{"product_id":"atomically-precise-nanochemistry-isbn-9781119788645","title":"Atomically Precise Nanochemistry","description":"\u003cb\u003eAtomically Precise Nanochemistry\u003c\/b\u003e \u003cp\u003e\u003cb\u003eExplore recent progress and developments in atomically precise nanochemistry\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eChemists have long been motivated to create atomically precise nanoclusters, not only for addressing some fundamental issues that were not possible to tackle with imprecise nanoparticles, but also to provide new opportunities for applications such as catalysis, optics, and biomedicine. In \u003ci\u003eAtomically Precise Nanochemistry\u003c\/i\u003e, a team of distinguished researchers delivers a state-of-the-art reference for researchers and industry professionals working in the fields of nanoscience and cluster science, in disciplines ranging from chemistry to physics, biology, materials science, and engineering. \u003c\/p\u003e\u003cp\u003eA variety of different nanoclusters are covered, including metal nanoclusters, semiconductor nanoclusters, metal-oxo systems, large-sized organometallic nano-architectures, carbon clusters, and supramolecular architectures. The book contains not only experimental contributions, but also theoretical insights into the atomic and electronic structures, as well as the catalytic mechanisms. The authors explore synthesis, structure, geometry, bonding, and applications of each type of nanocluster. \u003c\/p\u003e\u003cp\u003ePerfect for researchers working in nanoscience, nanotechnology, and materials chemistry, \u003ci\u003eAtomically Precise Nanochemistry \u003c\/i\u003ewill also benefit industry professionals in these sectors seeking a practical and up-to-date resource. \u003c\/p\u003e\u003cp\u003eList of Contributors xiii\u003c\/p\u003e \u003cp\u003ePreface xvii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction to Atomically Precise Nanochemistry 1\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eRongchao Jin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Why Atomically Precise Nanochemistry? 1\u003c\/p\u003e \u003cp\u003e1.1.1 Motivations from Nanoscience Research 1\u003c\/p\u003e \u003cp\u003e1.1.2 Motivations from Inorganic Chemistry Research 5\u003c\/p\u003e \u003cp\u003e1.1.3 Motivations from Gas Phase Cluster Research 6\u003c\/p\u003e \u003cp\u003e1.1.4 Motivations from Other Areas 6\u003c\/p\u003e \u003cp\u003e1.2 Types of Nanoclusters Covered in This Book 7\u003c\/p\u003e \u003cp\u003e1.2.1 Atomically Precise Metal Nanoclusters (Au, Ag, Cu, Ni, Rh) 8\u003c\/p\u003e \u003cp\u003e1.2.2 Endohedral Fullerenes and Graphene Nanoribbons 10\u003c\/p\u003e \u003cp\u003e1.2.3 Zintl Clusters 10\u003c\/p\u003e \u003cp\u003e1.2.4 Metal- Oxo Nanoclusters 11\u003c\/p\u003e \u003cp\u003e1.3 Some Fundamental Aspects 12\u003c\/p\u003e \u003cp\u003e1.3.1 Synthesis and Crystallization 12\u003c\/p\u003e \u003cp\u003e1.3.2 Structural and Bonding Patterns 16\u003c\/p\u003e \u003cp\u003e1.3.3 Transition from Nonmetallic to Metallic State: Emergence of Plasmon 25\u003c\/p\u003e \u003cp\u003e1.3.4 Transition from Metal Complexes to the Cluster State: Emergence of Core 29\u003c\/p\u003e \u003cp\u003e1.3.5 Doping and Alloying 32\u003c\/p\u003e \u003cp\u003e1.3.6 Redox and Magnetism 33\u003c\/p\u003e \u003cp\u003e1.3.7 Energy Gap Engineering 39\u003c\/p\u003e \u003cp\u003e1.3.8 Assembly of Atomically Precise Nanoclusters 40\u003c\/p\u003e \u003cp\u003e1.4 Some Applications 42\u003c\/p\u003e \u003cp\u003e1.4.1 Chemical and Biological Sensing 43\u003c\/p\u003e \u003cp\u003e1.4.2 Biomedical Imaging, Drug Delivery, and Therapy 44\u003c\/p\u003e \u003cp\u003e1.4.3 Antibacteria 45\u003c\/p\u003e \u003cp\u003e1.4.4 Solar Energy Conversion 45\u003c\/p\u003e \u003cp\u003e1.4.5 Catalysis 