{"product_id":"introduction-to-chemical-engineering-kinetics-and-reactor-design-isbn-9781118368251","title":"Introduction to Chemical Engineering Kinetics and Reactor Design","description":"\u003cp\u003e\u003cb\u003eThe \u003ci\u003eSecond Edition\u003c\/i\u003e features new problems that engage readers in contemporary reactor design\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eHighly praised by instructors, students, and chemical engineers, \u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e has been extensively revised and updated in this \u003ci\u003eSecond Edition\u003c\/i\u003e. The text continues to offer a solid background in chemical reaction kinetics as well as in material and energy balances, preparing readers with the foundation necessary for success in the design of chemical reactors. Moreover, it reflects not only the basic engineering science, but also the mathematical tools used by today’s engineers to solve problems associated with the design of chemical reactors.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e enables readers to progressively build their knowledge and skills by applying the laws of conservation of mass and energy to increasingly more difficult challenges in reactor design. The first one-third of the text emphasizes general principles of chemical reaction kinetics, setting the stage for the subsequent treatment of reactors intended to carry out homogeneous reactions, heterogeneous catalytic reactions, and biochemical transformations. Topics include:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eThermodynamics of chemical reactions\u003c\/li\u003e \u003cli\u003eDetermination of reaction rate expressions\u003c\/li\u003e \u003cli\u003eElements of heterogeneous catalysis\u003c\/li\u003e \u003cli\u003eBasic concepts in reactor design and ideal reactor models\u003c\/li\u003e \u003cli\u003eTemperature and energy effects in chemical reactors\u003c\/li\u003e \u003cli\u003eBasic and applied aspects of biochemical transformations and bioreactors\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eAbout 70% of the problems in this \u003ci\u003eSecond Edition\u003c\/i\u003e are new. These problems, frequently based on articles culled from the research literature, help readers develop a solid understanding of the material. Many of these new problems also offer readers opportunities to use current software applications such as Mathcad and MATLAB\u003csup\u003e®\u003c\/sup\u003e.\u003c\/p\u003e \u003cp\u003eBy enabling readers to progressively build and apply their knowledge, the \u003ci\u003eSecond Edition\u003c\/i\u003e of \u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e remains a premier text for students in chemical engineering and a valuable resource for practicing engineers.\u003c\/p\u003e \u003cp\u003ePreface ix\u003c\/p\u003e \u003cp\u003ePreface to the First Edition xi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1. Stoichiometric Coefficients and Reaction Progress Variables 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.0 Introduction 1\u003c\/p\u003e \u003cp\u003e1.1 Basic Stoichiometric Concepts 2\u003c\/p\u003e \u003cp\u003eLiterature Citation 3\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2. Thermodynamics of Chemical Reactions 4\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.0 Introduction 4\u003c\/p\u003e \u003cp\u003e2.1 Chemical Potentials and Standard States 4\u003c\/p\u003e \u003cp\u003e2.2 Energy Effects Associated with Chemical Reactions 5\u003c\/p\u003e \u003cp\u003e2.3 Sources of Thermochemical Data 7\u003c\/p\u003e \u003cp\u003e2.4 The Equilibrium Constant and its Relation to Δ\u003ci\u003eG\u003c\/i\u003e\u003csup\u003e0\u003c\/sup\u003e 7\u003c\/p\u003e \u003cp\u003e2.5 Effects of Temperature and Pressure Changes on the Equilibrium Constant 8\u003c\/p\u003e \u003cp\u003e2.6 Determination of Equilibrium Compositions 9\u003c\/p\u003e \u003cp\u003e2.7 Effects of Reaction Conditions on Equilibrium Yields 11\u003c\/p\u003e \u003cp\u003e2.8 