The Chemistry of Metal Phenolates, Volume 2

PATAI's Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 140 volumes have been published in the series.
Metal phenolate chemistry provides synthetic routes to phenols and polyphenols (including calixarenes), which are important compound classes in biological processes such as ageing, signaling and cell repair. They are also increasingly used as scaffolds for pharmaceuticals, and as catalysts. The present volume extends and complements the previous volume, which was published in 2014.In der Reihe PATAI's Chemistry of Functional Groups werden umfassende Reviews zu allen Aspekten spezifischer funktioneller Gruppen veröffentlicht. Jeder Band enthält herausragende Expertisen zu Theorie und Berechnung, NMR, MS, weiteren spektroskopischen Verfahren, zur Analytischen Chemie, zu strukturellen Aspekten, Thermochemie, Photochemie, synthetischen Ansätzen und Strategien, synthetischen Einsätzen und Anwendungen in dem chemischen und pharmazeutischen Industrie, zu biologischen, biochemischen und Umweltaspekten. Heute zählt die Reihe über 140 Bände. The Chemistry of Metal Phenolates behandelt Synthesewege für Phenole und Polyphenole (auch Calixarene), die wichtige Verbindungsklassen bei biologischen Prozessen darstellen, z. B. bei Alterungsprozessen, im Bereich Signaling und bei der Zellreparatur. Diese Stoffe werden auch zunehmend als Gerüst für Pharmazeutika und als Katalysatoren eingesetzt. Der vorliegende Band erweitert und ergänzt die Ausgabe von 2014.

1. Recent advances in acid–base and solvation properties of metal phenolates 1
Erick L. Bastos and Caroline O. Machado

2. Photophysical and structural properties of rare-earth phenolate compounds 61
Ercules E. S. Teotonio, Lucas C. V. Rodrigues, Hermi F. Brito, Maria Claudia F. C. Felinto, and Oscar M. L. Malta

3. Advances in the catalysis of organic processes by metal phenolates 125
Maria Elisa da Silva Serra and Dina M. B. Murtinho

4. Metal complexes with oligo(salen)-type ligands 153
Shigehisa Akine

5. Coordination chemistry and applications of phenolic homooxa and homoazacalixarene–metal complexes 195
Paula M. Marcos and Peter J. Cragg

6. Coordination chemistry and applications of phenolic thiacalixarene–metal complexes 237
Peter J. Cragg and Paula M. Marcos

7. Recent advances in the field of phenoxyl radical–metal complexes 269
Yuichi Shimazaki

8. Polymerization catalysis by metal phenolates 295
Samuel Dagorne and Charles Romain

9. Recent advances in biomimetic metal phenolates 339
Gabriella Tamasi and Renzo Cini

10. Contemporary use of azophenolates and related species in the determination of metal cations 383
Maja Ponikvar-Svet and Joel F. Liebman

11. Advances in the analytical chemistry of metal phenolates 407
Jacob Zabicky

Subject index 449

Jacob Zabicky is an emeritus professor at Ben Gurion University of the Negev in Beer Sheva, Israel. Earning his Ph.D. in Organic Chemistry with Saul Patai in the 1950s, he has since worked and taught at many different institutions in Israel, the UK, Venezuela, Germany, Spain, South Africa, and the USA. Prof. Zabicky is currently a lecturer at the Jerusalem College of Engineering and a member of the steering committee for the Israeli Center for Powder Technology. He has edited volumes in the Patai Series since the 1970s, the most recent ones on the subjects of metal enolates and metal phenolates.

A series of advanced treatises founded by Professor Saul Patai and now under the general editorship of Professors Ilan Marek, Zvi Rappoport and Joel F. Liebman

PATAI's Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 150 volumes have been published in the series.

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