{"product_id":"inorganic-syntheses-volume-35-isbn-9780471682554","title":"Inorganic Syntheses, Volume 35","description":"The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds.  \u003cul\u003e \u003cli\u003eIncludes complete, up-to-date procedures involving important inorganic substances\u003c\/li\u003e \u003cli\u003eContains subject, contributor, and formula indexes\u003c\/li\u003e \u003c\/ul\u003e  Preface.  \u003cp\u003eContributors.\u003c\/p\u003e \u003cp\u003eDedication.\u003c\/p\u003e \u003cp\u003eNotice to Contributors and Checkers.\u003c\/p\u003e \u003cp\u003eToxic Substances and Laboratory Hazards.\u003c\/p\u003e \u003cp\u003eChapter One COMPLEXES OF BULKY ß-DIKETIMINATE LIGANDS.\u003c\/p\u003e \u003cp\u003e1. Introduction.\u003c\/p\u003e \u003cp\u003e2. ß-Diketiminate Precursors HL\u003csup\u003eMe,Me3\u003c\/sup\u003e and TlL\u003csup\u003eMe,Me3\u003c\/sup\u003e (L\u003csup\u003eMe,Me3\u003c\/sup\u003e = 2,4-Bis-(Mesitylimido)Pentyl).\u003c\/p\u003e \u003cp\u003e3. ß-Diketiminate Precursors L\u003csup\u003eMe,iPr2\u003c\/sup\u003eH, [\u003csup\u003eLMe,iPr2\u003c\/sup\u003eLi]x, and [L\u003csup\u003etBu,iPr2\u003c\/sup\u003eK]x (L\u003csup\u003eMe,iPr2\u003c\/sup\u003e = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl; L\u003csup\u003etBu,iPr2\u003c\/sup\u003e = 2,2,6,6-\u003c\/p\u003e \u003cp\u003eTetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl).\u003c\/p\u003e \u003cp\u003e4. ß-Diketiminate Precursors L\u003csup\u003etBu,iPr2\u003c\/sup\u003eH and L\u003csup\u003etBu,iPr2\u003c\/sup\u003eLi(THF) (L\u003csup\u003etBu,iPr2\u003c\/sup\u003e=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl).\u003c\/p\u003e \u003cp\u003e5. Scandium Trichloride Tris(Tetrahydrofuran) and ß-Diketiminate-Supported Scandium Chloride Complexes.\u003c\/p\u003e \u003cp\u003e6. ß-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes.\u003c\/p\u003e \u003cp\u003e7. ß-Diketiminate-Supported Vanadium and Chromium Chloride Complexes.\u003c\/p\u003e \u003cp\u003e8. ß-Diketiminate-Supported Manganese and Zinc Complexes.\u003c\/p\u003e \u003cp\u003e9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (L\u003csup\u003eMe,iPr2\u003c\/sup\u003eFeCl).\u003c\/p\u003e \u003cp\u003e10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (L\u003csup\u003etBu,iPr2\u003c\/sup\u003eFeCl).\u003c\/p\u003e \u003cp\u003e11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (L\u003csup\u003etBu,iPr2\u003c\/sup\u003eCoCl).\u003c\/p\u003e \u003cp\u003e12. ß-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of L\u003csup\u003eMe,Me3\u003c\/sup\u003e (L\u003csup\u003eMe,Me3\u003c\/sup\u003e = 2,4-Bis-(Mesitylimido)Pentyl).\u003c\/p\u003e \u003cp\u003e13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [L\u003csup\u003eMe,iPr2\u003c\/sup\u003eNi(µ-Cl)]\u003csub\u003e2\u003c\/sub\u003e.\u003c\/p\u003e \u003cp\u003e14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (L\u003csup\u003eMe,Me3\u003c\/sup\u003eCu)\u003csub\u003e2\u003c\/sub\u003e(µ-n\u003csup\u003e2\u003c\/sup\u003e:n\u003csup\u003e2\u003c\/sup\u003e-C\u003csub\u003e7\u003c\/sub\u003eH\u003csub\u003e8\u003c\/sub\u003e).\u003c\/p\u003e \u003cp\u003e15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (L\u003csup\u003eMe,iPr2\u003c\/sup\u003eCuCl).\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Two BORON CLUSTER COMPOUNDS.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16. Salts of Dodecamethylcarba-\u003ci\u003ecloso\u003c\/i\u003e-Dodecaborate(—) Anion, CB\u003csub\u003e11\u003c\/sub\u003eMe\u003csub\u003e12\u003c\/sub\u003e, and the Radical Dodecamethylcarba-\u003ci\u003ecloso\u003c\/i\u003e-Dodecaboranyl, CB\u003csub\u003e11\u003c\/sub\u003eMe\u003csub\u003e12\u003c\/sub\u003e.\u003c\/p\u003e \u003cp\u003e17. Cesium Dodecahydroxy-\u003ci\u003ecloso\u003c\/i\u003e-Dodecaborate, Cs\u003csub\u003e2\u003c\/sub\u003e[B\u003csub\u003e12\u003c\/sub\u003e(OH)\u003csub\u003e12\u003c\/sub\u003e].\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Three COORDINATION COMPOUNDS.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18. Pentaaquanitrosylchromium Sulfate.\u003c\/p\u003e \u003cp\u003e19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex.\u003c\/p\u003e \u003cp\u003e20. Tris(2-Picolinyl)Methane and Its Copper(I) Complex.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Four CARBENE LIGANDS AND COMPLEXES.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e21. 1,3-Dialkyl-Imidazole-2-Ylidenes.\u003c\/p\u003e \u003cp\u003e22. A Chelating Rhodium \u003ci\u003eN\u003c\/i\u003e-Heterocyclic Carbene Complex by Transmetallation from a Silver–NHC Intermediate.