{"product_id":"handbook-of-aggregation-induced-emission-volume-1-isbn-9781119642916","title":"Handbook of Aggregation-Induced Emission, Volume 1","description":"\u003cp\u003e\u003cb\u003eThe first volume of the ultimate reference on the science and applications of aggregation-induced emission \u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eThe Handbook of Aggregation-Induced Emission\u003c\/i\u003e explores foundational and advanced topics in aggregation-induced emission, as well as cutting-edge developments in the field, celebrating twenty years of progress and achievement in this important and interdisciplinary field. The three volumes combine to offer readers a comprehensive and insightful interpretation accessible to both new and experienced researchers working on aggregation-induced emission. \u003c\/p\u003e \u003cp\u003eIn this first volume of three, the editors survey the subject of  aggregation-induced emission with a focus on the fundamentals of various branches of the discipline, such as crystallization-induced emission, room temperature phosphorescence, aggregation-induced delayed fluorescence, and more. This book covers the new properties of materials endowed by molecular aggregates. It also includes:  \u003c\/p\u003e \u003cul\u003e \u003cli\u003eA thorough introduction to the mechanistic understanding of the importance of molecular motion to aggregation-induced emission \u003c\/li\u003e \u003cli\u003eAn exploration of the aggregation-induced emission mechanism at the molecular level \u003c\/li\u003e \u003cli\u003ePractical discussions of aggregation-induced emission from the restriction of double bond rotation at the excited state, and clusterization-triggered emission \u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003ePerfect for academic researchers working on aggregation-induced emission, this set of volumes is also ideal for professionals and students in the fields of photophysics, photochemistry, materials science, optoelectronic materials, synthetic organic chemistry, macromolecular chemistry, polymer science, and biological sciences. \u003c\/p\u003eDer erste Band des ultimativen Referenzwerks zur Wissenschaft und Anwendung aggregationsinduzierter Emissionen\u003cbr\u003e \u003cbr\u003e Im Handbook of Aggregation-Induced Emission werden grundlegende und erweiterte Themen der aggregationsinduzierten Emissionen sowie innovative Entwicklungen in diesem Bereich dargestellt, einem wichtigen, interdisziplinären Forschungsbereich, in dem über die letzten zwanzig Jahre zahlreiche Fortschritte und Erfolge erzielt wurden. Die drei Bände des Werks vermitteln den Leserinnen und Lesern eine umfassende, aufschlussreiche Sichtweise, die für neue und erfahrene Forscher auf dem Gebiet der aggregationsinduzierten Emissionen verständlich ist.\u003cbr\u003e \u003cbr\u003e In diesem ersten der drei Bände geben die Herausgeber einen Überblick über das Gebiet der aggregationsinduzierten Emissionen und legen dabei den Schwerpunkt auf die Grundlagen der verschiedenen Felder, die zu diesem Fachgebiet gehören, wie kristallisationsinduzierte Emissionen, Phosphoreszenz bei Raumtemperatur, aggregationsinduzierte verzögerte Fluoreszenz usw. Es werden die neuen Eigenschaften von Materialien betrachtet, die durch molekulare Aggregate entstehen. Darüber hinaus enthält dieser Band:\u003cbr\u003e * Eine umfassende Einführung in das mechanistische Verständnis der Bedeutung der Molekularbewegung für aggregationsinduzierte Emissionen\u003cbr\u003e * Eine Betrachtung des Mechanismus der aggregationsinduzierten Emissionen auf molekularer Ebene\u003cbr\u003e * Praktische Erörterungen der aggregationsinduzierten