45\u003c\/p\u003e \u003cp\u003e1.5 Concluding Remarks 49\u003c\/p\u003e \u003cp\u003eAcknowledgment 49\u003c\/p\u003e \u003cp\u003eReferences 49\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Total Synthesis of Thiolate- Protected Noble Metal Nanoclusters 57\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eQiaofeng Yao, Yitao Cao, Tiankai Chen, and Jianping Xie\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 57\u003c\/p\u003e \u003cp\u003e2.2 Size Engineering of Metal Nanoclusters 58\u003c\/p\u003e \u003cp\u003e2.2.1 Size Engineering by Reduction- Growth Strategy 58\u003c\/p\u003e \u003cp\u003e2.2.2 Size Engineering by Size Conversion Strategy 62\u003c\/p\u003e \u003cp\u003e2.3 Composition Engineering of Metal Nanoclusters 64\u003c\/p\u003e \u003cp\u003e2.3.1 Metal Composition Engineering 64\u003c\/p\u003e \u003cp\u003e2.3.2 Ligand Composition Engineering 70\u003c\/p\u003e \u003cp\u003e2.4 Structure Engineering of Metal Nanoclusters 73\u003c\/p\u003e \u003cp\u003e2.4.1 Pseudo- Isomerization 75\u003c\/p\u003e \u003cp\u003e2.4.2 Isomerization 75\u003c\/p\u003e \u003cp\u003e2.5 Top- Down Etching Reaction of Metal Nanoclusters 78\u003c\/p\u003e \u003cp\u003e2.6 Conclusion and Outlooks 80\u003c\/p\u003e \u003cp\u003eContributions 83\u003c\/p\u003e \u003cp\u003eReferences 83\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Thiolated Gold Nanoclusters with Well- Defined Compositions and Structures 87\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eWanmiao Gu and Zhikun Wu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 87\u003c\/p\u003e \u003cp\u003e3.2 Synthesis, Purification, and Characterization of Gold Nanoclusters 88\u003c\/p\u003e \u003cp\u003e3.2.1 Synthesis 88\u003c\/p\u003e \u003cp\u003e3.2.1.1 Synthesis Strategy 89\u003c\/p\u003e \u003cp\u003e3.2.1.2 Gold Salt (Complex) Reduction Method 89\u003c\/p\u003e \u003cp\u003e3.2.1.3 Ligand Induction Method 91\u003c\/p\u003e \u003cp\u003e3.2.1.4 Anti- Galvanic Reaction Method 91\u003c\/p\u003e \u003cp\u003e3.2.2 Isolation and Purification 92\u003c\/p\u003e \u003cp\u003e3.2.3 Characterization 94\u003c\/p\u003e \u003cp\u003e3.3 Structures of Gold Nanoclusters 95\u003c\/p\u003e \u003cp\u003e3.3.1 Kernel Structures of Au \u003csub\u003en\u003c\/sub\u003e (SR) \u003csub\u003em\u003c\/sub\u003e 96\u003c\/p\u003e \u003cp\u003e3.3.2 Kernels Based on Tetrahedral Au \u003csub\u003e4\u003c\/sub\u003e Units 96\u003c\/p\u003e \u003cp\u003e3.3.2.1 Kernels in fcc Structure 99\u003c\/p\u003e \u003cp\u003e3.3.2.2 Kernels Arranged in hcp and bcc Fashions 99\u003c\/p\u003e \u003cp\u003e3.3.2.3 Kernels in Mirror Symmetry and Dual- Packing (fcc and non- fcc) 101\u003c\/p\u003e \u003cp\u003e3.3.2.4 Kernels Based on Icosahedral Au \u003csub\u003e13\u003c\/sub\u003e Unit 102\u003c\/p\u003e \u003cp\u003e3.3.2.5 Kernels with Multiple Shells 105\u003c\/p\u003e \u003cp\u003e3.3.3 Protecting Surface Motifs of Au \u003csub\u003en\u003c\/sub\u003e (SR) \u003csub\u003em\u003c\/sub\u003e Clusters 111\u003c\/p\u003e \u003cp\u003e3.3.3.1 Staple- Like Au \u003csub\u003eX\u003c\/sub\u003e (sr) \u003csub\u003eX+1\u003c\/sub\u003e (x = 1, 2, 3, 4, 8) Motifs 111\u003c\/p\u003e \u003cp\u003e3.3.3.2 Ring- Like Au \u003csub\u003eX\u003c\/sub\u003e (sr) \u003csub\u003eX\u003c\/sub\u003e (x = 4, 5, 6, 8) Motifs 111\u003c\/p\u003e \u003cp\u003e3.3.3.3 Giant Au \u003csub\u003e20\u003c\/sub\u003e S \u003csub\u003e3\u003c\/sub\u003e (SR) \u003csub\u003e18\u003c\/sub\u003e and Au \u003csub\u003e23\u003c\/sub\u003e S \u003csub\u003e4\u003c\/sub\u003e (SR) \u003csub\u003e18\u003c\/sub\u003e Staple Motifs 112\u003c\/p\u003e \u003cp\u003e3.3.3.4 Homo- Kernel Hetero- Staples 112\u003c\/p\u003e \u003cp\u003e3.4 Properties and Applications 115\u003c\/p\u003e \u003cp\u003e3.4.1 Properties 115\u003c\/p\u003e \u003cp\u003e3.4.1.1 