Advanced Structural Chemistry, 3 Volumes

Advanced Structural Chemistry

Discover the relationships between inorganic chemical synthesis, structure, and property with these comprehensive and insightful volumes

Advanced Structural Chemistry: Tailoring Properties of Inorganic Materials and their Applications (3 Volume Set) offers readers the opportunity to discover the relationship between the structure and function of matter, develop efficient and precise synthesis methodology, and to understand the theoretical tools for new functional substances.

Advanced Structural Chemistry clarifies the relationships between synthesis and structure, as well as structure and property, both of which are central to the creation of new materials with unique functions. In addition to subjects like the syntheses of metal-oxide clusters, metal-organic cages, and metal-organic frameworks with tailored optical, electric, ferroelectric, magnetic, adsorption, separation, and catalytic properties, the accomplished editor Rong Cao provides readers with information on a wide variety of topics, such as:

• Coordination-assembled metal-organic macrocycles and cages, including metallacycles and metallacages
• The structural chemistry of metal-oxo clusters, including the oxo clusters of transition metal, main group metal, and lanthanides
• Synthetic approaches, structural diversities, and biological aspects of molybdenum-based heterometallic sulfide clusters and coordination polymers
• Group 11-15 metal chalcogenides, including discrete chalcogenide clusters synthesized in ionic liquids
• The structures of metal-organic frameworks, including one-, two-, and three-dimensional MOFs

Perfect for inorganic chemists, structural chemists, solid state chemists, material scientists, and solid state physicists, Advanced Structural Chemistry also belongs on the bookshelves of catalytic and industrial chemists who seek to improve their understanding of the structure and functions of inorganic materials.Diese einzigartige Publikation beschäftigt sich mit der Beziehung zwischen Struktur und Funktion von Stoffen, wirkungsvollen und präzisen Synthesemethoden und theoretischen Werkzeugen für neue Funktionscluster und poröse Materialien.

Volume 1

1 Introduction 1
Jian Zhang, Guo-Cong Guo, Rong Cao, and Xin-Tao Wu

2 Coordination-Assembled Metal–Organic Macrocycles and Cages 9
Xiao-Zhen Li, Yu-Ling Liang, Li-Peng Zhou, Li-Xuan Cai, Qiang-Yu Zhu, Zhuo Wang, Xiao-Qing Guo, Dan-Ni Yan, Shao-Jun Hu, Shao-Chuan Li, Shi-Yu Wu, Shi-Long Han, Ran Chen, Pei-Ming Cheng, Kai Cheng, Xiao-Shan Feng, Tian-Pu Sheng, Can He, Feng-Rong Dai, and Qing-Fu Sun

2.1 Introduction 9

2.2 Metallacycles 9

2.3 Metallacages 35

2.4 Conclusion 77

Acknowledgments 77

References 77

3 Structural Chemistry of Metal-Oxo Clusters 81
Xiaofeng Yi, Weihui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, and Lei Zhang

3.1 Oxo Clusters of Transition Metal 81

3.2 Oxo Clusters of Main Group Metal 111

3.3 Oxo Clusters of Lanthanides 122

3.4 Conclusion 149

Acknowledgments 149

References 149

4 Synthetic Approaches, Structural Diversities, and Biological Aspects of Molybdenum (Tungsten)-Based Heterometallic Sulfide Clusters and Coordination Polymers 163
Du Shaowu and Wu Xintao

4.1 Introduction 163

4.2 Synthesis of Mo–Fe–S Cuboidal Clusters for the Structural Modeling of the Iron–Molybdenum Cofactor
(FeMoco) 167

4.3 Rationally Designed Synthesis of Mo(W)–Cu(Ag)–S Clusters 173

4.4 Rationally Designed Synthesis of W(Mo)–Ag–S Coordination Polymers 182

4.5 Conclusion 190

Acknowledgments 191

References 191

5 Group 11–15 Metal Chalcogenides 195
Jian-Rong Li, Mei-Ling Feng, Bing Hu, and Xiao-Ying Huang

5.1 Introduction 195

5.2 Inorganic–Organic Hybrid Chalcogenides Based on II–VI Semiconductors 198

5.3 Discrete Chalcogenide Clusters Synthesized in Ionic Liquids 209

5.4 Chalcogenidostannates 218

5.5 Chalcogenidoantimonates 234

5.6 Selected Properties 260

5.7 Conclusion 275

Acknowledgments 276

References 277

Volume 2

6 The Structures of Metal–Organic Frameworks 283
Yuehong Wen, Xintao Wu, and Qi-Long Zhu

7 Structural Design and Rational Synthesis 391
Qipu Lin

8 Structural Topologies and Interpenetration in the Coordination Polymers 425
Fei Wang, Hai-Xia Zhang, and Jian Zhang

9 Inorganic Chalcogenides: From Zero-Dimensional Clusters to Three-Dimensional Frameworks 465
Hua Lin, Xin-Tao Wu, and Qi-Long Zhu

