{"product_id":"materials-thermodynamics-isbn-9780470484142","title":"Materials Thermodynamics","description":"\u003cb\u003eA timely, applications-driven text in thermodynamics\u003c\/b\u003e  \u003cp\u003e\u003ci\u003eMaterials Thermodynamics\u003c\/i\u003e provides both students and professionals with the in-depth explanation they need to prepare for the real-world application of thermodynamic tools. Based upon an actual graduate course taught by the authors, this class-tested text covers the subject with a broader, more industry-oriented lens than can be found in any other resource available. This modern approach:\u003c\/p\u003e \u003cul\u003e \u003cli\u003e \u003cp\u003eReflects changes rapidly occurring in society at large—from the impact of computers on the teaching of thermodynamics in materials science and engineering university programs to the use of approximations of higher order than the usual Bragg-Williams in solution-phase modeling\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eMakes students aware of the practical problems in using thermodynamics\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eEmphasizes that the calculation of the position of phase and chemical equilibrium in complex systems, even when properly defined, is not easy\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eRelegates concepts like equilibrium constants, activity coefficients, free energy functions, and Gibbs-Duhem integrations to a relatively minor role\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eIncludes problems and exercises, as well as a solutions manual\u003c\/p\u003e \u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThis authoritative text is designed for students and professionals in materials science and engineering, particularly those in physical metallurgy, metallic materials, alloy design and processing, corrosion, oxidation, coatings, and high-temperature alloys.\u003c\/p\u003e \u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003eQuantities, Units, and Nomenclature xix\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Review of Fundamentals 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Systems, Surroundings, and Work 2\u003c\/p\u003e \u003cp\u003e1.2 Thermodynamic Properties 4\u003c\/p\u003e \u003cp\u003e1.3 The Laws of Thermodynamics 5\u003c\/p\u003e \u003cp\u003e1.4 The Fundamental Equation 8\u003c\/p\u003e \u003cp\u003e1.5 Other Thermodynamic Functions 9\u003c\/p\u003e \u003cp\u003e1.5.1 Maxwell’s Equations 11\u003c\/p\u003e \u003cp\u003e1.5.2 Defining Other Forms of Work 11\u003c\/p\u003e \u003cp\u003e1.6 Equilibrium State 14\u003c\/p\u003e \u003cp\u003eExercises 15\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Thermodynamics of Unary Systems 19\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Standard State Properties 19\u003c\/p\u003e \u003cp\u003e2.2 The Effect of Pressure 27\u003c\/p\u003e \u003cp\u003e2.2.1 Gases 28\u003c\/p\u003e \u003cp\u003e2.2.2 Condensed Phases 29\u003c\/p\u003e \u003cp\u003e2.3 The Gibbs–Duhem Equation 30\u003c\/p\u003e \u003cp\u003e2.4 Experimental Methods 31\u003c\/p\u003e \u003cp\u003eExercises 32\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Calculation of Thermodynamic Properties of Unary Systems 35\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Constant-Pressure\/Constant-Volume Conversions 36\u003c\/p\u003e \u003cp\u003e3.2 Excitations in Gases 37\u003c\/p\u003e \u003cp\u003e3.2.1 Perfect Monatomic Gas 37\u003c\/p\u003e \u003cp\u003e3.2.2 Molecular Gases 39\u003c\/p\u003e \u003cp\u003e3.3 Excitations in Pure Solids 39\u003c\/p\u003e \u003cp\u003e3.4 The Thermodynamic Properties of a Pure Solid 43\u003c\/p\u003e \u003cp\u003e3.4.1 Inadequacies of the Model 46\u003c\/p\u003e \u003cp\u003eExercises 46\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Phase Equilibria in Unary Systems 49\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 The Thermodynamic Condition for