Optical Absorption 116\u003c\/p\u003e \u003cp\u003e3.4.1.2 Photoluminescence 119\u003c\/p\u003e \u003cp\u003e3.4.1.3 Chirality 123\u003c\/p\u003e \u003cp\u003e3.4.1.4 Magnetism 124\u003c\/p\u003e \u003cp\u003e3.4.2 Applications 125\u003c\/p\u003e \u003cp\u003e3.4.2.1 Sensing 125\u003c\/p\u003e \u003cp\u003e3.4.2.2 Biological Labeling and Biomedicine 127\u003c\/p\u003e \u003cp\u003e3.4.2.3 Catalysis 127\u003c\/p\u003e \u003cp\u003e3.5 Conclusion and Future Perspectives 130\u003c\/p\u003e \u003cp\u003eAcknowledgments 131\u003c\/p\u003e \u003cp\u003eReferences 131\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Structural Design of Thiolate- Protected Gold Nanoclusters 141\u003cbr\u003e \u003c\/b\u003e\u003ci\u003ePengye Liu, Wenhua Han, and Wen Wu Xu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 141\u003c\/p\u003e \u003cp\u003e4.2 Structural Design Based on “Divide and Protect” Rule 142\u003c\/p\u003e \u003cp\u003e4.2.1 A Brief Introduction of the Idea 142\u003c\/p\u003e \u003cp\u003e4.2.2 Atomic Structure of Au \u003csub\u003e68\u003c\/sub\u003e (SH) \u003csub\u003e32\u003c\/sub\u003e 142\u003c\/p\u003e \u003cp\u003e4.2.3 Atomic Structure of Au \u003csub\u003e68\u003c\/sub\u003e (SH) \u003csub\u003e34\u003c\/sub\u003e 142\u003c\/p\u003e \u003cp\u003e4.3 Structural Design via Redistributing the “Staple” Motifs on the Known Au Core Structures 144\u003c\/p\u003e \u003cp\u003e4.3.1 A Brief Introduction of the Idea 144\u003c\/p\u003e \u003cp\u003e4.3.2− Atomic Structure of Au \u003csub\u003e22\u003c\/sub\u003e (SH) \u003csub\u003e17\u003c\/sub\u003e 145\u003c\/p\u003e \u003cp\u003e4.3.3 Atomic Structures of Au \u003csub\u003e27\u003c\/sub\u003e (SH) − \u003csub\u003e20\u003c\/sub\u003e , Au \u003csub\u003e32\u003c\/sub\u003e (SR) − \u003csub\u003e21\u003c\/sub\u003e , Au \u003csub\u003e34\u003c\/sub\u003e (SR) − \u003csub\u003e23\u003c\/sub\u003e , and Au \u003csub\u003e36\u003c\/sub\u003e (SR) \u003csub\u003e25\u003c\/sub\u003e − 146\u003c\/p\u003e \u003cp\u003e4.4 Structural Design via Structural Evolution 149\u003c\/p\u003e \u003cp\u003e4.4.1 A Brief Introduction of the Idea 149\u003c\/p\u003e \u003cp\u003e4.4.2 Atomic Structures of Au \u003csub\u003e60\u003c\/sub\u003e (SR) \u003csub\u003e36\u003c\/sub\u003e , Au \u003csub\u003e68\u003c\/sub\u003e (SR) \u003csub\u003e40\u003c\/sub\u003e , and Au \u003csub\u003e76\u003c\/sub\u003e (SR) \u003csub\u003e44\u003c\/sub\u003e 150\u003c\/p\u003e \u003cp\u003e4.4.3 Atomic Structure of Au \u003csub\u003e58\u003c\/sub\u003e (SR) \u003csub\u003e30\u003c\/sub\u003e 152\u003c\/p\u003e \u003cp\u003e4.5 Structural Design via Grand Unified Model 153\u003c\/p\u003e \u003cp\u003e4.5.1 A Brief Introduction of the Idea 153\u003c\/p\u003e \u003cp\u003e4.5.2 Atomic Structures of Hollow Au \u003csub\u003e36\u003c\/sub\u003e (SR) \u003csub\u003e12\u003c\/sub\u003e and Au \u003csub\u003e42\u003c\/sub\u003e (SR) \u003csub\u003e14\u003c\/sub\u003e 154\u003c\/p\u003e \u003cp\u003e4.5.3 Atomic Structures of Au \u003csub\u003e28\u003c\/sub\u003e (SR) \u003csub\u003e20\u003c\/sub\u003e 155\u003c\/p\u003e \u003cp\u003e4.6 Conclusion and Perspectives 155\u003c\/p\u003e \u003cp\u003eAcknowledgment 156\u003c\/p\u003e \u003cp\u003eReferences 156\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Electrocatalysis on Atomically Precise Metal Nanoclusters 161\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eHoeun Seong, Woojun Choi, Yongsung Jo, and Dongil Lee\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 161\u003c\/p\u003e \u003cp\u003e5.1.1 Materials Design Strategy for Electrocatalysis 161\u003c\/p\u003e \u003cp\u003e5.1.2 Atomically Precise Metal Nanoclusters as Electrocatalysts 163\u003c\/p\u003e \u003cp\u003e5.2 Electrochemistry of Atomically Precise Metal Nanoclusters 164\u003c\/p\u003e \u003cp\u003e5.2.1 