{"product_id":"endohedral-metallofullerenes-isbn-9781119942726","title":"Endohedral Metallofullerenes","description":"\u003cp\u003e\u003ci\u003eEndohedral Metallofullerenes: Fullerenes with Metal Inside\u003c\/i\u003e presents a comprehensive survey of the current state of knowledge on endohedral metallofullerenes, from preparation to functionalization, reactivity and applications. Following a brief historical overview, the book describes methods for synthesis, extraction, separation and purification, and provides an insight into the molecular and crystal structures. Subsequent chapters discuss various categories of endohedral metallofullerenes based on the encapsulated species, including carbides, nitrides, sulphides, oxides, non-metal and non-IPR endohedral metallofullerenes, followed by scanning tunneling microscopy studies and the examination of electronic, vibrational, magnetic and optical properties. The book concludes with chapters addressing the chemical functionalization of endohedral metallofullerenes, and applications ranging from solar cells to biomedicine.\u003c\/p\u003e Foreword ix \u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003ePersonal Reflection – Nori Shinohara xiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 The First Experimental Evidence of Metallofullerenes 1\u003c\/p\u003e \u003cp\u003e1.2 Early Years of Metallofullerene Research 3\u003c\/p\u003e \u003cp\u003e1.3 Conventional and IUPAC Nomenclature for Metallofullerenes 5\u003c\/p\u003e \u003cp\u003eReferences 6\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Synthesis, Extraction, and Purification 9\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Synthesis of Endohedral Metallofullerenes 9\u003c\/p\u003e \u003cp\u003e2.2 Solvent Extraction of Metallofullerenes from Primary Soot 14\u003c\/p\u003e \u003cp\u003e2.3 Purification and Isolation by HPLC 15\u003c\/p\u003e \u003cp\u003e2.4 Fast Separation and Purification with Lewis Acids 18\u003c\/p\u003e \u003cp\u003eReferences 19\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Molecular and Crystal Structures 23\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Endohedral or Exohedral? A Big Controversy 23\u003c\/p\u003e \u003cp\u003e3.2 Structural Analyses 25\u003c\/p\u003e \u003cp\u003eReferences 37\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Electronic States and Structures 43\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Electron Transfer in Metallofullerenes 43\u003c\/p\u003e \u003cp\u003e4.2 ESR Evidence on the Existence of Structural Isomers 45\u003c\/p\u003e \u003cp\u003e4.3 Electrochemistry of Metallofullerenes 48\u003c\/p\u003e \u003cp\u003e4.4 Similarity in the UV]Vis]NIR Absorption Spectra 51\u003c\/p\u003e \u003cp\u003e4.5 Fermi Levels and the Electronic Structures 57\u003c\/p\u003e \u003cp\u003e4.6 Metal–Cage Vibration within Metallofullerenes 59\u003c\/p\u003e \u003cp\u003eReferences 63\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Carbide and Nitride Metallofullerenes 69\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Discovery of Carbide Metallofullerenes 69\u003c\/p\u003e \u003cp\u003e5.2 Fullerene Quantum Gyroscope: An Ideal Molecular Rotor 75\u003c\/p\u003e \u003cp\u003e5.3 Nitride Metallofullerenes 77\u003c\/p\u003e \u003cp\u003eReferences 81\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Non]Isolated Pentagon Rule Metallofullerenes 85\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Isolated Pentagon Rule 85\u003c\/p\u003e \u003cp\u003e6.2 Non]IPR Metallofullerenes 86\u003c\/p\u003e \u003cp\u003eReferences 89\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Oxide and Sulfide Metallofullerenes 91\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 O xide Metallofullerenes 91\u003c\/p\u003e \u003cp\u003e7.2 Sulfide Metallofullerenes 95\u003c\/p\u003e \u003cp\u003eReferences 100\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Non]metal Endohedral Fullerenes 103\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Nitrogen]Containing \u003ca href=\"mailto:N@C60\"\u003eN@C60\u003c\/a\u003e 103\u003c\/p\u003e \u003cp\u003e8.2 Phosphorus]Containing \u003ca href=\"mailto:P@C60\"\u003eP@C60\u003c\/a\u003e 111\u003c\/p\u003e \u003cp\u003e8.3 Inert Gas Endohedral Fullerenes \u003ca href=\"mailto:He@C60\"\u003eHe@C60\u003c\/a\u003e, \u003ca href=\"mailto:Ne@C60\"\u003eNe@C60\u003c\/a\u003e, \u003ca href=\"mailto:Ar@C60\"\u003eAr@C60\u003c\/a\u003e, \u003ca href=\"mailto:Kr@C60\"\u003eKr@C60\u003c\/a\u003e, and \u003ca href=\"mailto:Xe@C60\"\u003eXe@C60\u003c\/a\u003e 112\u003c\/p\u003e \u003cp\u003e8.4 Hydrogen]Containing \u003ca href=\"mailto:H2@C60\"\u003eH2@C60\u003c\/a\u003e 120\u003c\/p\u003e \u003cp\u003e8.5 Water]Containing \u003ca href=\"mailto:H2O@C60\"\u003eH2O@C60\u003c\/a\u003e 125\u003c\/p\u003e \u003cp\u003eReferences 