Emissionen aufgrund der Einschränkung der Doppelbindungsrotation im angeregten Zustand sowie der durch Clusterbildung ausgelösten Emissionen\u003cbr\u003e \u003cbr\u003e Dieses dreibändige Werk ist ideal für Forscher im akademischen Bereich, die sich mit aggregationsinduzierten Emissionen befassen, es richtet sich aber auch an Fachleute und Studierende in den Bereichen Photophysik, Photochemie, Materialwissenschaft, optoelektronische Materialien, synthetische organische Chemie, makromolekulare Chemie, Polymerwissenschaft und Biowissenschaften. \u003cp\u003eList of Contributors xv\u003c\/p\u003e \u003cp\u003ePreface to Handbook of Aggregation-Induced Emission xxi\u003c\/p\u003e \u003cp\u003ePreface to Volume 1: Fundamentals xxiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 The Mechanistic Understanding of the Importance of Molecular Motions to Aggregation-induced Emission 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJunkai Liu and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Restriction of Intramolecular Motion 2\u003c\/p\u003e \u003cp\u003e1.2.1 Restriction of Intramolecular Rotation 3\u003c\/p\u003e \u003cp\u003e1.2.2 Restriction of Intramolecular Vibration 4\u003c\/p\u003e \u003cp\u003e1.2.3 Ultrafast Insights into Tetraphenylethylene Derivatives 6\u003c\/p\u003e \u003cp\u003e1.2.4 Theoretical Insights into Restriction of Intramolecular Motion 8\u003c\/p\u003e \u003cp\u003e1.3 Restricted Access to Conical Intersection 12\u003c\/p\u003e \u003cp\u003e1.4 Restriction of Access to the Dark State 14\u003c\/p\u003e \u003cp\u003e1.5 Suppression of Kasha’s Rule 15\u003c\/p\u003e \u003cp\u003e1.6 Through Space Conjugation 17\u003c\/p\u003e \u003cp\u003e1.6.1 Clusterization-Triggered Emission 18\u003c\/p\u003e \u003cp\u003e1.6.2 Polymerization-induced Emission 19\u003c\/p\u003e \u003cp\u003e1.6.3 Excited-state Through-space Conjugation 19\u003c\/p\u003e \u003cp\u003e1.7 Perspective 21\u003c\/p\u003e \u003cp\u003eReferences 23\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Understanding the AIE Mechanism at the Molecular Level \u003c\/b\u003e\u003cb\u003e27\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eXiaoyan Zheng and Qian Peng\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 27\u003c\/p\u003e \u003cp\u003e2.2 Theoretical Methods 28\u003c\/p\u003e \u003cp\u003e2.2.1 Radiative and Nonradiative Rate Constants 28\u003c\/p\u003e \u003cp\u003e2.2.2 Computational Details 29\u003c\/p\u003e \u003cp\u003e2.3 Revealed AIE Mechanism 31\u003c\/p\u003e \u003cp\u003e2.3.1 Rotating Vibrations of Intramolecular Aromatic Ring 31\u003c\/p\u003e \u003cp\u003e2.3.2 Stretching Vibrations of Bonds 33\u003c\/p\u003e \u003cp\u003e2.3.3 Bending Vibration of Bonds 34\u003c\/p\u003e \u003cp\u003e2.3.4 Flipping Vibrations of Molecular Skeletons 35\u003c\/p\u003e \u003cp\u003e2.3.5 Twisting Vibration of Molecular Skeletons 36\u003c\/p\u003e \u003cp\u003e2.4 Visualize Calculated Parameters in Experiments 37\u003c\/p\u003e \u003cp\u003e2.4.1 Stokes Shift vs Reorganization Energy 37\u003c\/p\u003e \u003cp\u003e2.4.2 Resonance Raman Spectroscopy (RSS) vs Reorganization Energy 38\u003c\/p\u003e \u003cp\u003e2.4.3 Isotope Effect vs DRE 40\u003c\/p\u003e \u003cp\u003e2.4.4 Linear Relationship between Fluorescence Intensity and Amorphous Aggregate Size 42\u003c\/p\u003e \u003cp\u003e2.4.5 Pressure-induced Enhanced Emission (PIEE) 44\u003c\/p\u003e \u003cp\u003e2.5 Molecular Design Based on AIE Mechanism 45\u003c\/p\u003e \u003cp\u003e2.6 Summary and Outlook 46\u003c\/p\u003e \u003cp\u003eAcknowledgments 48\u003c\/p\u003e \u003cp\u003eReferences 48\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Aggregation-induced