Size- Dependent Voltammetry 164\u003c\/p\u003e \u003cp\u003e5.2.2 Metal- Doped Gold Nanoclusters 166\u003c\/p\u003e \u003cp\u003e5.2.3 Metal- Doped Silver Nanoclusters 169\u003c\/p\u003e \u003cp\u003e5.3 Electrocatalytic Water Splitting on Atomically Precise Metal Nanoclusters 170\u003c\/p\u003e \u003cp\u003e5.3.1 Hydrogen Evolution Reaction: Core Engineering 170\u003c\/p\u003e \u003cp\u003e5.3.2 Hydrogen Evolution Reaction: Shell Engineering 172\u003c\/p\u003e \u003cp\u003e5.3.3 Hydrogen Evolution Reaction on Ag Nanoclusters 173\u003c\/p\u003e \u003cp\u003e5.3.4 Oxygen Evolution Reaction 176\u003c\/p\u003e \u003cp\u003e5.4 Electrocatalytic Conversion of CO \u003csub\u003e2\u003c\/sub\u003e on Atomically Precise Metal Nanoclusters 178\u003c\/p\u003e \u003cp\u003e5.4.1 Mechanistic Investigation of CO \u003csub\u003e2\u003c\/sub\u003e RR on Au Nanoclusters 179\u003c\/p\u003e \u003cp\u003e5.4.2 Identification of CO \u003csub\u003e2\u003c\/sub\u003e RR Active Sites 181\u003c\/p\u003e \u003cp\u003e5.4.3 CO \u003csub\u003e2\u003c\/sub\u003e RR on Cu Nanoclusters 183\u003c\/p\u003e \u003cp\u003e5.4.4 Syngas Production on Formulated Metal Nanoclusters 185\u003c\/p\u003e \u003cp\u003e5.5 Conclusions and Outlook 187\u003c\/p\u003e \u003cp\u003eAcknowledgments 188\u003c\/p\u003e \u003cp\u003eReferences 188\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Atomically Precise Metal Nanoclusters as Electrocatalysts: From Experiment to Computational Insights 195\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eFang Sun, Qing Tang, and De- en Jiang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 195\u003c\/p\u003e \u003cp\u003e6.2 Factors Affecting the Activity and Selectivity of NCs Electrocatalysis 196\u003c\/p\u003e \u003cp\u003e6.2.1 Size Effect 196\u003c\/p\u003e \u003cp\u003e6.2.2 Shape Effect 198\u003c\/p\u003e \u003cp\u003e6.2.3 Ligands Effect 199\u003c\/p\u003e \u003cp\u003e6.2.3.1 Different –R Groups in Thiolate Ligands 199\u003c\/p\u003e \u003cp\u003e6.2.3.2 Different Types of Ligands 199\u003c\/p\u003e \u003cp\u003e6.2.3.3 Ligand- on and - off Effect 200\u003c\/p\u003e \u003cp\u003e6.2.4 Charge State Effect 201\u003c\/p\u003e \u003cp\u003e6.2.5 Doping and Alloying Effect 202\u003c\/p\u003e \u003cp\u003e6.3 Important Electrocatalytic Applications 205\u003c\/p\u003e \u003cp\u003e6.3.1 Electrocatalytic Water Splitting 205\u003c\/p\u003e \u003cp\u003e6.3.1.1 Water Electrolysis Process 205\u003c\/p\u003e \u003cp\u003e6.3.1.2 Cathodic Water Reduction–HER 206\u003c\/p\u003e \u003cp\u003e6.3.1.3 Anodic Water Oxidation–OER 208\u003c\/p\u003e \u003cp\u003e6.3.2 Oxygen Reduction Reaction (ORR) 210\u003c\/p\u003e \u003cp\u003e6.3.3 Electrochemical CO \u003csub\u003e2\u003c\/sub\u003e Reduction Reaction (CO \u003csub\u003e2\u003c\/sub\u003e RR) 213\u003c\/p\u003e \u003cp\u003e6.4 Conclusion and Perspectives 219\u003c\/p\u003e \u003cp\u003eAcknowledgments 220\u003c\/p\u003e \u003cp\u003eReferences 220\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Ag Nanoclusters: Synthesis, Structure, and Properties 227\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManman Zhou and Manzhou Zhu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 227\u003c\/p\u003e \u003cp\u003e7.2 Synthetic Methods 228\u003c\/p\u003e \u003cp\u003e7.2.1 One- Pot Synthesis 228\u003c\/p\u003e \u003cp\u003e7.2.2 Ligand Exchange 228\u003c\/p\u003e \u003cp\u003e7.2.3 Chemical Etching 229\u003c\/p\u003e \u003cp\u003e7.2.4 Seeded Growth Method 229\u003c\/p\u003e \u003cp\u003e7.3 Structure of Ag NCs 229\u003c\/p\u003e \u003cp\u003e7.3.1 Based on Icosahedral Units’ Assembly 231\u003c\/p\u003e \u003cp\u003e7.3.2 Based on Ag \u003csub\u003e14\u003c\/sub\u003e Units’ Assembly 235\u003c\/p\u003e \u003cp\u003e7.3.3 Other Special Ag NCs 241\u003c\/p\u003e \u003cp\u003e7.4 Properties of Ag