Heterogeneous Reactions 12\u003c\/p\u003e \u003cp\u003e2.9 Equilibrium Treatment of Simultaneous Reactions 12\u003c\/p\u003e \u003cp\u003e2.10 Supplementary Reading References 15\u003c\/p\u003e \u003cp\u003eLiterature Citations 15\u003c\/p\u003e \u003cp\u003eProblems 15\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3. Basic Concepts in Chemical Kinetics: Determination of the Reaction Rate Expression 22\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.0 Introduction 22\u003c\/p\u003e \u003cp\u003e3.1 Mathematical Characterization of Simple Reaction Systems 25\u003c\/p\u003e \u003cp\u003e3.2 Experimental Aspects of Kinetic Studies 29\u003c\/p\u003e \u003cp\u003e3.3 Techniques for the Interpretation of Kinetic Data 34\u003c\/p\u003e \u003cp\u003eLiterature Citations 53\u003c\/p\u003e \u003cp\u003eProblems 54\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4. Basic Concepts in Chemical Kinetics: Molecular Interpretations of Kinetic Phenomena 72\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.0 Introduction 72\u003c\/p\u003e \u003cp\u003e4.1 Reaction Mechanisms 73\u003c\/p\u003e \u003cp\u003e4.2 Chain Reactions 83\u003c\/p\u003e \u003cp\u003e4.3 Molecular Theories of Chemical Kinetics 93\u003c\/p\u003e \u003cp\u003eLiterature Citations 103\u003c\/p\u003e \u003cp\u003eProblems 104\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5. Chemical Systems Involving Multiple Reactions 117\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.0 Introduction 117\u003c\/p\u003e \u003cp\u003e5.1 Reversible Reactions 117\u003c\/p\u003e \u003cp\u003e5.2 Parallel or Competitive Reactions 125\u003c\/p\u003e \u003cp\u003e5.3 Series or Consecutive Reactions: Irreversible Series Reactions 133\u003c\/p\u003e \u003cp\u003e5.4 Complex Reactions 137\u003c\/p\u003e \u003cp\u003eLiterature Citations 142\u003c\/p\u003e \u003cp\u003eProblems 142\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6. Elements of Heterogeneous Catalysis 152\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.0 Introduction 152\u003c\/p\u003e \u003cp\u003e6.1 Adsorption Phenomena 153\u003c\/p\u003e \u003cp\u003e6.2 Adsorption Isotherms 156\u003c\/p\u003e \u003cp\u003e6.3 Reaction Rate Expressions for Heterogeneous Catalytic Reactions 160\u003c\/p\u003e \u003cp\u003e6.4 Physical Characterization of Heterogeneous Catalysts 170\u003c\/p\u003e \u003cp\u003e6.5 Catalyst Preparation, Fabrication, and Activation 174\u003c\/p\u003e \u003cp\u003e6.6 Poisoning and Deactivation of Catalysts 177\u003c\/p\u003e \u003cp\u003eLiterature Citations 178\u003c\/p\u003e \u003cp\u003eProblems 179\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7. Liquid Phase Reactions 189\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.0 Introduction 189\u003c\/p\u003e \u003cp\u003e7.1 Electrostatic Effects in Liquid Solution 191\u003c\/p\u003e \u003cp\u003e7.2 Pressure Effects on Reactions in Liquid Solution 192\u003c\/p\u003e \u003cp\u003e7.3 Homogeneous Catalysis in Liquid Solution 193\u003c\/p\u003e \u003cp\u003e7.4 Correlation Methods for Kinetic Data: Linear Free Energy Relations 202\u003c\/p\u003e \u003cp\u003eLiterature Citations 207\u003c\/p\u003e \u003cp\u003eProblems 207\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8. Basic Concepts in Reactor Design and Ideal Reactor Models 216\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.0 Introduction 216\u003c\/p\u003e \u003cp\u003e8.1 Design Analysis for Batch Reactors 225\u003c\/p\u003e \u003cp\u003e8.2 Design of Tubular Reactors 228\u003c\/p\u003e \u003cp\u003e8.3 Continuous Flow Stirred-Tank Reactors 234\u003c\/p\u003e \u003cp\u003e8.4 Reactor Networks Composed of Combinations of Ideal Continuous Flow Stirred-Tank Reactors and Plug Flow Reactors 254\u003c\/p\u003e \u003cp\u003e8.5 Summary of Fundamental Design Relations: Comparison of Isothermal Stirred-Tank and Plug Flow Reactors 256\u003c\/p\u003e \u003cp\u003e8.6 Semibatch or Semiflow Reactors 256\u003c\/p\u003e \u003cp\u003eLiterature Citations 259\u003c\/p\u003e \u003cp\u003eProblems 259\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9. Selectivity and Optimization Considerations in the Design of Isothermal Reactors 273\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.0 Introduction 273\u003c\/p\u003e \u003cp\u003e9.1 Competitive (Parallel) Reactions 274\u003c\/p\u003e \u003cp\u003e9.2 Consecutive (Series) Reactions: A →k1→ B →k2→ C →k3→ D 278\u003c\/p\u003e \u003cp\u003e9.3 Competitive Consecutive Reactions 283\u003c\/p\u003e \u003cp\u003e9.4 Reactor Design for Autocatalytic Reactions 290\u003c\/p\u003e \u003cp\u003eLiterature Citations 294\u003c\/p\u003e \u003cp\u003eProblems 294\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10. Temperature and Energy Effects in Chemical Reactors 305\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.0 Introduction 305\u003c\/p\u003e \u003cp\u003e10.1 The Energy Balance as Applied to Chemical Reactors 305\u003c\/p\u003e \u003cp\u003e10.2 The Ideal Well-Stirred Batch Reactor 307\u003c\/p\u003e \u003cp\u003e10.3 The Ideal Continuous Flow Stirred-Tank Reactor 311\u003c\/p\u003e \u003cp\u003e10.4 Temperature and Energy Considerations in Tubular Reactors 314\u003c\/p\u003e \u003cp\u003e10.5 Autothermal Operation of Reactors 317\u003c\/p\u003e \u003cp\u003e10.6 Stable Operating Conditions in Stirred Tank Reactors 320\u003c\/p\u003e \u003cp\u003e10.7 Selection of Optimum Reactor Temperature Profiles: Thermodynamic and Selectivity Considerations 324\u003c\/p\u003e \u003cp\u003eLiterature Citations 327\u003c\/p\u003e \u003cp\u003eProblems 328\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11. Deviations from Ideal Flow Conditions 337\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.0 Introduction 337\u003c\/p\u003e \u003cp\u003e11.1 Residence Time Distribution Functions, \u003ci\u003eF(t)\u003c\/i\u003e and \u003ci\u003edF(t)\u003c\/i\u003e 337\u003c\/p\u003e \u003cp\u003e11.2 Conversion Levels in Nonideal Flow Reactors 352\u003c\/p\u003e \u003cp\u003e11.3 General Comments and Rules of Thumb 358\u003c\/p\u003e \u003cp\u003eLiterature Citations 359\u003c\/p\u003e \u003cp\u003eProblems 359\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12. Reactor Design for Heterogeneous Catalytic Reactions 371\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.0 Introduction 371\u003c\/p\u003e \u003cp\u003e12.1 Commercially Significant Types of Heterogeneous Catalytic Reactors 371\u003c\/p\u003e \u003cp\u003e12.2 Mass Transport Processes within Porous Catalysts 376\u003c\/p\u003e \u003cp\u003e12.3 Diffusion and Reaction in Porous Catalysts 380\u003c\/p\u003e \u003cp\u003e12.4 Mass Transfer Between the Bulk Fluid and External Surfaces of Solid Catalysts 406\u003c\/p\u003e \u003cp\u003e12.5 Heat Transfer Between the Bulk Fluid and External Surfaces of Solid Catalysts 413\u003c\/p\u003e \u003cp\u003e12.6 Global Reaction Rates 416\u003c\/p\u003e \u003cp\u003e12.7 Design of Fixed Bed Reactors 418\u003c\/p\u003e \u003cp\u003e12.8 Design of Fluidized Bed Catalytic Reactors 437\u003c\/p\u003e \u003cp\u003eLiterature Citations 439\u003c\/p\u003e \u003cp\u003eProblems 441\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13. Basic and Applied Aspects of Biochemical Transformations and Bioreactors 451\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.0 Introduction 451\u003c\/p\u003e \u003cp\u003e13.1 Growth Cycles of Microorganisms: Batch Operation of Bioreactors 452\u003c\/p\u003e \u003cp\u003e13.2 Principles and Special Considerations for Bioreactor Design 472\u003c\/p\u003e \u003cp\u003e13.3 Commercial Scale Applications of Bioreactors in Chemical and Environmental Engineering 495\u003c\/p\u003e \u003cp\u003eLiterature Citations 516\u003c\/p\u003e \u003cp\u003eProblems 517\u003c\/p\u003e \u003cp\u003eAppendix A. Fugacity Coefficient Chart 527\u003c\/p\u003e \u003cp\u003eAppendix B. Nomenclature 528\u003c\/p\u003e \u003cp\u003eAppendix C. Supplementary References 535\u003c\/p\u003e \u003cp\u003eAuthor Index 537\u003c\/p\u003e \u003cp\u003eSubject