{"product_id":"membrane-materials-for-gas-and-separation-isbn-9781119112716","title":"Membrane Materials for Gas and Separation","description":"\u003cp\u003eSi containing polymers have been instrumental in the development of membrane gas separation practices since the early 1970s. Their function is to provide a selective barrier for different molecular species, where selection takes place either on the basis of size or on the basis of physical interactions or both. \u003c\/p\u003e \u003cul\u003e \u003cli\u003eCombines membrane science, organosilicon chemistry, polymer science, materials science, and physical chemistry\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e \u003c\/p\u003e \u003cul\u003e \u003cli\u003eOnly book to consider polymerization chemistry and synthesis of Si-containing polymers (both glassy and rubbery), and their role as membrane materials\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e \u003c\/p\u003e \u003cul\u003e \u003cli\u003eMembrane operations present environmental benefits such as reduced waste, and recovered\/recycled valuable raw materials that are currently lost to fuel or to flares\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eContributors xi \u003c\/p\u003e \u003cp\u003ePreface xv \u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Permeability of Polymers 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYuri Yampolskii\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e1.1 Introduction 1 \u003c\/p\u003e \u003cp\u003e1.2 Detailed mechanism of sorption and transport 3 \u003c\/p\u003e \u003cp\u003e1.2.1 Transition-state model 3 \u003c\/p\u003e \u003cp\u003e1.2.2 Free volume model 4 \u003c\/p\u003e \u003cp\u003e1.2.3 Sorption isotherms 5 \u003c\/p\u003e \u003cp\u003e1.3 Concentration dependence of permeability and diffusion coefficients 6 \u003c\/p\u003e \u003cp\u003e1.4 Effects of properties of gases and polymers on permeation parameters 10 \u003c\/p\u003e \u003cp\u003eAcknowledgement 13 \u003c\/p\u003e \u003cp\u003eReferences 13 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Organosiloxanes (Silicones), Polyorganosiloxane Block Copolymers: Synthesis, Properties, and Gas Permeation Membranes Based on Them 17\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eIgor Raygorodsky, Victor Kopylov, and Alexander Kovyazin\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e2.1 Introduction 17 \u003c\/p\u003e \u003cp\u003e2.2 Synthesis and transformations of organosiloxanes 17 \u003c\/p\u003e \u003cp\u003e2.2.1 Polyorganosiloxanes with aminoalkyl groups at silicon 19 \u003c\/p\u003e \u003cp\u003e2.2.2 Organosilicon alcohols and phenols 21 \u003c\/p\u003e \u003cp\u003e2.3 Synthesis of polyorganosiloxane block copolymers 23 \u003c\/p\u003e \u003cp\u003e2.3.1 Polyester(ether)–polyorganosiloxane block copolymers 24 \u003c\/p\u003e \u003cp\u003e2.3.2 Synthesis of polyurethane–, polyurea–, polyamide–, polyimide– organosiloxane POBCs 25 \u003c\/p\u003e \u003cp\u003e2.4 Properties of polyorganosiloxane block copolymers 29 \u003c\/p\u003e \u003cp\u003e2.4.1 Phase state of polyblock organosiloxane copolymers 29 \u003c\/p\u003e \u003cp\u003e2.5 Morphology of POBCs and its effects on their diffusion properties 30 \u003c\/p\u003e \u003cp\u003e2.5.1 Types of heterogeneous structure 30 \u003c\/p\u003e \u003cp\u003e2.6 Some representatives of POBC as membrane materials and their properties 32 \u003c\/p\u003e \u003cp\u003e2.6.1 Polycarbonate–polysiloxanes 32 \u003c\/p\u003e \u003cp\u003e2.6.2 Polyurethane(urea)–polysiloxanes 39 \u003c\/p\u003e \u003cp\u003e2.6.3 Polyimide(amide)–polysiloxanes 42 \u003c\/p\u003e \u003cp\u003e2.7 Conclusions 45 \u003c\/p\u003e \u003cp\u003eReferences 46 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Polysilalkylenes 53\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eNikolay V. Ushakov, Stepan Guselnikov, and Eugene Finkelshtein\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003eAcknowledgement 65 \u003c\/p\u003e \u003cp\u003eReferences 65 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Polyvinylorganosilanes: The Materials for Membrane Gas Separation 69\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eNikolay V. Ushakov\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e4.1 Introduction: Historical background 69 \u003c\/p\u003e \u003cp\u003e4.2 Syntheses and polymerization of vinyltriorganosilanes 71 \u003c\/p\u003e \u003cp\u003e4.2.1 Syntheses of vinyltriorganosilanes 71 \u003c\/p\u003e \u003cp\u003e4.2.2 Vinyltriorganosilane (VTOS) polymerization 73 \u003c\/p\u003e \u003cp\u003e4.2.2.1 VTOS homopolymerization 73 \u003c\/p\u003e \u003cp\u003e4.2.2.2 Statistical copolymerization of VTOS with other monomers 83 \u003c\/p\u003e \u003cp\u003e4.2.2.3 Block-copolymerization of VTOS with monomers of other types 85 \u003c\/p\u003e \u003cp\u003e4.3 Physico-chemical and membrane properties of polymeric PVTOS materials 88 \u003c\/p\u003e \u003cp\u003e4.4 Concluding remarks 94 \u003c\/p\u003e \u003cp\u003eAcknowledgement 95 \u003c\/p\u003e \u003cp\u003eReferences 95 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Substituted Polyacetylenes 107\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eToshikazu Sakaguchi, Yanming Hu, and Toshio Masuda\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e5.1 Introduction 107 \u003c\/p\u003e \u003cp\u003e5.2 Poly(1-trimethylsilyl-1-propyne) (PTMSP) and related polymers 110 \u003c\/p\u003e \u003cp\u003e5.2.1 Synthesis and general properties 110 \u003c\/p\u003e \u003cp\u003e5.2.2 Permeation of gases and liquids 112  \u003c\/p\u003e \u003cp\u003e5.2.3 Aging effect and cross-linking 114 \u003c\/p\u003e \u003cp\u003e5.2.4 Free volume 115 \u003c\/p\u003e \u003cp\u003e5.2.5 Nanocomposites and hybrids 116 \u003c\/p\u003e \u003cp\u003e5.3 Poly[1-phenyl-2-(p-trimethylsilylphenyl)acetylene] and related polymers 117 \u003c\/p\u003e \u003cp\u003e5.3.1 Polymer synthesis 118 \u003c\/p\u003e \u003cp\u003e5.3.2 Gas separation 121 \u003c\/p\u003e \u003cp\u003e5.4 Desilylated polyacetylenes 124 \u003c\/p\u003e \u003cp\u003e5.4.1 Desilylation of poly[1(p-trimethylsilylphenyl)-2-phenylacetylene] 124 \u003c\/p\u003e \u003cp\u003e5.4.2 PDPAs from precursor polymers with various silyl groups 125 \u003c\/p\u003e \u003cp\u003e5.4.3 Soluble poly(diphenylacetylene)s obtained by desilylation 127 \u003c\/p\u003e \u003cp\u003e5.4.4 Poly(diarylacetylene)s 128 \u003c\/p\u003e \u003cp\u003e5.5 Polar-group-containing polyacetylenes 130 \u003c\/p\u003e \u003cp\u003e5.5.1 Hydroxy group 130 \u003c\/p\u003e \u003cp\u003e5.5.2 Sulfonated and nitrated poly(diphenylacetylene)s 132 \u003c\/p\u003e \u003cp\u003e5.5.3 Other polar groups 134 \u003c\/p\u003e \u003cp\u003e5.6 Concluding remarks 135 \u003c\/p\u003e \u003cp\u003eReferences 136 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Polynorbornenes 143\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eEugene Finkelshtein, Maria Gringolts, Maksim Bermeshev, Pavel Chapala,\u003c\/i\u003e\u003ci\u003eand Yulia Rogan\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e6.1 Introduction 143 \u003c\/p\u003e \u003cp\u003e6.2 Monomer synthesis 144 \u003c\/p\u003e \u003cp\u003e6.2.1 Synthesis of silicon-substituted norbornenes and norbornadienes 145 \u003c\/p\u003e \u003cp\u003e6.2.1.1 [4π +2π]-cycloaddition of Si-substituted ethylenes and acetylenes to