NCs 245\u003c\/p\u003e \u003cp\u003e7.4.1 Chirality of Ag NCs 245\u003c\/p\u003e \u003cp\u003e7.4.2 Photoluminescence of Ag NCs 247\u003c\/p\u003e \u003cp\u003e7.4.3 Catalytic Properties of Ag NCs 250\u003c\/p\u003e \u003cp\u003e7.5 Conclusion and Perspectives 250\u003c\/p\u003e \u003cp\u003eAcknowledgment 251\u003c\/p\u003e \u003cp\u003eReferences 251\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Atomically Precise Copper Nanoclusters: Syntheses, Structures, and Properties 257\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eChunwei Dong, Saidkhodzha Nematulloev, Peng Yuan, and Osman M. Bakr\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 257\u003c\/p\u003e \u003cp\u003e8.2 Syntheses of Copper NCs 258\u003c\/p\u003e \u003cp\u003e8.2.1 Direct Synthesis 258\u003c\/p\u003e \u003cp\u003e8.2.2 Indirect Synthesis: Nanocluster- to- Nanocluster Transformation 260\u003c\/p\u003e \u003cp\u003e8.3 Structures of Copper NCs 261\u003c\/p\u003e \u003cp\u003e8.3.1 Superatom- like Copper NCs without Hydrides 261\u003c\/p\u003e \u003cp\u003e8.3.2 Superatom- like Copper NCs with Hydrides 263\u003c\/p\u003e \u003cp\u003e8.3.3 Copper(I) Hydride NCs 265\u003c\/p\u003e \u003cp\u003e8.3.3.1 Determination of Hydrides 265\u003c\/p\u003e \u003cp\u003e8.3.3.2 Copper(I) Hydride NCs Determined by Single- Crystal Neutron Diffraction 265\u003c\/p\u003e \u003cp\u003e8.3.3.3 Copper(I) Hydride NCs Determined by Single- Crystal X- ray Diffraction 268\u003c\/p\u003e \u003cp\u003e8.4 Properties 270\u003c\/p\u003e \u003cp\u003e8.4.1 Photoluminescence of Copper NCs 270\u003c\/p\u003e \u003cp\u003e8.4.1.1 Aggregation- Induced Emission 271\u003c\/p\u003e \u003cp\u003e8.4.1.2 Circularly Polarized Luminescence (CPL) 273\u003c\/p\u003e \u003cp\u003e8.4.2 Catalytic Properties of Copper NCs 273\u003c\/p\u003e \u003cp\u003e8.4.2.1 Reduction of CO \u003csub\u003e2\u003c\/sub\u003e 273\u003c\/p\u003e \u003cp\u003e8.4.2.2 “Click” Reaction 276\u003c\/p\u003e \u003cp\u003e8.4.2.3 Hydrogenation 276\u003c\/p\u003e \u003cp\u003e8.4.2.4 Carbonylation Reactions 276\u003c\/p\u003e \u003cp\u003e8.4.3 Other Properties 276\u003c\/p\u003e \u003cp\u003e8.4.3.1 Hydrogen Storage 276\u003c\/p\u003e \u003cp\u003e8.4.3.2 Electronic Devices 277\u003c\/p\u003e \u003cp\u003e8.5 Summary Comparison with Gold and Silver NCs 277\u003c\/p\u003e \u003cp\u003e8.6 Conclusion and Perspectives 278\u003c\/p\u003e \u003cp\u003eReferences 279\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Atomically Precise Nanoclusters of Iron, Cobalt, and Nickel: Why Are They So Rare? 285\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eTrevor W. Hayton\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 285\u003c\/p\u003e \u003cp\u003e9.2 General Considerations 287\u003c\/p\u003e \u003cp\u003e9.3 Synthesis of Ni APNCs 288\u003c\/p\u003e \u003cp\u003e9.4 Synthesis of Co APNCs 294\u003c\/p\u003e \u003cp\u003e9.5 Attempted Synthesis of Fe APNCs 297\u003c\/p\u003e \u003cp\u003e9.6 Conclusions and Outlook 299\u003c\/p\u003e \u003cp\u003eAcknowledgments 300\u003c\/p\u003e \u003cp\u003eReferences 300\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Atomically Precise Heterometallic Rhodium Nanoclusters Stabilized by Carbonyl Ligands 309\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eGuido Bussoli, Cristiana Cesari, Cristina Femoni, Maria C. Iapalucci, Silvia Ruggieri, and Stefano Zacchini\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 309\u003c\/p\u003e \u003cp\u003e10.1.1 Metal Carbonyl Clusters: A Brief Historical Overview 309\u003c\/p\u003e \u003cp\u003e10.1.2 State of the Art on Rhodium Carbonyl Clusters 310\u003c\/p\u003e \u003cp\u003e10.2 Synthesis of Heterometallic Rhodium Carbonyl Nanoclusters 311\u003c\/p\u003e \u003cp\u003e10.2.1 Synthesis of the [Rh\u003csub\u003e12\u003c\/sub\u003e