Index 545\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eCHARLES G. HILL, J\u003csmall\u003eR\u003c\/small\u003e., S\u003csmall\u003eC\u003c\/small\u003e.D,\u003c\/b\u003e is Professor Emeritus at the University of Wisconsin–Madison with over 200 peer-reviewed publications to his credit. In addition to his academic work, he has served as a consultant to government agencies and private corporations. Dr. Hill’s research has been highly interdisciplinary, including experience as a Fulbright Senior Scholar collaborating on studies of enzymatic reactions at the Institute for Catalysis and Petrochemistry (Spain).\u003c\/p\u003e \u003cp\u003e\u003cb\u003eTHATCHER W. ROOT, P\u003csmall\u003eH\u003c\/small\u003eD,\u003c\/b\u003e is Professor of Chemical Engineering at the University of Wisconsin–Madison. Dr. Root was awarded an NSF Presidential Young Investigator Award and recently received the Benjamin Smith Reynolds Award for Excellence in Teaching Engineers.\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eThe \u003ci\u003eSecond Edition\u003c\/i\u003e features new problems that engage readers in contemporary reactor design\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eHighly praised by instructors, students, and chemical engineers, \u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e has been extensively revised and updated in this \u003ci\u003eSecond Edition\u003c\/i\u003e. The text continues to offer a solid background in chemical reaction kinetics as well as in material and energy balances, preparing readers with the foundation necessary for success in the design of chemical reactors. Moreover, it reflects not only the basic engineering science, but also the mathematical tools used by today’s engineers to solve problems associated with the design of chemical reactors.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e enables readers to progressively build their knowledge and skills by applying the laws of conservation of mass and energy to increasingly more difficult challenges in reactor design. The first one-third of the text emphasizes general principles of chemical reaction kinetics, setting the stage for the subsequent treatment of reactors intended to carry out homogeneous reactions, heterogeneous catalytic reactions, and biochemical transformations. Topics include:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eThermodynamics of chemical reactions\u003c\/li\u003e \u003cli\u003eDetermination of reaction rate expressions\u003c\/li\u003e \u003cli\u003eElements of heterogeneous catalysis\u003c\/li\u003e \u003cli\u003eBasic concepts in reactor design and ideal reactor models\u003c\/li\u003e \u003cli\u003eTemperature and energy effects in chemical reactors\u003c\/li\u003e \u003cli\u003eBasic and applied aspects of biochemical transformations and bioreactors\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eAbout 70% of the problems in this \u003ci\u003eSecond Edition\u003c\/i\u003e are new. These problems, frequently based on articles culled from the research literature, help readers develop a solid understanding of the material. Many of these new problems also offer readers opportunities to use current software applications such as Mathcad and MATLAB\u003csup\u003e®\u003c\/sup\u003e.\u003c\/p\u003e \u003cp\u003eBy enabling readers to progressively build and apply their knowledge, the \u003ci\u003eSecond Edition\u003c\/i\u003e of \u003ci\u003eIntroduction to Chemical Engineering Kinetics \u0026amp; Reactor Design\u003c\/i\u003e remains a premier text for students in chemical engineering and a valuable resource for practicing engineers.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989456928997,"sku":"NP9781118368251","price":130.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781118368251.jpg?v=1761784174","url":"https:\/\/k12savings.com\/es\/products\/introduction-to-chemical-engineering-kinetics-and-reactor-design-isbn-9781118368251","provider":"K12savings","version":"1.0","type":"link"}