10 Relationship Between Structure and Electroluminescent, Photochromic, or Second-Order Nonlinear Optical Property 531
Ming-Sheng Wang, San-Gen Zhao, Qian Wang, and Zhong-Ning Che

11 Relationship Between Structure and Ferroelectric Properties 601
Wuqian Guo, Zhihua Sun, Zhiyun Xu, Shiguo Han, and Junhua Luo

Volume 3

12 The Relationship Between Structure and Electric Property 669
Guan-E Wang, Yonggang Zhen, Guo-Dong Wu, Huanli Dong, and Gang Xu

13 Understanding Magneto-Structural Correlations Toward Design of Molecular Magnets 777
Zhu Zhuo, Guo-Ling Li, and You-Gui Huang

14 Relationship Between MOF Structures and Gas Absorption Properties 833
Qi Yin and Tian-Fu Liu

15 Relationship Between Structure and Separation Property 881
Zhanfeng Ju, El-Sayed M. El-Sayed, and Daqiang Yuan

16 Catalysis in Metal–Organic Frameworks: Relationship Between Activities and Structures 953
Yuan-Biao Huang, Teng Zhang, and Rong Cao

Index 995

VOLUME 1
1. INTRODUCTION
2. COORDINATION-ASSEMBLED METAL-ORGANIC MACROCYCLES AND CAGES
3. STRUCTURAL CHEMISTRY OF METAL-OXO CLUSTERS
4. SYNTHETIC APPROACHES, STRUCTURAL DIVERSITIES, AND BIOLOGICAL ASPECTS OF MOLYBDENUM (TUNGSTEN)-BASED HETEROMETALLIC SULFIDE CLUSTERS AND COORDINATION POLYMERS
5. GROUP 11-15 METAL CHALCOGENIDES

VOLUME 2
6. THE STRUCTURES OF METAL?ORGANIC FRAMEWORKS
7. STRUCTURAL DESIGN AND RATIONAL SYNTHESIS
8. STRUCTURAL TOPOLOGIES AND INTERPENETRATION IN THE COORDINATION POLYMERS
9. INORGANIC CHALCOGENIDES: FROM ZERO-DIMENSIONAL CLUSTERS TO THREE-DIMENSIONAL FRAMEWORKS
10. RELATIONSHIP BETWEEN STRUCTURE AND ELECTROLUMINESCENT, PHOTOCHROMIC, OR SECOND-ORDER NONLINEAR OPTICAL PROPERTY
11. RELATIONSHIP BETWEEN STRUCTURE AND FERROELECTRIC PROPERTIES

VOLUME 3
12. THE RELATIONSHIP BETWEEN STRUCTURE AND ELECTRIC PROPERTY
Introduction
Structure and Electrical Properties of Inorganic Conductive Materials
Structure and Electrical Properties of Organic Conductive Materials
Structure and Electrical Properties of Organic-Inorganic Hybrid Conductive Materials
13. UNDERSTANDING MAGNETO-STRUCTURAL CORRELATIONS TOWARD DESIGN OF MOLECULAR MAGNETS
Introduction
Magneto-Structural Correlations in Spin-Crossover Compounds
Magneto-Structural Correlations of Low-Dimensional Magnets
Influence of Ligand Bridging Modes on the Mediated Magnetic Coupling
Geometrically Frustrated Molecular Magnetic Materials
14. RELATIONSHIP BETWEEN MOF STRUCTURES AND GAS ABSORPTION PROPERTIES
Introduction
Basic Conceptions About Gas Absorption
The Correlation Between Physical Adsorption Isotherms and MOFs Structures
Effect of Material Defects on Gas Adsorption
Representative MOFs with Ultrahigh Surface Area and the Factors Effecting on Surface Area
Adsorption Enthalpy of MOF Materials
15. RELATIONSHIP BETWEEN STRUCTURE AND SEPARATION PROPERTY
Introduction
CO2 Capture and Separation
Separation of Hydrocarbons
Separation of Noble Gases
Separation of Hydrogen Isotopes
Enantioselective Separation
16. CATALYSIS IN METAL-ORGANIC FRAMEWORKS: RELATIONSHIP BETWEEN ACTIVITIES AND STRUCTURES
Introduction
Catalysis by Metal Nodes
Catalysis by Functionalized Linkers
Catalysis by Species in Pores
Asymmetric Catalysis in MOFs
Photocatalysis in MOFs
Multi-Component Catalysis Using MOFs

Rong Cao, PhD, is Director of the Fujian Institute of Research on the Structure of Matter (FJIRM) and Director of the Institute of Urban Environment at the Chinese Academy of Sciences (CAS). He received his doctorate in Chemical Physics from the FJIRM, CAS. He is the recipient of multiple awards, including the China Youth Science and Technology Award and the National Candidate of New Century Talents Project in 2006.