Emission from the Restriction of Double Bond Rotation at the Excited State \u003c\/b\u003e\u003cb\u003e55\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMing Hu and Yan-Song Zheng\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 55\u003c\/p\u003e \u003cp\u003e3.2 AIE Phenomena and Applications from RDBR Mechanism 58\u003c\/p\u003e \u003cp\u003e3.2.1 Evolvement and Development of AIE Mechanisms 58\u003c\/p\u003e \u003cp\u003e3.2.2 Investigation of RDBR AIE Mechanism by \u003ci\u003eE\/Z \u003c\/i\u003eisomerization 64\u003c\/p\u003e \u003cp\u003e3.2.3 Investigating of RDBR AIE Mechanism by Immobilization of TPE Propeller-like Conformation 69\u003c\/p\u003e \u003cp\u003e3.2.4 Research of Theoretical Calculation on RDBR 78\u003c\/p\u003e \u003cp\u003e3.2.5 Other AIEgens Involving RBDR Process 84\u003c\/p\u003e \u003cp\u003e3.3 Conclusions 93\u003c\/p\u003e \u003cp\u003eReferences 94\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 The Expansion of AIE Thought: From Single Molecule to Molecular Uniting \u003c\/b\u003e\u003cb\u003e99\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eQiuyan Liao, Qianqian Li, and Zhen Li\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Aggregation-Induced Emission 99\u003c\/p\u003e \u003cp\u003e4.2 Photoluminescence Materials Based on Molecular Set 101\u003c\/p\u003e \u003cp\u003e4.3 Mechanoluminescence Materials Based on Molecular Set 106\u003c\/p\u003e \u003cp\u003e4.3.1 Mechanoluminescence Materials with Fluorescence Emission 106\u003c\/p\u003e \u003cp\u003e4.3.2 Mechanoluminescence Materials with Mechanical Induced Dual-or Tri-color Emission 115\u003c\/p\u003e \u003cp\u003e4.3.3 Quantitative Research of Mechanoluminescence Property 121\u003c\/p\u003e \u003cp\u003e4.4 Mechanochromism Materials 122\u003c\/p\u003e \u003cp\u003e4.4.1 Mechanochromism Materials Based on Polymorphs 122\u003c\/p\u003e \u003cp\u003e4.4.2 Mechanochromism Materials Based on Excimer Emission 125\u003c\/p\u003e \u003cp\u003e4.4.3 Other Kinds of Mechanochromism Materials 128\u003c\/p\u003e \u003cp\u003e4.5 Room Temperature Phosphorescence Materials Based on Molecular Uniting 131\u003c\/p\u003e \u003cp\u003e4.5.1 Room Temperature Phosphorescence Materials with Aromatics 131\u003c\/p\u003e \u003cp\u003e4.5.2 Room Temperature Phosphorescence Materials with Simple or Nonaromatic Structure 140\u003c\/p\u003e \u003cp\u003e4.5.3 Room Temperature Phosphorescence Materials with Multiple Emission 142\u003c\/p\u003e \u003cp\u003e4.5.4 Photoinduced Room Temperature Phosphorescence Materials 144\u003c\/p\u003e \u003cp\u003e4.6 Conclusion and Perspectives 147\u003c\/p\u003e \u003cp\u003eReferences 147\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Clusterization-Triggered Emission \u003c\/b\u003e\u003cb\u003e153\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHaoke Zhang and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 153\u003c\/p\u003e \u003cp\u003e5.2 Pure \u003ci\u003en\u003c\/i\u003e-Electron Systems 156\u003c\/p\u003e \u003cp\u003e5.3 Pure \u003ci\u003eπ\u003c\/i\u003e-Electron Systems 160\u003c\/p\u003e \u003cp\u003e5.4 (\u003ci\u003en\u003c\/i\u003e, \u003ci\u003eπ\u003c\/i\u003e)-Electrons Systems 164\u003c\/p\u003e \u003cp\u003e5.5 Other Systems 166\u003c\/p\u003e \u003cp\u003e5.6 Summary 167\u003c\/p\u003e \u003cp\u003eReferences 168\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Crystallization-induced Emission Enhancement \u003c\/b\u003e\u003cb\u003e177\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYong Qiang Dong, Yingying Liu, Mengyang Liu, Qian Wang, and Kang Wang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 177\u003c\/p\u003e \u003cp\u003e6.2 Tetraphenylethylene Derivatives 178\u003c\/p\u003e \u003cp\u003e6.3 CIEE Active Luminogens with Bulky Conjugation Core 183\u003c\/p\u003e \u003cp\u003e6.3.1 Dibenzofulvene (DBF) Derivatives (Chart 6.2) 183\u003c\/p\u003e \u003cp\u003e6.3.2 9-([1,1\u003cb\u003e′\u003c\/b\u003e-Biphenyl]-4-ylphenylmethylene)-9H-xanthene 185\u003c\/p\u003e \u003cp\u003e6.3.3 Dicyanomethylenated Acridones 186\u003c\/p\u003e \u003cp\u003e6.3.4 Bis(diarylmethylene)dihydroanthracene [31] 187\u003c\/p\u003e \u003cp\u003e6.4 Other High-contrast CIEE Luminogens 190\u003c\/p\u003e \u003cp\u003e6.4.1 4-Dimethylamino-2-Benzylidene Malonic Acid Dimethyl Ester 190\u003c\/p\u003e \u003cp\u003e6.4.2 Diphenyl Maleimide Derivatives [33] 191\u003c\/p\u003e \u003cp\u003e6.4.3 3,4-Bisthienylmaleic Anhydride [34] 192\u003c\/p\u003e \u003cp\u003e6.4.4 Boron-containing CIEE Luminogens 193\u003c\/p\u003e \u003cp\u003e6.5 Potential Applications 196\u003c\/p\u003e \u003cp\u003e6.5.1 Volatile Organic Compounds (VOCs) Sensor 196\u003c\/p\u003e \u003cp\u003e6.5.2 OLED 196\u003c\/p\u003e \u003cp\u003e6.5.3 High-density Data Storage 197\u003c\/p\u003e \u003cp\u003e6.5.4 Mechanochromic (MC) Luminescent Sensor 198\u003c\/p\u003e \u003cp\u003e6.6 Summary and Perspective 198\u003c\/p\u003e \u003cp\u003eReferences 198\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Surface-fixation Induced Emission \u003c\/b\u003e\u003cb\u003e203\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYohei Ishida and Shinsuke Takagi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 203\u003c\/p\u003e \u003cp\u003e7.2 What Happened to the Characteristics of Molecules on the Clay Mineral Nanosheets 205\u003c\/p\u003e \u003cp\u003e7.3 Clay–Molecular Complexes 206\u003c\/p\u003e \u003cp\u003e7.4 Absorption Spectra of Clay–Molecular Complexes 207\u003c\/p\u003e \u003cp\u003e7.5 Emission Enhancement Phenomenon in Clay–Molecular Complexes: S-FIE 208\u003c\/p\u003e \u003cp\u003e7.6 Mechanism of Surface-Fixation Induced Emission 211\u003c\/p\u003e \u003cp\u003e7.7 Summary and Outlook 214\u003c\/p\u003e \u003cp\u003eAcknowledgment 215\u003c\/p\u003e \u003cp\u003eReferences 215\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Aggregation-induced Delayed Fluorescence \u003c\/b\u003e\u003cb\u003e221\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYan Fu, Hao Chen, Zujin Zhao, and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 221\u003c\/p\u003e \u003cp\u003e8.2 Novel Aggregation-induced Delayed Fluorescence Luminogens 222\u003c\/p\u003e \u003cp\u003e8.3 Conclusion and Outlook 247\u003c\/p\u003e \u003cp\u003eReferences 247\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Homogeneous Systems to Induce Emission of AIEgens \u003c\/b\u003e\u003cb\u003e251\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKenta Kokado and Kazuki Sada\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 251\u003c\/p\u003e \u003cp\u003e9.2 Homogeneous Solution 252\u003c\/p\u003e \u003cp\u003e9.2.1 Complexation with Anions 253\u003c\/p\u003e \u003cp\u003e9.2.2 Complexation with Cations 254\u003c\/p\u003e \u003cp\u003e9.2.3 Inclusion Complexes 256\u003c\/p\u003e \u003cp\u003e9.2.4 Adhesion on Macromolecules 257\u003c\/p\u003e \u003cp\u003e9.2.5 Steric Hindrance 258\u003c\/p\u003e \u003cp\u003e9.2.6 Covalent Linkage 259\u003c\/p\u003e \u003cp\u003e9.3 Liquid 260\u003c\/p\u003e \u003cp\u003e9.4 Gels and Network Polymers 261\u003c\/p\u003e \u003cp\u003e9.4.1 Chemically Crosslinked Gels 261\u003c\/p\u003e \u003cp\u003e9.4.2 Physically Crosslinked Gels 262\u003c\/p\u003e \u003cp\u003e9.5 Crystalline Materials 264\u003c\/p\u003e \u003cp\u003e9.6 Outlook and Future