E(CO)\u003csub\u003e27\u003c\/sub\u003e ] n− Family of Nanoclusters 311\u003c\/p\u003e \u003cp\u003e10.2.2 Growth of Rhodium Heterometallic Nanoclusters 314\u003c\/p\u003e \u003cp\u003e10.2.2.1 Rh─Ge Nanoclusters 314\u003c\/p\u003e \u003cp\u003e10.2.2.2 Rh─Sn Nanoclusters 316\u003c\/p\u003e \u003cp\u003e10.2.2.3 Rh─Sb Nanoclusters 316\u003c\/p\u003e \u003cp\u003e10.2.2.4 Rh─Bi Nanoclusters 319\u003c\/p\u003e \u003cp\u003e10.3 Electron- Reservoir Behavior of Heterometallic Rhodium Nanoclusters 319\u003c\/p\u003e \u003cp\u003e10.4 Conclusions and Perspectives 322\u003c\/p\u003e \u003cp\u003eAcknowledgments 324\u003c\/p\u003e \u003cp\u003eReferences 324\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Endohedral Fullerenes: Atomically Precise Doping Inside Nano Carbon Cages 331\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eYang- Rong Yao, Jiawei Qiu, Lihao Zheng, Hongjie Jiang, Yunpeng Xia, and Ning Chen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 331\u003c\/p\u003e \u003cp\u003e11.2 Synthesis of Endohedral Metallofullerenes 332\u003c\/p\u003e \u003cp\u003e11.3 Fullerene Structures Tuned by Endohedral Doping 334\u003c\/p\u003e \u003cp\u003e11.3.1 Geometry of Empty and Endohedral Fullerene Cage Structures 334\u003c\/p\u003e \u003cp\u003e11.3.2 Conventional Endohedral Metallofullerenes 336\u003c\/p\u003e \u003cp\u003e11.3.2.1 Mono- Metallofullerens 336\u003c\/p\u003e \u003cp\u003e11.3.2.2 Di- Metallofullerenes 337\u003c\/p\u003e \u003cp\u003e11.3.3 Clusterfullerenes 339\u003c\/p\u003e \u003cp\u003e11.3.3.1 Nitride Clusterfullerenes 339\u003c\/p\u003e \u003cp\u003e11.3.3.2 Carbide Clusterfullerenes 339\u003c\/p\u003e \u003cp\u003e11.3.3.3 Oxide and Sulfide Clusterfullerenes 341\u003c\/p\u003e \u003cp\u003e11.3.3.4 Carbonitride and Cyanide Clusterfullerenes 341\u003c\/p\u003e \u003cp\u003e11.4 Properties Tuned by Endohedral Doping 342\u003c\/p\u003e \u003cp\u003e11.4.1 Spectroscopic Properties 342\u003c\/p\u003e \u003cp\u003e11.4.1.1 NMR Spectroscopy 343\u003c\/p\u003e \u003cp\u003e11.4.1.2 Absorption Spectroscopy 344\u003c\/p\u003e \u003cp\u003e11.4.1.3 Vibrational Spectroscopy 347\u003c\/p\u003e \u003cp\u003e11.4.2 Electrochemical Properties 349\u003c\/p\u003e \u003cp\u003e11.4.2.1 Conventional Endohedral Metallofullerenes 349\u003c\/p\u003e \u003cp\u003e11.4.2.2 Clusterfullerenes 351\u003c\/p\u003e \u003cp\u003e11.4.3 Magnetic Properties 353\u003c\/p\u003e \u003cp\u003e11.4.3.1 Dimetallofullerenes 353\u003c\/p\u003e \u003cp\u003e11.4.3.2 Clusterfullerenes 354\u003c\/p\u003e \u003cp\u003e11.5 Chemical Reactivity Tune by Endohedral Doping 358\u003c\/p\u003e \u003cp\u003e11.5.1 Impact of Endohedral Doping on the Reactivity of Fullerene Cages 358\u003c\/p\u003e \u003cp\u003e11.5.2 Chemical Reactivity of Endohedral Fullerenes Altered by Atomically Endohedral Doping 360\u003c\/p\u003e \u003cp\u003e11.6 Conclusions and Perspectives 362\u003c\/p\u003e \u003cp\u003eReferences 362\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 On- Surface Synthesis of Polyacenes and Narrow Band- Gap Graphene Nanoribbons 373\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eHironobu Hayashi and Hiroko Yamada\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 373\u003c\/p\u003e \u003cp\u003e12.1.1 Nanocarbon Materials 374\u003c\/p\u003e \u003cp\u003e12.1.2 Graphene Nanoribbons 374\u003c\/p\u003e \u003cp\u003e12.2 Bottom- Up Synthesis of Graphene Nanoribbons 375\u003c\/p\u003e \u003cp\u003e12.3 On- Surface Synthesis of Narrow Bandgap Armchair- Type Graphene Nanoribbons 378\u003c\/p\u003e \u003cp\u003e12.4 On- Surface Synthesis of Polyacenes as Partial Structure of Zigzag- Type Graphene Nanoribbons 382\u003c\/p\u003e \u003cp\u003e12.5 Conclusion and Perspectives 390\u003c\/p\u003e \u003cp\u003eAcknowledgments 390\u003c\/p\u003e \u003cp\u003eReferences 