cyclopentadiene 145 \u003c\/p\u003e \u003cp\u003e6.2.1.2 Synthesis of silyl-substituted norbornenes and norbornadienes with alkyl and functional substituents via Si–Cl bond transformation 150 \u003c\/p\u003e \u003cp\u003e6.2.1.3 Other approaches to silylnorbornene and norbornadiene preparation 151 \u003c\/p\u003e \u003cp\u003e6.2.2 Synthesis of Si-containing exo-tricyclo[4.2.1.0 2,5 ]non-7-enes 152 \u003c\/p\u003e \u003cp\u003e6.2.2.1 The[2σ +2σ +2π]-cycloaddition reaction of quadricyclane with Si-containing alkenes or relative compounds as a simple way to highly active monomers 153 \u003c\/p\u003e \u003cp\u003e6.2.2.2 Cycloaddition of Q with vinylsilanes or relative compounds 154 \u003c\/p\u003e \u003cp\u003e6.2.2.3 Cycloaddition of Q with Si-containing disubstituted alkenes\/acetylenes 157 \u003c\/p\u003e \u003cp\u003e6.2.2.4 Cycloaddition of Q with Si-containing 1,2,3-trisubstituted alkenes 159 \u003c\/p\u003e \u003cp\u003e6.3 Metathesis polynorbornenes 163 \u003c\/p\u003e \u003cp\u003e6.4 Addition polymerization 183 \u003c\/p\u003e \u003cp\u003e6.4.1 Addition polynorbornenes and polynorbornenes with alkyl side groups 184 \u003c\/p\u003e \u003cp\u003e6.4.2 Silicon and germanium-substituted polynorbornenes 187 \u003c\/p\u003e \u003cp\u003e6.4.3 Composites with addition silicon-containing polytricyclononenes 205 \u003c\/p\u003e \u003cp\u003e6.5 Conclusions 209 \u003c\/p\u003e \u003cp\u003eAcknowledgement 210 \u003c\/p\u003e \u003cp\u003eReferences 210 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Polycondensation Materials Containing Bulky Side Groups: Synthesis and Transport Properties 223\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSusanta BanerjeeandDebaditya Bera\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e7.1 Introduction 223 \u003c\/p\u003e \u003cp\u003e7.2 Synthesis of the polymers 224 \u003c\/p\u003e \u003cp\u003e7.2.1 Polyimides 224 \u003c\/p\u003e \u003cp\u003e7.2.1.1 One-step polymerization 224 \u003c\/p\u003e \u003cp\u003e7.2.1.2 Two-step polymerization 225 \u003c\/p\u003e \u003cp\u003e7.2.2 Poly(arylene ether)s (PAEs) 227 \u003c\/p\u003e \u003cp\u003e7.2.3 Aromatic polyamides (PAs) 228 \u003c\/p\u003e \u003cp\u003e7.2.3.1 Low temperature polymerization 228 \u003c\/p\u003e \u003cp\u003e7.2.3.2 High temperature polymerization 229 \u003c\/p\u003e \u003cp\u003e7.3 Effect of different bulky groups on polymer gas transport properties 229 \u003c\/p\u003e \u003cp\u003e7.3.1 Gas transport properties of the polyimides containing different bulky groups 229 \u003c\/p\u003e \u003cp\u003e7.3.2 Gas transport properties of polyamides containing different bulky groups 241 \u003c\/p\u003e \u003cp\u003e7.3.3 Gas transport properties of poly(arylene ether)s containing different bulky groups 248 \u003c\/p\u003e \u003cp\u003e7.3.4 Concluding remarks 263 \u003c\/p\u003e \u003cp\u003eReferences 265 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Gas and Vapor Transport Properties of Si-Containing and Related Polymers 271\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYuri Yampolskii\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e8.1 Introduction 271 \u003c\/p\u003e \u003cp\u003e8.2 Rubbery Si-containing polymers 272 \u003c\/p\u003e \u003cp\u003e8.2.1 Polysiloxanes 272 \u003c\/p\u003e \u003cp\u003e8.2.2 Siloxane-containing copolymers (block copolymers, random copolymers and graft copolymers) 274 \u003c\/p\u003e \u003cp\u003e8.2.3 Polysilmethylenes 277 \u003c\/p\u003e \u003cp\u003e8.3 Glassy Si-containing polymers 278 \u003c\/p\u003e \u003cp\u003e8.3.1 Polymers with Si–O–Si bonds in side chains 278 \u003c\/p\u003e \u003cp\u003e8.3.2 Poly(vinyltrimethyl silane) and related vinylic