NO\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e2 \u003c\/sub\u003e209\u003c\/p\u003e \u003cp\u003eExperiment 18 Positive Oxidation States of Iodine: Preparation of Dipyridineiodine(I) Nitrate 210\u003c\/p\u003e \u003cp\u003eExperiment 19 Synthesis of Interhalogens: Iodine Trichloride 213\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 8 Chemistry of the Transition Metals 217\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExperiment 20 Metal Complexes of Dimethyl Sulfoxide 218\u003c\/p\u003e \u003cp\u003ePart A Preparation of CuCl\u003csub\u003e2\u003c\/sub\u003e·2DMSO 220\u003c\/p\u003e \u003cp\u003ePart B Preparation of PdCl\u003csub\u003e2\u003c\/sub\u003e·2DMSO 221\u003c\/p\u003e \u003cp\u003ePart C Preparation of RuCl\u003csub\u003e2\u003c\/sub\u003e·4DMSO 221\u003c\/p\u003e \u003cp\u003eExperin1ent 21 Preparation of trans-Dichlorotetrapyridinerhodium(III) Chloride 222\u003c\/p\u003e \u003cp\u003eExperiment 22 Synthesis of Metal Acetylacetonates 224\u003c\/p\u003e \u003cp\u003ePart A Preparation of Tris(2,4-pentanedionato) chromium(III) 226\u003c\/p\u003e \u003cp\u003ePart B Preparation of Tris(2,4-pentanedionato) manganese(III) 227\u003c\/p\u003e \u003cp\u003eExperiment 23 Gas Chromatographic Analysis of Brominated Tris(2,4-pentanedionato) chromium(III) 229\u003c\/p\u003e \u003cp\u003eExperiment 24 Determination of Magnetic Moments in Metal–Metal Bonded Complexes 231\u003c\/p\u003e \u003cp\u003ePart A Synthesis of Rhodium(II) Acetate Ethanolate 232\u003c\/p\u003e \u003cp\u003ePart B Synthesis of Copper(II) Acetate Monohydrate 234\u003c\/p\u003e \u003cp\u003eExperiment 25 Multiply Bonded Species: Preparation of Tetrabutylammonium Octachlorodirhenate(III) 235\u003c\/p\u003e \u003cp\u003eExperiment 26 Geometic Isomerism 239\u003c\/p\u003e \u003cp\u003ePart A Synthesis of trans-Dichlorobis(ethylenediamine)cobalt(III) Chloride 241\u003c\/p\u003e \u003cp\u003ePart B Synthesis of cis-Dichlorobis(ethylenediamine)cobalt(III) Chloride 242\u003c\/p\u003e \u003cp\u003eExperiment 27 Optical Isomers: Separation of an Optical Isomer of\u003c\/p\u003e \u003cp\u003ecis-Dichlorobis (ethylenediamine)cobalt(III) Chloride 243\u003c\/p\u003e \u003cp\u003eExperiment 28 Ion Exchange Separation of the Oxidation States of Vanadium 246\u003c\/p\u003e \u003cp\u003eExperiment 29 Determination of Δ\u003csub\u003e0\u003c\/sub\u003e in Cr(III) Complexes 248\u003c\/p\u003e \u003cp\u003eExperiment 30 Preparation and Study of a Cobalt(II) Oxygen Adduct Complex 252\u003c\/p\u003e \u003cp\u003ePart A Preparation of \u003ci\u003eN,N'\u003c\/i\u003e -Bis(salicylaldehyde) ethylenediimine, salenH2 254\u003c\/p\u003e \u003cp\u003ePart B Preparation of Co(salen) 254\u003c\/p\u003e \u003cp\u003ePart C Determination of Oxygen Absorption by Co(salen) 256\u003c\/p\u003e \u003cp\u003ePart D Reaction of Oxygen Adduct with Chloroform 257\u003c\/p\u003e \u003cp\u003eExperiment 31 Preparation of Dichloro-1,3-bis[diphenylphosphino)propanenickel(II) 257\u003c\/p\u003e \u003cp\u003eExperiment 32 Preparation of Iron(II) Chloride (Use of FeCl\u003csub\u003e3\u003c\/sub\u003e as a Friedel–Crafts Chlorination Source) 260\u003c\/p\u003e \u003cp\u003eExperiment 33 Reaction of Cr(III) with a Multidentate Ligand: A Kinetics Experiment 263\u003c\/p\u003e \u003cp\u003eExperiment 34 Organometallic Compounds and Catalysis: Synthesis and Use of Wilkinson’s Catalyst 271\u003c\/p\u003e \u003cp\u003ePart A Synthesis of