Phase Equilibrium 52\u003c\/p\u003e \u003cp\u003e4.2 Phase Changes 54\u003c\/p\u003e \u003cp\u003e4.2.1 The Slopes of Boundaries in Phase Diagrams 54\u003c\/p\u003e \u003cp\u003e4.2.2 Gibbs Energy Changes for Phase Transformations 57\u003c\/p\u003e \u003cp\u003e4.3 Stability and Critical Phenomena 59\u003c\/p\u003e \u003cp\u003e4.4 Gibbs’s Phase Rule 61\u003c\/p\u003e \u003cp\u003eExercises 63\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Thermodynamics of Binary Solutions I: Basic Theory and Application to Gas Mixtures 67\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Expressing Composition 67\u003c\/p\u003e \u003cp\u003e5.2 Total (Integral) and Partial Molar Quantities 68\u003c\/p\u003e \u003cp\u003e5.2.1 Relations between Partial and Integral Quantities 70\u003c\/p\u003e \u003cp\u003e5.2.2 Relation between Partial Quantities: the Gibbs–Duhem Equation 72\u003c\/p\u003e \u003cp\u003e5.3 Application to Gas Mixtures 73\u003c\/p\u003e \u003cp\u003e5.3.1 Partial Pressures 73\u003c\/p\u003e \u003cp\u003e5.3.2 Chemical Potentials in Perfect Gas Mixtures 74\u003c\/p\u003e \u003cp\u003e5.3.3 Real Gas Mixtures: Component Fugacities and Activities 75\u003c\/p\u003e \u003cp\u003eExercises 75\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Thermodynamics of Binary Solutions II: Theory and Experimental Methods 79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Ideal Solutions 79\u003c\/p\u003e \u003cp\u003e6.1.1 Real Solutions 82\u003c\/p\u003e \u003cp\u003e6.1.2 Dilute Solution Reference States 83\u003c\/p\u003e \u003cp\u003e6.2 Experimental Methods 85\u003c\/p\u003e \u003cp\u003e6.2.1 Chemical Potential Measurements 86\u003c\/p\u003e \u003cp\u003eExercises 89\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Thermodynamics of Binary Solutions III: Experimental Results and Their Analytical Representation 93\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Some Experimental Results 93\u003c\/p\u003e \u003cp\u003e7.1.1 Liquid Alloys 93\u003c\/p\u003e \u003cp\u003e7.1.2 Solid Alloys 95\u003c\/p\u003e \u003cp\u003e7.2 Analytical Representation of Results for Liquid or Solid Solutions 97\u003c\/p\u003e \u003cp\u003eExercises 102\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Two-Phase Equilibrium I: Theory 103\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 103\u003c\/p\u003e \u003cp\u003e8.2 Criterion for Phase Equilibrium Between Two Specified Phases 104\u003c\/p\u003e \u003cp\u003e8.2.1 Equilibrium between Two Solution Phases 104\u003c\/p\u003e \u003cp\u003e8.2.2 Equilibrium between a Solution Phase and a Stoichiometric Compound Phase 107\u003c\/p\u003e \u003cp\u003e8.3 Gibbs’s Phase Rule 108\u003c\/p\u003e \u003cp\u003eExercises 110\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Two-Phase Equilibrium II: Example Calculations 113\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eExercises 121\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Binary Phase Diagrams: Temperature–Composition Diagrams 125\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 True Phase Diagrams 126\u003c\/p\u003e \u003cp\u003e10.2 T –x\u003csub\u003ei\u003c\/sub\u003e Phase Diagrams for Strictly Regular Solutions 128\u003c\/p\u003e \u003cp\u003e10.2.1 Some General Observations 131\u003c\/p\u003e \u003cp\u003e10.2.2 More on Miscibility Gaps 133\u003c\/p\u003e \u003cp\u003e10.2.3 The Chemical Spinodal 134\u003c\/p\u003e \u003cp\u003e10.3 Polymorphism 135\u003c\/p\u003e \u003cp\u003eExercises 136\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Binary Phase Diagrams: Temperature–Chemical Potential Diagrams 139\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Some General Points 140\u003c\/p\u003e \u003cp\u003eExercises 146\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Phase Diagram Topology 149\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Gibbs’s Phase Rule 151\u003c\/p\u003e \u003cp\u003e12.2 Combinatorial Analysis 151\u003c\/p\u003e \u003cp\u003e12.3 