Perspectives 266\u003c\/p\u003e \u003cp\u003eReferences 266\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Hetero-aggregation-induced Tunable Emission (HAITE) Through Cocrystal Strategy \u003c\/b\u003e\u003cb\u003e273\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYinjuan Huang and Qichun Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 273\u003c\/p\u003e \u003cp\u003e10.2 Interactions Within Organic Cocrystals 274\u003c\/p\u003e \u003cp\u003e10.3 Preparation of Organic Cocrystals 275\u003c\/p\u003e \u003cp\u003e10.4 Molecular Stacking Modes Within Organic Cocrystals 276\u003c\/p\u003e \u003cp\u003e10.5 Characterization of Organic Cocrystals 277\u003c\/p\u003e \u003cp\u003e10.6 HAITE Through Cocrystal Strategy 277\u003c\/p\u003e \u003cp\u003e10.6.1 HAITE with Tunable Color and Enhanced Emission 278\u003c\/p\u003e \u003cp\u003e10.6.1.1 Insignificant Changed Intensity but Tuned Color 278\u003c\/p\u003e \u003cp\u003e10.6.1.2 Enhanced Emission and Tuned Color 287\u003c\/p\u003e \u003cp\u003e10.6.2 HAITE with Increased PLQY but Intrinsic Color 291\u003c\/p\u003e \u003cp\u003e10.6.3 HAITE: Thermally Activated Delayed Fluorescence 297\u003c\/p\u003e \u003cp\u003e10.6.4 HAITE-phosphorescence 300\u003c\/p\u003e \u003cp\u003e10.7 Summary and Outlook 302\u003c\/p\u003e \u003cp\u003eReferences 304\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Anti-Kasha Emission from Organic Aggregates \u003c\/b\u003e\u003cb\u003e311\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eWenbin Huang and Zikai He\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 311\u003c\/p\u003e \u003cp\u003e11.2 Anti-Kasha Emission from Aromatic Carbonyl Compounds in Aggregates 312\u003c\/p\u003e \u003cp\u003e11.3 Anti-Kasha Emission from Azulene Compounds in Aggregate 322\u003c\/p\u003e \u003cp\u003e11.4 Anti-Kasha Emission from Other Unconventional Aromatic Compounds in Aggregates 324\u003c\/p\u003e \u003cp\u003e11.5 Conclusions 327\u003c\/p\u003e \u003cp\u003eReferences 327\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Aggregation-enhanced Emission: From Flexible to Rigid Cores \u003c\/b\u003e\u003cb\u003e333\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHarnimarta Deol, Gurpreet Singh, Vandana Bhalla, and Manoj Kumar\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 333\u003c\/p\u003e \u003cp\u003e12.2 Freely Moving Rotors-induced Emission Enhancement 334\u003c\/p\u003e \u003cp\u003e12.3 Guest-induced Emission Enhancement 344\u003c\/p\u003e \u003cp\u003e12.4 Conclusion 366\u003c\/p\u003e \u003cp\u003eAcknowledgment 367\u003c\/p\u003e \u003cp\u003eReferences 367\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Room-temperature Phosphorescence of Pure Organics \u003c\/b\u003e\u003cb\u003e371\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eTianwen Zhu, Zihao Zhao, Tianjia Yang, and Wang Zhang Yuan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 371\u003c\/p\u003e \u003cp\u003e13.2 Fundamental Mechanism in Organic Phosphorescence 372\u003c\/p\u003e \u003cp\u003e13.2.1 Photophysical Process for Phosphorescence 372\u003c\/p\u003e \u003cp\u003e13.2.2 Theoretical Study on Phosphorescent Process 373\u003c\/p\u003e \u003cp\u003e13.3 Recent Progress in Organic RTP Materials 375\u003c\/p\u003e \u003cp\u003e13.3.1 Crystallization-induced RTP 375\u003c\/p\u003e \u003cp\u003e13.3.1.1 Heavy Atom Effect 376\u003c\/p\u003e \u003cp\u003e13.3.1.2 Molecular Interaction 380\u003c\/p\u003e \u003cp\u003e13.3.1.3 H-aggregation 380\u003c\/p\u003e \u003cp\u003e13.3.2 Doping in Rigid Matrix-induced RTP 382\u003c\/p\u003e \u003cp\u003e13.3.2.1 Host–Guest System 385\u003c\/p\u003e \u003cp\u003e13.3.2.2 Doping in