RhCl(PPh\u003csub\u003e3\u003c\/sub\u003e)\u003csub\u003e3\u003c\/sub\u003e, Wilkinson’s Catalyst 276\u003c\/p\u003e \u003cp\u003ePart B Substitution of the Chloro Ligand in Wilkinson’s Catalyst 277\u003c\/p\u003e \u003cp\u003ePart C Reaction of Wilkinson’s Catalyst with Aldehydes 278\u003c\/p\u003e \u003cp\u003ePart D Reaction of Wilkinson’s Catalyst with Ethylene 279\u003c\/p\u003e \u003cp\u003ePart E Absorption of Hydrogen by Wilkinson’s Catalyst 279\u003c\/p\u003e \u003cp\u003ePart F Catalytic Hydrogenation of Olefins in the Presence of Wilkinson’s Catalyst 281\u003c\/p\u003e \u003cp\u003eExperiment 35 Synthesis and Reactions of Cobalt Phenanthroline Complexes 282\u003c\/p\u003e \u003cp\u003ePart A Preparation of \u003ci\u003eTris\u003c\/i\u003e(1, 10-phenanthroline) cobalt(II) Bromide 283\u003c\/p\u003e \u003cp\u003ePart A (Alternate): Preparation of Tris(1, 10-phenanthroline) cobalt(II) Antimonyl-d-tartrate 284\u003c\/p\u003e \u003cp\u003ePart B Preparation of \u003ci\u003eTris\u003c\/i\u003e(1, 10-phenanthroline) cobalt(III) Tetrafluoroborate 285\u003c\/p\u003e \u003cp\u003ePart C Preparation of \u003ci\u003eTris\u003c\/i\u003e(1, 10-phenanthroline-5,6-quinone)cobalt(III) Hexafluorophosphate 286\u003c\/p\u003e \u003cp\u003ePart D Isolation of 1, 10-phenanthroline-5,6-quinone 287\u003c\/p\u003e \u003cp\u003eExperiment 36 Preparation of Tetrakis(triphenylphosphine)platinum(0) 288\u003c\/p\u003e \u003cp\u003eExperiment 37 Platinum(II) Complexes––the Trans Effect 290\u003c\/p\u003e \u003cp\u003ePart A Preparation of cis-Dichloro(dipyridine) platinum(II) 291\u003c\/p\u003e \u003cp\u003ePart B Preparation of trans-Dichloro(dipyridine) platinum(II) 291\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 9 Chemistry of Organometallic and Related Compounds 295\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExperiment 38 Organoplatinum[II) Complexes: Preparation of η\u003csup\u003e4\u003c\/sup\u003e-C\u003csub\u003e8\u003c\/sub\u003eH\u003csub\u003e12\u003c\/sub\u003ePtCl\u003csub\u003e2\u003c\/sub\u003e 296\u003c\/p\u003e \u003cp\u003eExperiment 39 NMR Investigation of Molecular Fluxionality: Synthesis of Allylpalladium Complexes 298\u003c\/p\u003e \u003cp\u003eExperiment 40 Preparation and Use of Ferrocene 302\u003c\/p\u003e \u003cp\u003ePart A Preparation of Cyclopentadiene 304\u003c\/p\u003e \u003cp\u003ePart B Preparation of Ferrocene 305\u003c\/p\u003e \u003cp\u003ePart C Acetylation of Ferrocene 307\u003c\/p\u003e \u003cp\u003ePart D HPLC Analysis of the Acetylation Reaction 309\u003c\/p\u003e \u003cp\u003eExperiment 41 Preparation of Organopalladium Complexes 310\u003c\/p\u003e \u003cp\u003ePart A Preparation of Dichloro-bis-(benzonitrile) palladium(II) 311\u003c\/p\u003e \u003cp\u003ePart B Preparation of Di-µ-chlorodichlorodiethylenedipalladium(II) 312\u003c\/p\u003e \u003cp\u003eExperiment 42 Synthesis of Metal Carbonyls 313\u003c\/p\u003e \u003cp\u003ePart A Preparation of trans-Chlorocarbonylbis­ (triphenylphosphine)rhodium(I) 315\u003c\/p\u003e \u003cp\u003ePart B Preparation of mer-Carbonyltrichlorobis ­(triphenylphosphine)rhodium(III) 316\u003c\/p\u003e \u003cp\u003ePart C Synthesis of the SO\u003csub\u003e2 \u003c\/sub\u003eAdduct of trans­ Chlorocarbonylbis(triphenylphosphine)rhodium(I) 317\u003c\/p\u003e \u003cp\u003eExperiment 43 Sunlight Photochemistry: Preparation of Dicarbonyl(η\u003csup\u003e5\u003c\/sup\u003e-methylcyclopentadienyl)triphenylphosphinemanganese (0) 318\u003c\/p\u003e \u003cp\u003eExperiment 44 Synthesis