Schreinemaker’s Rules 153\u003c\/p\u003e \u003cp\u003e12.4 The Gibbs–Konovalov Equations 154\u003c\/p\u003e \u003cp\u003e12.4.1 Slopes of T –μ\u003csub\u003ei\u003c\/sub\u003e Phase Boundaries 155\u003c\/p\u003e \u003cp\u003e12.4.2 Slopes of T –x\u003csub\u003ei\u003c\/sub\u003e Phase Boundaries 157\u003c\/p\u003e \u003cp\u003e12.4.3 Some Applications of Gibbs–Konovalov Equations 159\u003c\/p\u003e \u003cp\u003eExercises 162\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Solution Phase Models I: Configurational Entropies 165\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Substitutional Solutions 168\u003c\/p\u003e \u003cp\u003e13.2 Intermediate Phases 169\u003c\/p\u003e \u003cp\u003e13.3 Interstitial Solutions 172\u003c\/p\u003e \u003cp\u003eExercises 174\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Solution Phase Models II: Configurational Energy 177\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Pair Interaction Model 178\u003c\/p\u003e \u003cp\u003e14.1.1 Ground-State Structures 179\u003c\/p\u003e \u003cp\u003e14.1.2 Nearest Neighbor Model 180\u003c\/p\u003e \u003cp\u003e14.2 Cluster Model 183\u003c\/p\u003e \u003cp\u003eExercises 188\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Solution Models III: The Configurational Free Energy 189\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Helmholtz Energy Minimization 190\u003c\/p\u003e \u003cp\u003e15.2 Critical Temperature for Order\/Disorder 193\u003c\/p\u003e \u003cp\u003eExercises 196\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Solution Models IV: Total Gibbs Energy 197\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Atomic Size Mismatch Contributions 199\u003c\/p\u003e \u003cp\u003e16.2 Contributions from Thermal Excitations 202\u003c\/p\u003e \u003cp\u003e16.2.1 Coupling between Configurational and Thermal Excitations 203\u003c\/p\u003e \u003cp\u003e16.3 The Total Gibbs Energy in Empirical Model Calculations 204\u003c\/p\u003e \u003cp\u003eExercises 205\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Chemical Equilibria I: Single Chemical Reaction Equations 207\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 207\u003c\/p\u003e \u003cp\u003e17.2 The Empirical Equilibrium Constant 207\u003c\/p\u003e \u003cp\u003e17.3 The Standard Equilibrium Constant 208\u003c\/p\u003e \u003cp\u003e17.3.1 Relation to Δ\u003csub\u003er\u003c\/sub\u003e G◦ 208\u003c\/p\u003e \u003cp\u003e17.3.2 Measurement of Δ\u003csub\u003er\u003c\/sub\u003e G◦ 211\u003c\/p\u003e \u003cp\u003e17.4 Calculating the Equilibrium Position 213\u003c\/p\u003e \u003cp\u003e17.5 Application of the Phase Rule 217\u003c\/p\u003e \u003cp\u003eExercises 218\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Chemical Equilibria II: Complex Gas Equilibria 221\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18.1 The Importance of System Definition 221\u003c\/p\u003e \u003cp\u003e18.2 Calculation of Chemical Equilibrium 224\u003c\/p\u003e \u003cp\u003e18.2.1 Using the Extent of Reaction 225\u003c\/p\u003e \u003cp\u003e18.2.2 Using Lagrangian Multipliers 227\u003c\/p\u003e \u003cp\u003e18.3 Evaluation of Elemental Chemical Potentials in Complex Gas Mixtures 229\u003c\/p\u003e \u003cp\u003e18.4 Application of the Phase Rule 231\u003c\/p\u003e \u003cp\u003eExercises 232\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Chemical Equilibria Between Gaseous and Condensed Phases I 233\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e19.1 Graphical Presentation of Standard Thermochemical Data 233\u003c\/p\u003e \u003cp\u003e19.2 Ellingham Diagrams 234\u003c\/p\u003e \u003cp\u003e19.2.1 Chemical Potentials 238\u003c\/p\u003e \u003cp\u003eExercises 240\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Chemical Equilibria Between Gaseous and Condensed Phases II 243\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e20.1 Subsidiary Scales on Ellingham Diagrams 244\u003c\/p\u003e \u003cp\u003e20.2 System