\u003c\/p\u003e \u003cp\u003e23. Rhodium and Iridium \u003ci\u003eN\u003c\/i\u003e-Heterocyclic Carbene Complexes from Imidazolium Carboxylates.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Five FUNCTIONAL LIGANDS AND COMPLEXES.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e24. \u003ci\u003eN\u003c\/i\u003e-\u003ci\u003etert\u003c\/i\u003e-Butyl \u003ci\u003eortho\u003c\/i\u003e-Aminophenol, \u003ci\u003eortho\u003c\/i\u003e-Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex.\u003c\/p\u003e \u003cp\u003e25. Synthesis of the Water-Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane).\u003c\/p\u003e \u003cp\u003e26. Synthesis of Metal-Organic Frameworks: MOF-5 and MOF-177.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Six ORGANOMETALLIC REAGENTS.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e27. Tricarbonyl 1,3,5-Trimethyl-1,3,5-Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)\u003csub\u003e3\u003c\/sub\u003e(Me\u003csub\u003e3\u003c\/sub\u003eTACH) (M = Cr, Mo, W)].\u003c\/p\u003e \u003cp\u003e28. Manganese Tricarbonyl Transfer (MTT) Agents.\u003c\/p\u003e \u003cp\u003e29. Bis(1,5-Cyclooctadiene)Nickel(0).\u003c\/p\u003e \u003cp\u003e30. Sodium (n\u003csup\u003e5\u003c\/sup\u003e-Cyclopentadienyl)Tris(Dimethylphosphito-\u003ci\u003eP\u003c\/i\u003e) Cobaltate(III), Na[(C\u003csub\u003e5\u003c\/sub\u003eH\u003csub\u003e5\u003c\/sub\u003e)Co{P(O)(OMe)\u003csub\u003e2\u003c\/sub\u003e}\u003csub\u003e3\u003c\/sub\u003e].\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Seven BIO-INSPIRED IRON AND NICKEL COMPLEXES.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e31. Iron–Cyanocarbonyl Complexes [PPN][Fe(CO)\u003csub\u003e4\u003c\/sub\u003e(CN)] and [PPN][FeBr(CO)\u003csub\u003e3\u003c\/sub\u003e(CN)\u003csub\u003e2\u003c\/sub\u003e].\u003c\/p\u003e \u003cp\u003e32. Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine.\u003c\/p\u003e \u003cp\u003e33. Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates.\u003c\/p\u003e \u003cp\u003e34 (1,3-Propanedithiolato)-Hexacarbonyldiiron and Cyanide Derivatives.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Eight RUTHENIUM COMPLEXES.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e35. Ruthenium(II)-Chlorido Complexes of Dimethylsulfoxide.\u003c\/p\u003e \u003cp\u003e36. Synthesis of Chloride-Free Ruthenium(II) Hexaaqua Tosylate, [Ru(H\u003csub\u003e2\u003c\/sub\u003eO)\u003csub\u003e6\u003c\/sub\u003e]tos\u003csub\u003e2\u003c\/sub\u003e.\u003c\/p\u003e \u003cp\u003e37. Basic Ruthenium Acetate and Mixed Valence Derivatives.\u003c\/p\u003e \u003cp\u003e38. Di-µ-Chloro(Ethylbenzoate)Diruthenium(II), [(n\u003csup\u003e6\u003c\/sup\u003e-etb)RuCl\u003csub\u003e2\u003c\/sub\u003e]\u003csub\u003e2\u003c\/sub\u003e.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter Nine IRIDIUM COMPLEXES.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e39. The Diphosphine tfepma and its Diiridium Complex Ir\u003csub\u003e2\u003c\/sub\u003e\u003csup\u003e0,II\u003c\/sup\u003e(tfepma)\u003csub\u003e3\u003c\/sub\u003eCl\u003csub\u003e2\u003c\/sub\u003e.\u003c\/p\u003e \u003cp\u003e40. Heteroleptic Cyclometalated Iridium(III) Complexes.\u003c\/p\u003e \u003cp\u003e41. Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes.\u003c\/p\u003e \u003cp\u003eContributor Index.\u003c\/p\u003e \u003cp\u003eSubject Index.\u003c\/p\u003e \u003cp\u003eFormula Index.\u003c\/p\u003e  \u003cp\u003e\u003cstrong\u003eThomas Rauchfuss\u003c\/strong\u003e received his undergraduate degree from the University of Puget Sound (1971) and his Ph.D. from Washington State University (1976). He has studied overseas at the following institutions: the Australian National University, University of Auckland, University of Strasbourg, and the Technical University of Karlsruhe. He is interested in all aspects of the synthesis and reactivity of inorganic, organometallic, and main-group compounds and materials.?He is a winner of the prestigious ACS Award in Inorganic Chemistry, and is Fellow of both the American Chemical Society and the Japan Society for the Promotion of Science.?Among others, Dr. Rauchfuss has held the Guggenheim Fellowship as well as the Alfred P. Sloan Fellowship,and has written numerous papers and book chapters.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989430190309,"sku":"NP9780471682554","price":182.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9780471682554.jpg?v=1761784073","url":"https:\/\/k12savings.com\/es\/products\/inorganic-syntheses-volume-35-isbn-9780471682554","provider":"K12savings","version":"1.0","type":"link"}