Polymer Matrix 387\u003c\/p\u003e \u003cp\u003e13.3.3 Clustering-triggered RTP 389\u003c\/p\u003e \u003cp\u003e13.3.3.1 Natural Products 389\u003c\/p\u003e \u003cp\u003e13.3.3.2 Synthetic Compounds 394\u003c\/p\u003e \u003cp\u003e13.3.4 Other Systems 399\u003c\/p\u003e \u003cp\u003e13.3.4.1 Amorphous Organics 399\u003c\/p\u003e \u003cp\u003e13.3.4.2 Organic Framework 399\u003c\/p\u003e \u003cp\u003e13.3.4.3 Supramolecular Organics 402\u003c\/p\u003e \u003cp\u003e13.3.4.4 Hybrid Perovskites 403\u003c\/p\u003e \u003cp\u003e13.3.5 Applications 405\u003c\/p\u003e \u003cp\u003e13.4 Conclusions and Perspectives 405\u003c\/p\u003e \u003cp\u003eReferences 407\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 A Global Potential Energy Surface Approach to the Photophysics of AIEgens: The Role of Conical Intersections \u003c\/b\u003e\u003cb\u003e411\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRachel Crespo-Otero and Lluís Blancafort\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 411\u003c\/p\u003e \u003cp\u003e14.2 Methodological Aspects 412\u003c\/p\u003e \u003cp\u003e14.2.1 Intramolecular Restriction Models and the FGR-based Approach 412\u003c\/p\u003e \u003cp\u003e14.2.2 A PES-based Description of Photochemical Mechanisms 412\u003c\/p\u003e \u003cp\u003e14.2.3 Computational Approaches for Excited States 416\u003c\/p\u003e \u003cp\u003e14.2.3.1 Electronic Structure Methods for Excited States 416\u003c\/p\u003e \u003cp\u003e14.2.3.2 Dynamics Simulations in the Context of AIE 420\u003c\/p\u003e \u003cp\u003e14.2.4 Methods for Large Systems 420\u003c\/p\u003e \u003cp\u003e14.3 CI-centered Global PES for AIEgens 424\u003c\/p\u003e \u003cp\u003e14.3.1 Double-bond Torsion 424\u003c\/p\u003e \u003cp\u003e14.3.2 Double-bond Torsion \u003ci\u003evs \u003c\/i\u003eCyclization in TPE Derivatives 428\u003c\/p\u003e \u003cp\u003e14.3.3 Excited-state Intramolecular Proton Transfer (ESIPT) Compounds 431\u003c\/p\u003e \u003cp\u003e14.3.4 Ring Puckering 432\u003c\/p\u003e \u003cp\u003e14.3.5 Bond Stretching 435\u003c\/p\u003e \u003cp\u003e14.3.6 A View of AIE Based on the RACI Model and the Global PES 436\u003c\/p\u003e \u003cp\u003e14.4 Crystallization-induced Phosphorescence 436\u003c\/p\u003e \u003cp\u003e14.5 Effect of Intermolecular and Intramolecular Interactions on the Photophysics of AIEgens 437\u003c\/p\u003e \u003cp\u003e14.5.1 Excitonic Effects in AIE 437\u003c\/p\u003e \u003cp\u003e14.5.2 Effect of Intramolecular and Intermolecular Interactions on Emission Color 439\u003c\/p\u003e \u003cp\u003e14.6 New Challenges 439\u003c\/p\u003e \u003cp\u003e14.6.1 The Role of Dark States in AIE 439\u003c\/p\u003e \u003cp\u003e14.6.2 Pressure-induced Emission Enhancement 440\u003c\/p\u003e \u003cp\u003e14.6.3 AIE in Transition Metal (TM) Compounds 442\u003c\/p\u003e \u003cp\u003e14.7 Conclusions and Outlook 443\u003c\/p\u003e \u003cp\u003eReferences 444\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Multicomponent Reactions as Synthetic Design Tools of AIE and Emission Solvatochromic Quinoxalines \u003c\/b\u003e\u003cb\u003e455\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLukas Biesen and Thomas J. J. Müller\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 455\u003c\/p\u003e \u003cp\u003e15.2 Synthetic Approaches to Quinoxalines via Multicomponent Reactions and One-Pot Processes 456\u003c\/p\u003e \u003cp\u003e15.3 Photophysical Properties and Emission Solvatochromicity of Quinoxalines 462\u003c\/p\u003e \u003cp\u003e15.4 AIE Characteristics and Effects of Quinoxalines 468\u003c\/p\u003e \u003cp\u003e15.5 Conclusion 476\u003c\/p\u003e \u003cp\u003eAcknowledgments 476\u003c\/p\u003e \u003cp\u003eReferences 476\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Aggregation-induced Emission Luminogens with Both High-luminescence Efficiency and Charge Mobility \u003c\/b\u003e\u003cb\u003e485\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYing Yu, Zheng Zhao, and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 485\u003c\/p\u003e \u003cp\u003e16.2 p-Type OSCs 487\u003c\/p\u003e \u003cp\u003e16.3 n-Type OSCs 495\u003c\/p\u003e \u003cp\u003e16.4 Ambipolar OSCs 500\u003c\/p\u003e \u003cp\u003e16.5 Conclusion and Perspective 505\u003c\/p\u003e \u003cp\u003eReferences 505\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Morphology Modulation of Aggregation-induced Emission: From Thermodynamic Self-assembly to Kinetic Controlling \u003c\/b\u003e\u003cb\u003e509\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKaizhi Gu, Chenxu Yan, Zhiqian Guo, and Wei-Hong Zhu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 509\u003c\/p\u003e \u003cp\u003e17.2 Aggregation Modulation of AIE Bioprobes via Hydrophilicity Improvement 511\u003c\/p\u003e \u003cp\u003e17.2.1 Molecular Modification 511\u003c\/p\u003e \u003cp\u003e17.2.2 Polymerization with Hydrophilic Matrix 515\u003c\/p\u003e \u003cp\u003e17.3 Thermodynamic Self-assembly of AIE Materials 519\u003c\/p\u003e \u003cp\u003e17.4 Morphology Tuning of AIE Nanoaggregates 519\u003c\/p\u003e \u003cp\u003e17.5 Kinetic-driven Preparation of AIE NPs 523\u003c\/p\u003e \u003cp\u003e17.6 Conclusion and Outlook 527\u003c\/p\u003e \u003cp\u003eReferences 527\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 AIE-active Polymer \u003c\/b\u003e\u003cb\u003e531\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRong Hu, Anjun Qin, and Ben Zhong Tang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 531\u003c\/p\u003e \u003cp\u003e18.2 Photophysical Properties 532\u003c\/p\u003e \u003cp\u003e18.2.1 Quantum Yield 532\u003c\/p\u003e \u003cp\u003e18.2.2 Photosensitization 536\u003c\/p\u003e \u003cp\u003e18.2.3 Two-photon Absorption and Emission 538\u003c\/p\u003e \u003cp\u003e18.2.4 Circularly Polarized Luminescence 540\u003c\/p\u003e \u003cp\u003e18.3 Applications 541\u003c\/p\u003e \u003cp\u003e18.3.1 Chem-sensor 541\u003c\/p\u003e \u003cp\u003e18.3.2 Bioimaging 543\u003c\/p\u003e \u003cp\u003e18.3.3 Therapy Applications 546\u003c\/p\u003e \u003cp\u003e18.4 Conclusion and Perspective 549\u003c\/p\u003e \u003cp\u003eAcknowledgments 550\u003c\/p\u003e \u003cp\u003eReferences 550\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Liquid-crystalline AIEgens: Materials and Applications \u003c\/b\u003e\u003cb\u003e555\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKyohei Hisano, Supattra Panthai, and Osamu Tsutsumi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 555\u003c\/p\u003e \u003cp\u003e19.2 Materials: Molecular Design 556\u003c\/p\u003e \u003cp\u003e19.2.1 Discotic LC AIEgen 556\u003c\/p\u003e \u003cp\u003e19.2.2 Calamitic LC AIEgens 561\u003c\/p\u003e \u003cp\u003e19.2.3 Polymeric LC AIEgens 566\u003c\/p\u003e \u003cp\u003e19.3 Applications of LC AIEgens 567\u003c\/p\u003e \u003cp\u003e19.3.1 Linearly Polarized Luminescence 567\u003c\/p\u003e \u003cp\u003e19.3.2 Circularly Polarized Luminescence 568\u003c\/p\u003e \u003cp\u003e19.4 Conclusion 571\u003c\/p\u003e \u003cp\u003eReferences 571\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Push–Pull AIEgens \u003c\/b\u003e\u003cb\u003e575\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAndrea Nitti and Dario Pasini\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 575\u003c\/p\u003e \u003cp\u003e20.2 Basic Concept of Molecular Design 576\u003c\/p\u003e \u003cp\u003e20.2.1 