Definition 247\u003c\/p\u003e \u003cp\u003eExercises 252\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 Thermodynamics of Ternary Systems 255\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e21.1 Analytical Representation of Thermodynamic Properties 256\u003c\/p\u003e \u003cp\u003e21.1.1 Substitutional Solution Phases 256\u003c\/p\u003e \u003cp\u003e21.1.2 Sublattice Phases 259\u003c\/p\u003e \u003cp\u003e21.2 Phase Equilibria 260\u003c\/p\u003e \u003cp\u003eExercises 264\u003c\/p\u003e \u003cp\u003e\u003cb\u003e22 Generalized Phase Diagrams for Ternary Systems 267\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e22.1 System Definition 276\u003c\/p\u003e \u003cp\u003eExercises 278\u003c\/p\u003e \u003cp\u003eAppendix A Some Linearized Standard Gibbs Energies of Formation 279\u003c\/p\u003e \u003cp\u003eAppendix B Some Useful Calculus 281\u003c\/p\u003e \u003cp\u003eIndex 289 \u003c\/p\u003e  \u003cb\u003eY. Austin Chang\u003c\/b\u003e is Wisconsin Distinguished Professor Emeritus in the Department of Materials Science and Engineering at the University of Wisconsin–Madison. He is a member of the National Academy of Engineering, Foreign Member of the Chinese Academy of Sciences, and the recipient of many honors and awards, including the J. Willard Gibbs Award, the Gold Medal, and A. E. White Distinguished Teacher Award of ASM International, and the W. Hume-Rothery Award, John Bardeen Award, and the Educator Award, all awarded by The Minerals, Metals and Materials Society (TMS).  \u003cp\u003e\u003cb\u003eW. Alan Oates\u003c\/b\u003e is a recipient of several awards, including the W. Hume-Rothery Award of TMS.¿Since 1992, Oates has held the position of Honorary Professor at the Science Research Institute, University of Salford, England.\u003c\/p\u003e  \u003cb\u003eA timely, applications-driven text in thermodynamics\u003c\/b\u003e  \u003cp\u003e\u003ci\u003eMaterials Thermodynamics\u003c\/i\u003e provides both students and professionals with the in-depth explanation they need to prepare for the real-world application of thermodynamic tools. Based upon an actual graduate course taught by the authors, this class-tested text covers the subject with a broader, more industry-oriented lens than can be found in any other resource available. This modern approach:\u003c\/p\u003e \u003cul\u003e \u003cli\u003e \u003cp\u003eReflects changes rapidly occurring in society at large—from the impact of computers on the teaching of thermodynamics in materials science and engineering university programs to the use of approximations of higher order than the usual Bragg-Williams in solution-phase modeling\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eMakes students aware of the practical problems in using thermodynamics\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eEmphasizes that the calculation of the position of phase and chemical equilibrium in complex systems, even when properly defined, is not easy\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eRelegates concepts like equilibrium constants, activity coefficients, free energy functions, and Gibbs-Duhem integrations to a relatively minor role\u003c\/p\u003e \u003c\/li\u003e \u003cli\u003e \u003cp\u003eIncludes problems and exercises, as well as a solutions manual\u003c\/p\u003e \u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eThis authoritative text is designed for students and professionals in materials science and engineering, particularly those in physical metallurgy, metallic materials, alloy design and processing, corrosion, oxidation, coatings, and high-temperature alloys.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989585150181,"sku":"NP9780470484142","price":132.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780470484142.jpg?v=1761784699","url":"https:\/\/k12savings.com\/es\/products\/materials-thermodynamics-isbn-9780470484142","provider":"K12savings","version":"1.0","type":"link"}