The Chemistry of Organomanganese Compounds

The past 15 years have seen tremendous progress in manganese chemistry, with the low cost of this metal making it an attractive choice as a functional group in organic syntheses. Surveying key compounds and reaction intermediates used in organic syntheses, this is the first volume in the Patai Series to focus on manganese in organic and organometallic chemistry. With contributions by leading experts, the book delivers the usual high quality of the Patai series. It also emphasizes novel applications in organic synthesis as well as technological trends in industrial, biomedical, and materials science.

1 Structure and bonding of simple manganese-containing compounds 1
Minh Tho Nguyen, Devashis Majumdar, Jerzy Leszczynski and Szczepan Roszak

2 Structural organomanganese chemistry 43
Ryan M. Meier and Timothy P. Hanusa

3 Energetics of organomanganese compounds 171
Joel F. Liebman and Suzanne W. Slayden

4 Mass spectrometry and gas-phase ion chemistry of organomanganese complexes 223
Sergiu P. Palii and Dmitri V. Zagorevskii

5 Manganese in biological systems: Transport and function 289
Eitan Salomon, Nir Keren, Margarita Kanteev and Noam Adir

6 Preparation and reactivity of organomanganese compounds 305
Gérard Cahiez and Olivier Gager

7 Structures and reaction mechanisms of manganese oxidants 419
Donald G. Lee

8 Cationic(η⁶-arene)- and neutral (η⁵-cyclohexadienyl)-tricarbonylmanganese complexes: Synthesis and reactivity 489
Françoise Rose-Munch, Eric Rose and Antoine Eloi

9 Organomanganese-mediated radical reactions 559
Gregory K. Friestad

10 The chemistry of organomanganese ate complexes 585
Hideki Yorimitsu and Koichiro Oshima

11 Catalytic enantioselective reactions using organomanganese compounds 623
Nicka Chinkov

12 The chemistry of manganese enolates 707
José M. Concellón, Humberto Rodríguez-Solla and Vicente del Amo

13 s-Block-metal-mediated manganation reactions 721
Richard A. Layfield

Author index 739

Subject index 799

Professor Ilan Marek, Department of Chemistry, Technion — Israel Institute of Technology, Haifa, Israel.

Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem,? Jerusalem, Israel.