polymers 282 \u003c\/p\u003e \u003cp\u003e8.3.3 Metathesis norbornene polymers 285 \u003c\/p\u003e \u003cp\u003e8.3.4 Additive norbornene polymers 286 \u003c\/p\u003e \u003cp\u003e8.3.5 Polyacetylenes 290 \u003c\/p\u003e \u003cp\u003e8.3.6 Other glassy Si-containing polymers 293 \u003c\/p\u003e \u003cp\u003e8.4 Free volume in Si-containing polymers 294 \u003c\/p\u003e \u003cp\u003e8.5 Concluding remarks 296 \u003c\/p\u003e \u003cp\u003eAcknowledgement 298 \u003c\/p\u003e \u003cp\u003eReferences 298 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Modeling of Si-Containing Polymers 307\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJoel R. Fried, Timothy Dubbs, and Morteza Azizi\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e9.1 Introduction 307 \u003c\/p\u003e \u003cp\u003e9.2 Main-chain silicon-containing polymers 309 \u003c\/p\u003e \u003cp\u003e9.2.1 Polysiloxanes 309 \u003c\/p\u003e \u003cp\u003e9.2.2 Polysilanes and silalkylene polymers 314 \u003c\/p\u003e \u003cp\u003e9.3 Side-chain silicon-containing polymers 316 \u003c\/p\u003e \u003cp\u003e9.3.1 Poly(vinyltrimethylsilane) 316 \u003c\/p\u003e \u003cp\u003e9.3.2 Poly[1-(trimethylsilyl)-1-propyne] 317 \u003c\/p\u003e \u003cp\u003e9.3.2.1 Conformational studies 318 \u003c\/p\u003e \u003cp\u003e9.3.2.2 Simulation of gas transport 319 \u003c\/p\u003e \u003cp\u003e9.4 Conclusions 324 \u003c\/p\u003e \u003cp\u003eAppendices 325 \u003c\/p\u003e \u003cp\u003e9.a Molecular flexibility 325 \u003c\/p\u003e \u003cp\u003e9.b Simulation of diffusivity 325 \u003c\/p\u003e \u003cp\u003e9.b.1 Einstein relationship 325 \u003c\/p\u003e \u003cp\u003e9.b.2 VACF method 325 \u003c\/p\u003e \u003cp\u003e9.c Simulation of solubility: Widom method 325 \u003c\/p\u003e \u003cp\u003e9.d Molecular mechanics force fields 326 \u003c\/p\u003e \u003cp\u003e9.d.1 Dreiding 326 \u003c\/p\u003e \u003cp\u003e9.d.2 Polymer-consistent force field (pcff) 326 \u003c\/p\u003e \u003cp\u003e9.d.3 Gromos 326 \u003c\/p\u003e \u003cp\u003e9.d.4 Compass 326 \u003c\/p\u003e \u003cp\u003eReferences 327 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Pervaporation and Evapomeation with Si-Containing Polymers 335\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eTadashi Uragami\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003e10.1 Introduction 335 \u003c\/p\u003e \u003cp\u003e10.2 Structural design of Si-containing polymer membranes 335 \u003c\/p\u003e \u003cp\u003e10.2.1 Chemical design of Si-containing polymer membrane materials 336 \u003c\/p\u003e \u003cp\u003e10.2.2 Physical construction of Si-containing polymer membranes 336 \u003c\/p\u003e \u003cp\u003e10.3 Pervaporation 337 \u003c\/p\u003e \u003cp\u003e10.3.1 Principle of pervaporation 337 \u003c\/p\u003e \u003cp\u003e10.3.2 Fundamentals of pervaporation 338 \u003c\/p\u003e \u003cp\u003e10.3.3 Solution–diffusion model in pervaporation 339 \u003c\/p\u003e \u003cp\u003e10.4 Evapomeation 340 \u003c\/p\u003e \u003cp\u003e10.4.1 Principle of evapomeation 340 \u003c\/p\u003e \u003cp\u003e10.4.2 Principle of temperature-difference controlled evapomeation 341 \u003c\/p\u003e \u003cp\u003e10.5 Technology of pervaporation with Si-containing polymer membranes 342 \u003c\/p\u003e \u003cp\u003e10.5.1 Alcohol permselective membranes 342 \u003c\/p\u003e \u003cp\u003e10.5.2 Hydrocarbon permselective membranes 353 \u003c\/p\u003e \u003cp\u003e10.5.2.1 Aromatic hydrocarbon removal 353 \u003c\/p\u003e \u003cp\u003e10.5.2.2 Chlorinated hydrocarbon removal 358 \u003c\/p\u003e \u003cp\u003e10.5.3 Organic permselective membranes 360 \u003c\/p\u003e \u003cp\u003e10.5.4 Membranes for separation of organic–organic mixtures 361 \u003c\/p\u003e \u003cp\u003e10.5.5 Membranes for optical resolution 362 \u003c\/p\u003e \u003cp\u003e10.6 Technology of evapomeation with Si-containing polymer membranes 363 \u003c\/p\u003e \u003cp\u003e10.6.1 Permeation and separation by evapomeation 363 \u003c\/p\u003e \u003cp\u003e10.6.2 Concentration of ethanol by temperature-difference controlled evapomeation 364 \u003c\/p\u003e \u003cp\u003e10.7 Conclusions 365 \u003c\/p\u003e \u003cp\u003eReferences 365 \u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Si-Containing Polymers in Membrane Gas Separation 373\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAdele Brunetti, Leonardo Melone, Enrico Drioli, and Giuseppe Barbieri\u003c\/i\u003e \u003c\/p\u003e \u003cp\u003eExecutive summary 373 \u003c\/p\u003e \u003cp\u003e11.1 Introduction 373 \u003c\/p\u003e \u003cp\u003e11.2 Si-containing polymer membranes used in gas separation 375 \u003c\/p\u003e \u003cp\u003e11.2.1 Silicon rubber membrane materials 375 \u003c\/p\u003e \u003cp\u003e11.2.2 Polyacetylene membrane materials 376 \u003c\/p\u003e \u003cp\u003e11.2.3 Polynorbornene membrane materials 378 \u003c\/p\u003e \u003cp\u003e11.2.4 Other Si-containing membrane materials 378 \u003c\/p\u003e \u003cp\u003e11.3 Separations 379 \u003c\/p\u003e \u003cp\u003e11.4 Membrane modules 381 \u003c\/p\u003e \u003cp\u003e11.5 Competing technologies for separation of gases 384 \u003c\/p\u003e \u003cp\u003e11.6 Applications 385 \u003c\/p\u003e \u003cp\u003e11.6.1 Air separation 385 \u003c\/p\u003e \u003cp\u003e11.6.2 Hydrogen separation 386 \u003c\/p\u003e \u003cp\u003e11.6.3 Hydrocarbon separation 390 \u003c\/p\u003e \u003cp\u003e11.6.4 VOC separation 392 \u003c\/p\u003e \u003cp\u003eReferences 393 \u003c\/p\u003e \u003cp\u003eIndex 399\u003c\/p\u003e \u003cp\u003eEditors\u003cbr\u003e Yuri Yampolskii\u003cbr\u003e Eugene Finkelshtein\u003cbr\u003e A.V. Topchiev Institute of Petrochemical Synthesis, RAS, Moscow, Russia  \u003c\/p\u003e\u003cp\u003eThe key to the successful development of separation membrane materials is finding and elaborating convenient methods for the synthesis of appropriate monomers and the determination of their optimal polymerization conditions, resulting in polymers with good gas transport and film-forming properties. This book discusses the chemistry and synthesis of silicon-containing polymers, and gas permeation and separation properties of the prepared polymers. Topics include\u003c\/p\u003e \u003cul\u003e\n\u003cli\u003emonomer synthesis\u003c\/li\u003e \u003cli\u003epolymerization processes\u003c\/li\u003e \u003cli\u003ecatalyst selection\u003c\/li\u003e \u003cli\u003ephysicochemical properties\u003c\/li\u003e \u003cli\u003eparameters of permeability\u003c\/li\u003e \u003cli\u003ediffusivity\u003c\/li\u003e \u003cli\u003esorption thermodynamics\u003c\/li\u003e \u003cli\u003ecomputer modeling\u003c\/li\u003e \u003cli\u003efree volume\u003c\/li\u003e \u003cli\u003epractical applications\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003eAimed at researchers and advanced students working in membrane science, organosilicon chemistry, polymer science and physical chemistry as well as those in related areas such as materials science, this volume combines membrane science, organosilicon chemistry, polymer science, materials science and physical chemistry.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989606121701,"sku":"NP9781119112716","price":207.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119112716.jpg?v=1761784783","url":"https:\/\/k12savings.com\/es\/products\/membrane-materials-for-gas-and-separation-isbn-9781119112716","provider":"K12savings","version":"1.0","type":"link"}