390\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 A Branch of Zintl Chemistry: Metal Clusters of Group 15 Elements 395\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eYu-He Xu, Nikolay V. Tkachenko, Alvaro Muñoz-Castro, Alexander I. Boldyrev, and Zhong- Ming Sun\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 395\u003c\/p\u003e \u003cp\u003e13.1.1 Homoatomic Group 15 Clusters 395\u003c\/p\u003e \u003cp\u003e13.1.2 Bonding Concepts 396\u003c\/p\u003e \u003cp\u003e13.1.3 Aromaticity in Zintl Chemistry 397\u003c\/p\u003e \u003cp\u003e13.2 Complex Coordination Modes in Arsenic Clusters 399\u003c\/p\u003e \u003cp\u003e13.3 Antimony Clusters with Aromaticity and Anti- Aromaticity 401\u003c\/p\u003e \u003cp\u003e13.4 Recent Advances in Bismuth- Containing Compounds 408\u003c\/p\u003e \u003cp\u003e13.5 Ternary Clusters Containing Group 15 Elements 411\u003c\/p\u003e \u003cp\u003e13.6 Conclusion and Perspectives 414\u003c\/p\u003e \u003cp\u003eReferences 415\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Exploration of Controllable Synthesis and Structural Diversity of Titanium─Oxo Clusters 423\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eMei- Yan Gao, Lei Zhang, and Jian Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 423\u003c\/p\u003e \u003cp\u003e14.2 Coordination Delayed Hydrolysis Strategy 425\u003c\/p\u003e \u003cp\u003e14.2.1 Solvothermal Synthesis 426\u003c\/p\u003e \u003cp\u003e14.2.2 Aqueous Sol- Gel Synthesis 426\u003c\/p\u003e \u003cp\u003e14.2.3 Ionothermal Synthesis 427\u003c\/p\u003e \u003cp\u003e14.2.4 Solid- State- Like Synthesis 427\u003c\/p\u003e \u003cp\u003e14.3 Ti─O Core Diversity 427\u003c\/p\u003e \u003cp\u003e14.3.1 Dense Structures 431\u003c\/p\u003e \u003cp\u003e14.3.2 Wheel- Shaped Structures 431\u003c\/p\u003e \u003cp\u003e14.3.3 Sphere- Shaped Structures 431\u003c\/p\u003e \u003cp\u003e14.3.4 Multicluster Structures 432\u003c\/p\u003e \u003cp\u003e14.4 Ligand Diversity 432\u003c\/p\u003e \u003cp\u003e14.4.1 Carboxylate Ligands 433\u003c\/p\u003e \u003cp\u003e14.4.2 Phosphonate Ligands 433\u003c\/p\u003e \u003cp\u003e14.4.3 Polyphenolic Ligands 435\u003c\/p\u003e \u003cp\u003e14.4.4 Sulfate Ligands 436\u003c\/p\u003e \u003cp\u003e14.4.5 Nitrogen Heterocyclic Ligands 437\u003c\/p\u003e \u003cp\u003e14.5 Metal- Doping Diversity 438\u003c\/p\u003e \u003cp\u003e14.5.1 Transition Metal Doping 439\u003c\/p\u003e \u003cp\u003e14.5.2 Rare Earth Metal Doping 440\u003c\/p\u003e \u003cp\u003e14.6 Structural Influence on Properties and Applications 441\u003c\/p\u003e \u003cp\u003e14.7 Conclusion and Perspectives 445\u003c\/p\u003e \u003cp\u003eAcknowledgment 446\u003c\/p\u003e \u003cp\u003eReferences 446\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Atom- Precise Cluster- Assembled Materials: Requirement and Progresses 453\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eSourav Biswas, Panpan Sun, Xia Xin, Sukhendu Mandal, and Di Sun\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 453\u003c\/p\u003e \u003cp\u003e15.2 Prospect of Cluster- Assembling Process and Their Classification 454\u003c\/p\u003e \u003cp\u003e15.2.1 Nanocluster Assembly in Crystal Lattice through Surface Ligand Interaction 455\u003c\/p\u003e \u003cp\u003e15.2.2 Nanocluster Assembly through Metal–Metal Bonds 456\u003c\/p\u003e \u003cp\u003e15.2.3 Nanocluster Assembly through Linkers 461\u003c\/p\u003e \u003cp\u003e15.2.3.1 One- Dimensional Nanocluster Assembly 463\u003c\/p\u003e \u003cp\u003e15.2.3.2 Two- Dimensional Nanocluster Assembly 465\u003c\/p\u003e \u003cp\u003e15.2.3.3 Three- Dimensional Nanocluster Assembly 469\u003c\/p\u003e \u003cp\u003e15.2.4 Nanocluster Assembly through Aggregation 470\u003c\/p\u003e \u003cp\u003e15.3 Conclusions and Outlook 474\u003c\/p\u003e \u003cp\u003eNotes 474\u003c\/p\u003e \u003cp\u003eAcknowledgments 475\u003c\/p\u003e \u003cp\u003eReferences 475\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Coinage Metal Cluster- Assembled Materials 479\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eZhao- Yang Wang and Shuang- Quan Zang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 479\u003c\/p\u003e \u003cp\u003e16.2 Structures of Metal Cluster- Assembled Materials 480\u003c\/p\u003e \u003cp\u003e16.2.1 Silver Cluster- Assembled Materials (SCAMs) 480\u003c\/p\u003e \u003cp\u003e16.2.1.1 Simple Ion Linker 480\u003c\/p\u003e \u003cp\u003e16.2.1.2 POMs Linker 482\u003c\/p\u003e \u003cp\u003e16.2.1.3 Organic Linker 482\u003c\/p\u003e \u003cp\u003e16.2.2 Gold Cluster- Assembled Materials (GCAMs) 491\u003c\/p\u003e \u003cp\u003e16.2.3 Copper Cluster- Assembled Materials (CCAMs) 492\u003c\/p\u003e \u003cp\u003e16.3 Applications 493\u003c\/p\u003e \u003cp\u003e16.3.1 Ratiometric Luminescent Temperature Sensing 494\u003c\/p\u003e \u003cp\u003e16.3.2 Luminescent Sensing and Identifying O\u003csub\u003e2\u003c\/sub\u003e and VOCs 495\u003c\/p\u003e \u003cp\u003e16.3.3 Catalytic Properties 495\u003c\/p\u003e \u003cp\u003e16.3.4 Anti- Superbacteria 498\u003c\/p\u003e \u003cp\u003e16.4 Conclusion 499\u003c\/p\u003e \u003cp\u003eAcknowledgments 499\u003c\/p\u003e \u003cp\u003eReferences 499\u003c\/p\u003e \u003cp\u003eIndex 503\u003c\/p\u003e  \u003cp\u003e\u003cb\u003eRongchao Jin \u003c\/b\u003eis a leading expert in experimental work on atomically precise nanochemistry working in the Department of Chemistry at Carnegie Mellon University in the United States. \u003c\/p\u003e\u003cp\u003e\u003cb\u003eDe-en Jiang \u003c\/b\u003eis a leading theorist on atomically precise nanochemistry working in the Chemical and Biomolecular Engineering Department at Vanderbilt University in the United States.   \u003c\/p\u003e\u003cp\u003e\u003cb\u003eExplore recent progress and developments in atomically precise nanochemistry\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eChemists have long been motivated to create atomically precise nanoclusters, not only for addressing some fundamental issues that were not possible to tackle with imprecise nanoparticles, but also to provide new opportunities for applications such as catalysis, optics, and biomedicine. In \u003ci\u003eAtomically Precise Nanochemistry\u003c\/i\u003e, a team of distinguished researchers delivers a state-of-the-art reference for researchers and industry professionals working in the fields of nanoscience and cluster science, in disciplines ranging from chemistry to physics, biology, materials science, and engineering. \u003c\/p\u003e\u003cp\u003eA variety of different nanoclusters are covered, including metal nanoclusters, semiconductor nanoclusters, metal-oxo systems, large-sized organometallic nano-architectures, carbon clusters, and supramolecular architectures. The book contains not only experimental contributions, but also theoretical insights into the atomic and electronic structures, as well as the catalytic mechanisms. The authors explore synthesis, structure, geometry, bonding, and applications of each type of nanocluster. \u003c\/p\u003e\u003cp\u003ePerfect for researchers working in nanoscience, nanotechnology, and materials chemistry, \u003ci\u003eAtomically Precise Nanochemistry \u003c\/i\u003ewill also benefit industry professionals in these sectors seeking a practical and up-to-date resource.\u003c\/p\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":47988774600933,"sku":"NP9781119788645","price":190.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/1842\/7735\/files\/9781119788645.jpg?v=1761781541","url":"https:\/\/k12savings.com\/es\/products\/atomically-precise-nanochemistry-isbn-9781119788645","provider":"K12savings","version":"1.0","type":"link"}