Photophysical Excited States in Aggregates 576\u003c\/p\u003e \u003cp\u003e20.2.2 Fundamental Molecular Design to Achieve Push–Pull AIEgens 579\u003c\/p\u003e \u003cp\u003e20.3 Push–Pull AIEgens from Rotor Structure 581\u003c\/p\u003e \u003cp\u003e20.3.1 Double Bond Stator 582\u003c\/p\u003e \u003cp\u003e20.3.2 Point-restricted Rotors from Atoms or Functional Groups 584\u003c\/p\u003e \u003cp\u003e20.3.3 Aromatic Rotors 587\u003c\/p\u003e \u003cp\u003e20.4 Push–Pull AIEgens from ACQ Chromophores 589\u003c\/p\u003e \u003cp\u003e20.4.1 BT-based AIEgens 589\u003c\/p\u003e \u003cp\u003e20.4.2 Cyanine and DCM-based AIEgens 594\u003c\/p\u003e \u003cp\u003e20.4.3 QM-based AIEgens 595\u003c\/p\u003e \u003cp\u003e20.4.4 DPP-based AIEgens 597\u003c\/p\u003e \u003cp\u003e20.4.5 Rylene-based AIEgens 599\u003c\/p\u003e \u003cp\u003e20.5 Concluding Remarks 602\u003c\/p\u003e \u003cp\u003eReferences 602\u003c\/p\u003e \u003cp\u003eIndex 609\u003c\/p\u003e \u003cp\u003e\u003cb\u003eYouhong Tang\u003c\/b\u003e is a Professor at Flinders University, Australia and actively works in aggregation-induced emission areas. \u003c\/p\u003e\u003cp\u003e\u003cb\u003eBen Zhong Tang\u003c\/b\u003e is a Chair Professor at the Chinese University of Hong Kong, Shenzhen. He is widely known as the pioneer of the study of aggregation-induced emission.  \u003c\/p\u003e\u003cp\u003e\u003cb\u003eThe first volume of the ultimate reference on the science and applications of aggregation-induced emission\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eThe \u003ci\u003eHandbook of Aggregation-Induced Emission\u003c\/i\u003e explores foundational and advanced topics in aggregation-induced emission, as well as cutting-edge developments in the field, celebrating twenty years of progress and achievement in this important and interdisciplinary field. The three volumes combine to offer readers a comprehensive and insightful interpretation accessible to both new and experienced researchers working on aggregation-induced emission. \u003c\/p\u003e\u003cp\u003e In this first volume of three, the editors survey the subject of aggregation-induced emission with a focus on the fundamentals of various branches of the discipline, such as crystallization-induced emission, room temperature phosphorescence, aggregation-induced delayed fluorescence, and more. This book covers the new properties of materials endowed by molecular aggregates. It also includes: \u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eA thorough introduction to the mechanistic understanding of the importance of molecular motion to aggregation-induced emission\u003c\/li\u003e \u003cli\u003eAn exploration of the aggregation-induced emission mechanism at the molecular level\u003c\/li\u003e \u003cli\u003ePractical discussions of aggregation-induced emission from the restriction of double bond rotation at the excited state, and clusterization-triggered emission\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003ePerfect for academic researchers working on aggregation-induced emission, this set of volumes is also ideal for professionals and students in the fields of photophysics, photochemistry, materials science, optoelectronic materials, synthetic organic chemistry, macromolecular chemistry, polymer science, and biological sciences.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989325070565,"sku":"NP9781119642916","price":269.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119642916.jpg?v=1761783674","url":"https:\/\/k12savings.com\/es\/products\/handbook-of-aggregation-induced-emission-volume-1-isbn-9781119642916","provider":"K12savings","version":"1.0","type":"link"}