128\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Scanning Tunneling Microscopy Studies of Metallofullerenes 133\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 STM Studies of Metallofullerenes on Clean Surfaces 133\u003c\/p\u003e \u003cp\u003e9.2 Metallofullerenes as Superatom 135\u003c\/p\u003e \u003cp\u003e9.3 STM\/STS Studies on Metallofullerene Layers 137\u003c\/p\u003e \u003cp\u003e9.4 STM\/STS Studies on a Single Metallofullerene Molecule 139\u003c\/p\u003e \u003cp\u003eReferences 141\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Magnetic Properties of Metallofullerenes 145\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Magnetism of Mono]metallofullerenes 145\u003c\/p\u003e \u003cp\u003e10.2 SXAS and SXMCD Studies of Metallofullerenes 149\u003c\/p\u003e \u003cp\u003eReferences 154\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Organic Chemistry of Metallofullerenes 157\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Cycloaddition Reactions 157\u003c\/p\u003e \u003cp\u003e11.2 Radical Addition Reactions 178\u003c\/p\u003e \u003cp\u003e11.3 Miscellaneous Reactions 180\u003c\/p\u003e \u003cp\u003e11.4 Donor–Acceptor Dyads 185\u003c\/p\u003e \u003cp\u003e11.5 Bis]adduct Formation 194\u003c\/p\u003e \u003cp\u003e11.6 Supramolecular Functionalization 195\u003c\/p\u003e \u003cp\u003e11.7 Purification of Metallofullerenes by Chemical Methods 198\u003c\/p\u003e \u003cp\u003eReferences 200\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Applications with Metallofullerenes 209\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Solar Cells 209\u003c\/p\u003e \u003cp\u003e12.2 Biomedical Aspects of Water]Soluble Metallofullerenes 221\u003c\/p\u003e \u003cp\u003eReferences 226\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Growth Mechanism 229\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Carbon Clusters: A Road to Fullerene Growth 229\u003c\/p\u003e \u003cp\u003e13.2 Roles Played by Metal Atoms in the Fullerene Growth 233\u003c\/p\u003e \u003cp\u003e13.3 Top]Down or Bottom]Up Growth? 237\u003c\/p\u003e \u003cp\u003eReferences 251\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 \u003ca href=\"mailto:M@C60\"\u003eM@C60\u003c\/a\u003e: A Big Mystery and a Big Challenge 255\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 What Happens to \u003ca href=\"mailto:M@C60\"\u003eM@C60\u003c\/a\u003e? 255\u003c\/p\u003e \u003cp\u003e14.2 A Big Challenge: Superconductive Metallofullerenes 259\u003c\/p\u003e \u003cp\u003e14.3 Future Prospects 261\u003c\/p\u003e \u003cp\u003eReferences 262\u003c\/p\u003e \u003cp\u003eIndex 265\u003c\/p\u003e \u003cb\u003eHisanori Shinohara\u003c\/b\u003e Department of Chemistry, Nagoya University, Japan\u003cbr\u003e\u003cbr\u003e\u003cb\u003eNikos Tagmatarchis\u003c\/b\u003e Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, Greece\u003cbr\u003e\u003cbr\u003eForeword by \u003cb\u003eSir Harold Kroto\u003c\/b\u003e \u003cp\u003eEndohedral metallofullerenes are a fascinating class of fullerene materials because many of the structural, electronic and magnetic properties of the fullerenes change drastically upon encapsulation of metal atoms. Consequently these materials offer practical applications in a variety of areas including solar cells and biomedicine.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eEndohedral Metallofullerenes: Fullerenes with Metal Inside\u003c\/i\u003e presents a comprehensive survey of the current state of knowledge on endohedral metallofullerenes, from preparation to functionalization, reactivity and applications. Following a brief historical overview, the book describes methods for synthesis, extraction, separation and purification, and provides an insight into the molecular and crystal structures. Subsequent chapters discuss various categories of endohedral metallofullerenes based on the encapsulated species, including carbides, nitrides, sulphides, oxides, non-metal and non-IPR endohedral metallofullerenes, followed by scanning tunneling microscopy studies and the examination of electronic, vibrational, magnetic and optical properties. The book concludes with chapters addressing the chemical functionalization of endohedral metallofullerenes, and applications ranging from solar cells to biomedicine.\u003c\/p\u003e \u003cp\u003eThis book will provide scientists, researchers and students in the field of nanocarbons and nanomaterials with a fresh and authoritative look at the diverse areas of endohedral metallofullerenes.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47989132329189,"sku":"NP9781119942726","price":135.95,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119942726.jpg?v=1761782926","url":"https:\/\/k12savings.com\/es\/products\/endohedral-metallofullerenes-isbn-9781119942726","provider":"K12savings","version":"1.0","type":"link"}