of Metal Nitrosyl Complexes 320\u003c\/p\u003e \u003cp\u003ePart A Preparation of Trichloronitrosyl-bis(triphenylphosphine)ruthenium(II) 321\u003c\/p\u003e \u003cp\u003ePart B Preparation of Dinitrosylbis(triphenylphosphine)ruthenium(– II) 323\u003c\/p\u003e \u003cp\u003eExperiment 45 \u003csup\u003e13\u003c\/sup\u003eC NMR Analysis of Cyclopentadienylirondicarbonyl Dimer 324\u003c\/p\u003e \u003cp\u003ePart A Preparation of [(η\u003csup\u003e5\u003c\/sup\u003e-C\u003csub\u003e5\u003c\/sub\u003eH\u003csub\u003e5\u003c\/sub\u003e)Fe(CO)\u003csub\u003e2\u003c\/sub\u003e]\u003csub\u003e2 \u003c\/sub\u003e325\u003c\/p\u003e \u003cp\u003ePart B Variable Temperature 13C NMR lnvestigation of [η\u003csup\u003e5\u003c\/sup\u003e-C\u003csub\u003e5\u003c\/sub\u003eH\u003csub\u003e5\u003c\/sub\u003e)Fe(CO)\u003csub\u003e2\u003c\/sub\u003e]\u003csub\u003e2 \u003c\/sub\u003e327\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 10 Bioinorganic Chemistry 329\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExperiment 46 Synthesis of Palladium Nucleosides 330\u003c\/p\u003e \u003cp\u003ePart A Preparation of \u003ci\u003ecis\u003c\/i\u003e-[Dichlorobis(inosine) palladium(II)] 331\u003c\/p\u003e \u003cp\u003ePart B Preparation of \u003ci\u003ecis\u003c\/i\u003e-[Bis(lnosinato) palladium(II)] 332\u003c\/p\u003e \u003cp\u003ePart C Preparation of \u003ci\u003etrans\u003c\/i\u003e-[Bis(inosinato) palladium(II)] 333\u003c\/p\u003e \u003cp\u003eExperiment 47 Metal Complexes of Saccharin 334\u003c\/p\u003e \u003cp\u003ePart A Preparation of Tetraaqua-bis(o-sulfobenzoimido)copper(II) 336\u003c\/p\u003e \u003cp\u003ePart B Preparation of Tetraaqua-bis(o-sulfobenzoimido)cobalt(II) 336\u003c\/p\u003e \u003cp\u003eExperiment 48 Synthesis of \u003ci\u003ecis\u003c\/i\u003e-Diamminedihaloplatinum(II) Compounds 337\u003c\/p\u003e \u003cp\u003ePart A Preparation of \u003ci\u003ecis\u003c\/i\u003e-Diamminediiodoplatinum(II) 338\u003c\/p\u003e \u003cp\u003ePart B Preparation of \u003ci\u003ecis\u003c\/i\u003e-diamminedichloroplatinum(II), Cisplatin 339\u003c\/p\u003e \u003cp\u003eExperiment 49 Preparation of Copper Glycine Complexes 341\u003c\/p\u003e \u003cp\u003ePart A Preparation of \u003ci\u003ecis\u003c\/i\u003e-Bis(glycinato) copper(II) Monohydrate 342\u003c\/p\u003e \u003cp\u003ePart B Preparation of \u003ci\u003etrans\u003c\/i\u003e-Bis(glycinato) copper(II) 342\u003c\/p\u003e \u003cp\u003eAppendix A Safety Data for Common Solvents 345\u003c\/p\u003e \u003cp\u003eAppendix B List of Common Acids and Bases 347\u003c\/p\u003e \u003cp\u003eAppendix C Table of Reagents and Selected Solvents Used in Experiments 349\u003c\/p\u003e \u003cp\u003eAppendix D Table of Instrumental Techniques Used in Experiments 353\u003c\/p\u003e \u003cp\u003eAppendix E Companies and Addresses 355\u003c\/p\u003e \u003cp\u003eIndex 359\u003c\/p\u003e  \u003cp\u003eZvi Szafran is the author of Microscale Inorganic Chemistry: A Comprehensive Laboratory Experience, published by Wiley. \u003c\/p\u003e\u003cp\u003eRonald M. Pike is the author of Microscale Inorganic Chemistry: A Comprehensive Laboratory Experience, published by Wiley.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989621850341,"sku":"NP9780471619963","price":132.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780471619963.jpg?v=1761784847","url":"https:\/\/k12savings.com\/es\/products\/microscale-inorganic-chemistry-isbn-9780471619963","provider":"K12savings","version":"1.0","type":"link"}